A novel luminescent EuBTC@HA composite with dual sensing properties Weronika Bodylska, Adam W. Augustyniak, Dariusz C. Bieńko, Marzena Fandzloch Dalton Transactions, 2025 The first example of a Eu(iii)-based coordination polymer supported on a (bio)carrier: EuBTC@HA (where H3BTC = 1,3,5-benzenetricarboxylic acid and HA stands for hydroxyapatite) for dual sensing of Fe3+ ions and ofloxacin.
The Role of Water in Reactions Catalyzed by Transition Metals Catalysis for A Sustainable Environment Reactions Processes and Applied Technologies Volume 1 3, 2024
The two faces of platinum hydrospirophosphorane complexes—Not only relevant catalysts but cytotoxic compounds as well Anna Skarżyńska, Marta Kowalczyk, Mariusz Majchrzak, Marta Piętka, Adam W. Augustyniak, et al. Applied Organometallic Chemistry, 2022 Platinum complexes [PtCl2(L)] L = L1, L2 with symmetrical HP (OCH2CMe2NH)2 (L1) and unsymmetrical HP(OCMe2CMe2O)(OCH2CMe2NH) (L2) hydrospirophosphorane (HSP) ligands were demonstrated to play a dual role of catalysts and cytotoxic compounds as well. The structure of new complex [PtCl2(L2)] was confirmed by physicochemical and spectroscopic methods, as well as single X‐ray diffraction studies for [PtCl2{P (OCMe2CMe2O)(OCH2CMe2NH2)}]. HSP ligand coordinated to the platinum center in bidentate κ2‐P,NH2 chelating mode of fashion. Both complexes were found to exhibit catalytic activity for Heck cross‐coupling reactions of iodobenzene with substituted styrenes, with good conversion and yield of stilbenes. Moreover, complexes have been applied as excellent catalysts for highly regioselective hydrosilylation of aromatic and aliphatic terminal olefins, and acetylenes terminal and internal as well. On the other hand, the preliminary biological studies revealed that in the presence of foretinib, drug candidate in clinical trials for the treatment of cancer, platinum complexes revealed increased synergistic effect and efficiently decreased the number of viable cells of triple negative breast cancer MDA‐MB‐231 cell line.
New Palladium – ZrO2 Nano-Architectures from Thermal Transformation of UiO-66-NH2 for Carbonylative Suzuki and Hydrogenation Reactions Waleed Alsalahi, Adam W. Augustyniak, Włodzimierz Tylus, Anna M. Trzeciak Chemistry A European Journal, 2022 The new nanocomposites, Pd/C/ZrO2, PdO/ZrO2, and Pd/PdO/ZrO2, were prepared by thermal conversion of Pd@UiO‐66‐Zr−NH2 (MOF) in nitrogen or air atmosphere. The presence of Pd nanoparticles, uniformly distributed on the ZrO2 or C/ZrO2 matrix, was evidenced by transmission electron microscopy, scanning electron microscopy (SEM), Raman and X‐ray Photoelectron Spectroscopy (XPS) methods. All pyrolysed composites retained the shape of the MOF template. They catalyze carbonylative Suzuki coupling under 1 atm CO with an efficiency significantly higher than the original Pd@UiO‐66‐Zr−NH2. The most active PdO/ZrO2 composite, formed benzophenone with TOF up to 1600 h−1, while by using Pd@UiO‐66‐Zr−NH2, much lower TOF values, 51–95 h−1, were achieved. After the reaction, PdO/ZrO2 was recovered with the same composition and catalytic activity. Very good results were also obtained in the transfer hydrogenation of benzophenones to alcohols with Pd/C/ZrO2 and PdO/ZrO2 catalysts under microwave irradiation.
