Inclusion of CoTiO3 to ameliorate the re/dehydrogenation properties of the Mg–Na–Al system N.A. Ali, N.Y. Yusnizam, N.A. Sazelee, Sami-ullah Rather, Haizhen Liu, M. Ismail Journal of Magnesium and Alloys, 2024 For the first time, the MgH2–NaAlH4 (ratio 4:1) destabilized system with CoTiO3 addition has been explored. The CoTiO3-doped MgH2–NaAlH4 sample begins to dehydrogenate at 130 °C, which is declined by 40 °C compared to the undoped MgH2–NaAlH4. Moreover, the de/rehydrogenation kinetics characteristics of the CoTiO3-doped MgH2–NaAlH4 were greatly ameliorated. With the inclusion of CoTiO3, the MgH2–NaAlH4 composite absorbed 5.2 wt.% H2, higher than undoped MgH2–NaAlH4. In the context of dehydrogenation, the CoTiO3-doped MgH2–NaAlH4 sample desorbed 2.6 wt.% H2, almost doubled compared to the amount of hydrogen desorbed from the undoped MgH2–NaAlH4 sample. The activation energy obtained by the Kissinger analysis for MgH2 decomposition was significantly lower by 35.9 kJ/mol than the undoped MgH2–NaAlH4 sample. The reaction mechanism demonstrated that new phases of MgCo and AlTi3 were generated in situ during the heating process and are likely to play a substantial catalytic function and be useful in ameliorating the de/rehydrogenation properties of the destabilized MgH2–NaAlH4 system with the inclusion of CoTiO3.
Catalytic role of TiF3 in enhancing the hydrogen storage performance of LiAlH4-activated carbon composites NSC Mazlan, FAH Yap, NA Ali, M Ismail Materials Letters, 140434 , 2026 2026
The role of MgH2 in improving the hydrogen storage performance of the KBH4–LiAlH4 system NA Sazelee, NA Ali, M Ismail International Journal of Hydrogen Energy 199, 152863 , 2026 2026 Citations: 1
The thermal hydrogen storage properties of a ternary hydride system: MgH2–NaAlH4–Ca (BH4) 2 NA Ali, FAH Yap, NA Sazelee, MS Yahya, M Ismail Materials Letters, 139914 , 2025 2025
Improved dehydrogenation performances of LiAlH4 doped with CuFe2O4 MAN Ahmad, NA Ali, NA Sazelee, S Rather, S Suwarno, M Ismail Materials Today Communications 46, 112659 , 2025 2025 Citations: 4
Reaction mechanism and absorption/desorption kinetics performance of the destabilised KBH4–LiAlH4 system NA Sazelee, NA Ali, S Suwarno, S Rather, M Ismail International Journal of Hydrogen Energy 109, 520-527 , 2025 2025 Citations: 3
Effect of TiSiO4 addition on the dehydrogenation properties of NaAlH4 NY Yusnizam, NA Sazelee, NA Ali, M Ismail International Journal of Hydrogen Energy 73, 158-164 , 2024 2024 Citations: 13
Inclusion of CoTiO3 to ameliorate the re/dehydrogenation properties of the Mg–Na–Al system NA Ali, NY Yusnizam, NA Sazelee, S Rather, H Liu, M Ismail Journal of Magnesium and Alloys 12 (3), 1215-1226 , 2024 2024 Citations: 8
Improving the desorption properties of LiAlH4 by the addition of Ni0. 6Zn0. 4O NA Sazelee, NA Ali, H Liu, M Ismail International Journal of Hydrogen Energy 56, 543-551 , 2024 2024 Citations: 15
Zn2TiO4 synthesized via solid-state method and its effects on dehydrogenation properties of LiAlH4 NA Ali, MM Nasef, AA Jalil, M Ismail International Journal of Hydrogen Energy 50, 484-494 , 2024 2024 Citations: 12
Hydrogen storage properties and reaction mechanism of the Mg-Li-Na-Al ternary hydride system NSC Mazlan, FAH Yap, MS Yahya, NA Ali, NA Sazelee, M Ismail Materials Today: Proceedings 96, 23-29 , 2024 2024 Citations: 3