A chelate method for N0x removal from flue gases. State-of-the-art and future Przemysl Chemiczny, 2012
RECENT SCHOLAR PUBLICATIONS
A triazolopyrimidine Ag (I) coordination polymer: from solid-state characterization to bioapplication B Barszcz, AW Augustyniak, S Galli, J Trzcińska-Wencel, P Golińska, ... Journal of Molecular Structure, 145557 , 2026 2026
Funkcjonalizacja alkinów katalizowana związkami metali przejściowych A Skarżyńska, AM Trzeciak, I Czeluśniak, AW Augustyniak, W Bury Wiadomości Chemiczne 80 (1-2), 321-354 , 2026 2026
A novel luminescent EuBTC@ HA composite with dual sensing properties W Bodylska, AW Augustyniak, DC Bieńko, M Fandzloch Dalton Transactions 54 (23), 9376-9387 , 2025 2025
Double-doped Pd/CN–B nano-architectures for hydrogen evolution and hydrogenation reaction in water AW Augustyniak Catalysis Science & Technology 15 (12), 3536-3543 , 2025 2025 Citations: 3
The Role of Water in Reactions Catalyzed by Transition Metals AW Augustyniak, AM Trzeciak Catalysis for a Sustainable Environment: Reactions, Processes and Applied … , 2024 2024
A new MOF@ bioactive glass composite reinforced with silver nanoparticles–a new approach to designing antibacterial biomaterials M Fandzloch, AW Augustyniak, J Trzcińska-Wencel, P Golińska, K Roszek Dalton Transactions 53 (26), 10928-10937 , 2024 2024 Citations: 9
Bioactive nanoglasses and xerogels (SiO2–CaO and SiO2–CaO–P2O5) as promising candidates for biomedical applications M Fandzloch, W Bodylska, AW Augustyniak, K Roszek, A Jaromin, ... Ceramics International 49 (5), 7438-7451 , 2023 2023 Citations: 13
NiOBDP and Ni/NiOBDP catalyzed transfer hydrogenation of acetophenone and 4-nitrophenol AW Augustyniak, A Gniewek, R Szukiewicz, M Wiejak, M Korabik, ... Polyhedron 224, 116029 , 2022 2022 Citations: 3
Hydrogen production and transfer hydrogenation of phenylacetylene with ammonia borane in water catalyzed by the [Pd(2-pymo)2]n framework AMT Adam W. Augustyniak Inorganica Chimica Acta 538, 120977 , 2022 2022 Citations: 11
The two faces of platinum hydrospirophosphorane complexes—Not only relevant catalysts but cytotoxic compounds as well A Skarżyńska, M Kowalczyk, M Majchrzak, M Piętka, AW Augustyniak, ... Applied Organometallic Chemistry 36 (2), e6520 , 2022 2022 Citations: 5
New palladium‐ZrO2 nano‐architectures from thermal transformation of UiO‐66‐NH2 for carbonylative Suzuki and hydrogenation reactions AT W. Alsalahi, A.W. Augustyniak, W. Tylus Chemistry – A European Journal , 2021 2021 Citations: 9
Cover Feature: Pd‐Nanocomposites Formed by Calcination of [Pd(2‐pymo) 2 ] n Framework as Catalysts of Phenylacetylene Semihydrogenation in Water … AW Augustyniak, AM Trzeciak ChemCatChem 13 (9), 2094-2094 , 2021 2021
Pd‐Nanocomposites Formed by Calcination of [Pd(2‐pymo) 2 ] n Framework as Catalysts of Phenylacetylene Semihydrogenation in Water AW Augustyniak, AM Trzeciak ChemCatChem 13 (9), 2145-2151 , 2021 2021 Citations: 16
Phenylacetylene semihydrogenation over a palladium pyrazolate hydrogen-bonded network AW Augustyniak, AM Trzeciak Inorganica Chimica Acta 518, 120255 , 2021 2021 Citations: 5
Polimery koordynacyjne wanadu: stan obecny i perspektywy AW Augustyniak Wiadomości Chemiczne 75 (3-4), 253-269 , 2021 2021
First dinuclear rhodium (II) complexes with triazolopyrimidines and the prospect of their potential biological use M Fandzloch, AW Augustyniak, L Dobrzańska, T Jędrzejewski, J Sitkowski, ... Journal of Inorganic Biochemistry 210, 111072 , 2020 2020 Citations: 19
Incorporation of PdCl 2 P 2 Complexes in Ni‐MOF for Catalyzing Heck Arylation of Functionalized Olefins S Tarnowicz‐Ligus, A Augustyniak, AM Trzeciak European Journal of Inorganic Chemistry 2019 (39-40), 4282-4288 , 2019 2019 Citations: 19
Magnesium exchanged zirconium metal–organic frameworks with improved detoxification properties of nerve agents R Gil-San-Millan, E Lopez-Maya, AE Platero-Prats, V Torres-Pérez, ... Journal of the American Chemical Society 141 (30), 11801-11805 , 2019 2019 Citations: 88
The role of palladium nanoparticles in catalytic C–C cross-coupling reactions AM Trzeciak, AW Augustyniak Coordination Chemistry Reviews 384, 1-20 , 2019 2019 Citations: 233
Immobilized Pd (0) and Pd (II) catalysts for CC cross-coupling reactions AM Trzeciak, A Augustyniak, W Alsalahi 5th EUCHEMS INORGANIC CHEMISTRY CONFERENCE, 32-32 , 2019 2019
MOST CITED SCHOLAR PUBLICATIONS
The role of palladium nanoparticles in catalytic C–C cross-coupling reactions AM Trzeciak, AW Augustyniak Coordination Chemistry Reviews 384, 1-20 , 2019 2019 Citations: 233
Magnesium exchanged zirconium metal–organic frameworks with improved detoxification properties of nerve agents R Gil-San-Millan, E Lopez-Maya, AE Platero-Prats, V Torres-Pérez, ... Journal of the American Chemical Society 141 (30), 11801-11805 , 2019 2019 Citations: 88
Palladium nanoparticles supported on a nickel pyrazolate metal organic framework as a catalyst for Suzuki and carbonylative Suzuki couplings AW Augustyniak, W Zawartka, JAR Navarro, AM Trzeciak Dalton Transactions 45 (34), 13525-13531 , 2016 2016 Citations: 52
A vanadium(IV) pyrazolate metal organic polyhedron with permanent porosity and adsorption selectivity JARN Adam Wiktor Augustyniak, Marzena Fandzloch, Maria Domingo-Garcia, Iwona ... Chemical Communications , 2015 2015 Citations: 46
Applied kinetics aspects of ferric EDTA complex reduction with metal powder TT Suchecki, B Mathews, AW Augustyniak, H Kumazawa Industrial & Engineering Chemistry Research 53 (37), 14234-14240 , 2014 2014 Citations: 41
First dinuclear rhodium (II) complexes with triazolopyrimidines and the prospect of their potential biological use M Fandzloch, AW Augustyniak, L Dobrzańska, T Jędrzejewski, J Sitkowski, ... Journal of Inorganic Biochemistry 210, 111072 , 2020 2020 Citations: 19
Incorporation of PdCl 2 P 2 Complexes in Ni‐MOF for Catalyzing Heck Arylation of Functionalized Olefins S Tarnowicz‐Ligus, A Augustyniak, AM Trzeciak European Journal of Inorganic Chemistry 2019 (39-40), 4282-4288 , 2019 2019 Citations: 19
Design of Shape‐Palladium Nanoparticles Anchored on Titanium(IV) Metal‐Organic Framework: Highly Active Catalysts for Reduction of p ‐Nitrophenol in Water AW Augustyniak, M Sadakiyo, JAR Navarro, AM Trzeciak ChemistrySelect 3 (27), 7934-7939 , 2018 2018 Citations: 18
Pd‐Nanocomposites Formed by Calcination of [Pd(2‐pymo) 2 ] n Framework as Catalysts of Phenylacetylene Semihydrogenation in Water AW Augustyniak, AM Trzeciak ChemCatChem 13 (9), 2145-2151 , 2021 2021 Citations: 16
Reactivity of nano-size zinc powder in the aqueous solution of [Fe III (edta)(H 2 O)] − AW Augustyniak, TT Suchecki, H Kumazawa Environmental technology 38 (1), 103-107 , 2017 2017 Citations: 15
Bioactive nanoglasses and xerogels (SiO2–CaO and SiO2–CaO–P2O5) as promising candidates for biomedical applications M Fandzloch, W Bodylska, AW Augustyniak, K Roszek, A Jaromin, ... Ceramics International 49 (5), 7438-7451 , 2023 2023 Citations: 13
Hydrogen production and transfer hydrogenation of phenylacetylene with ammonia borane in water catalyzed by the [Pd(2-pymo)2]n framework AMT Adam W. Augustyniak Inorganica Chimica Acta 538, 120977 , 2022 2022 Citations: 11
A new MOF@ bioactive glass composite reinforced with silver nanoparticles–a new approach to designing antibacterial biomaterials M Fandzloch, AW Augustyniak, J Trzcińska-Wencel, P Golińska, K Roszek Dalton Transactions 53 (26), 10928-10937 , 2024 2024 Citations: 9
New palladium‐ZrO2 nano‐architectures from thermal transformation of UiO‐66‐NH2 for carbonylative Suzuki and hydrogenation reactions AT W. Alsalahi, A.W. Augustyniak, W. Tylus Chemistry – A European Journal , 2021 2021 Citations: 9
The two faces of platinum hydrospirophosphorane complexes—Not only relevant catalysts but cytotoxic compounds as well A Skarżyńska, M Kowalczyk, M Majchrzak, M Piętka, AW Augustyniak, ... Applied Organometallic Chemistry 36 (2), e6520 , 2022 2022 Citations: 5
Phenylacetylene semihydrogenation over a palladium pyrazolate hydrogen-bonded network AW Augustyniak, AM Trzeciak Inorganica Chimica Acta 518, 120255 , 2021 2021 Citations: 5
Double-doped Pd/CN–B nano-architectures for hydrogen evolution and hydrogenation reaction in water AW Augustyniak Catalysis Science & Technology 15 (12), 3536-3543 , 2025 2025 Citations: 3
NiOBDP and Ni/NiOBDP catalyzed transfer hydrogenation of acetophenone and 4-nitrophenol AW Augustyniak, A Gniewek, R Szukiewicz, M Wiejak, M Korabik, ... Polyhedron 224, 116029 , 2022 2022 Citations: 3
Katalizatory palladowe immobilizowane w materiałach typu MOF aktywne w reakcjach uwodornienia AW Augustyniak, AM Trzeciak Wiadomości Chemiczne 73 (3-4), 221-241 , 2019 2019 Citations: 2
A chelate method for NOx removal from flue gases. State-of-the-art and future AW Augustyniak, TT Suchecki PRZEMYSL CHEMICZNY 91 (12), 2476-2480 , 2012 2012 Citations: 1