Boosting the de-/rehydrogenation properties of MgH2 with the addition of BaCoF4 NY Yusnizam, NA Ali, NA Sazelee, MM Nasef, AA Jalil, M Ismail Journal of Alloys and Compounds 967, 171618 , 2023 2023 Citations: 43
Enhancement of hydrogen storage properties of NaAlH4 catalyzed by CuFe2O4 NS Mustafa, NA Sazelee, NA Ali, NN Sulaiman, M Ismail International Journal of Hydrogen Energy 48 (90), 35197-35205 , 2023 2023 Citations: 20
Influence of TiF3 catalyst on the enhancement of hydrogen storage properties of Mg-Na-Al-Li-B composite system NSC Mazlan, FAH Yap, MS Yahya, SB Mohamed, NA Sazelee, NA Ali, ... Journal of Energy Storage 71, 108097 , 2023 2023 Citations: 17
Synthesis of Zn2TiO4 via solid-state method as a promising additive for dehydrogenation properties of NaAlH4 NA Ali, M Ismail, S Rather, HS Bamufleh, H Alhumade, AA Taimoor, ... International Journal of Hydrogen Energy 48 (88), 34420-34429 , 2023 2023 Citations: 3
Enhancing hydrogen storage performance of MgH2 through the addition of BaMnO3 synthesized via solid-state method NA Sazelee, NA Ali, MS Yahya, MFM Din, M Ismail International Journal of Hydrogen Energy 48 (79), 30844-30857 , 2023 2023 Citations: 54
Ameliorating the re/dehydrogenation behaviour of MgH2 by zinc titanate addition NA Ali, NA Sazelee, MFM Din, MM Nasef, AA Jalil, H Liu, M Ismail Journal of Magnesium and Alloys 11 (6), 2205-2215 , 2023 2023 Citations: 53
Enhancement of the Desorption Properties of LiAlH 4 by the Addition of LaCoO 3 N Sazelee, NA Ali, M Ismail, SU Rather, HS Bamufleh, H Alhumade, ... Materials 16 (11), 4056 , 2023 2023 Citations: 4
Reinforce the dehydrogenation process of LiAlH4 by accumulating porous activated carbon NSC Mazlan, MFAAH Yap, M Ismail, MS Yahya, NA Ali, N Sazelee, ... International Journal of Hydrogen Energy 48 (43), 16381-16391 , 2023 2023 Citations: 25
Boosting the Dehydrogenation Properties of LiAlH 4 by Addition of TiSiO 4 NY Yusnizam, NA Ali, N Sazelee, M Ismail Materials 16 (6), 2178 , 2023 2023 Citations: 10
Enhanced hydrogen storage properties of NaAlH4 with the addition of CoTiO3 synthesised via a solid-state method NA Ali, M Ismail, MM Nasef, AA Jalil Journal of Alloys and Compounds 934, 167932 , 2023 2023 Citations: 28
MOST CITED SCHOLAR PUBLICATIONS
The effect of K2SiF6 on the MgH2 hydrogen storage properties M Ismail, MS Yahya, NA Sazelee, NA Ali, FAH Yap, NS Mustafa Journal of Magnesium and Alloys 8 (3), 832-840 , 2020 2020 Citations: 156
Advanced hydrogen storage of the Mg–Na–Al system: A review NA Ali, M Ismail Journal of Magnesium and Alloys , 2021 2021 Citations: 144
An overview of reactive hydride composite (RHC) for solid-state hydrogen storage materials NA Ali, NA Sazelee, M Ismail International Journal of Hydrogen Energy 46 (62), 31674-31698 , 2021 2021 Citations: 141
Modification of NaAlH4 properties using catalysts for solid-state hydrogen storage: A review NA Ali, M Ismail International Journal of Hydrogen Energy 46 (1), 766-782 , 2021 2021 Citations: 127
The hydrogen storage properties and catalytic mechanism of the CuFe2O4-doped MgH2 composite system M Ismail, NS Mustafa, NA Ali, NA Sazelee, MS Yahya International Journal of Hydrogen Energy 44 (1), 318-324 , 2019 2019 Citations: 120
Nanoflakes MgNiO2 synthesised via a simple hydrothermal method and its catalytic roles on the hydrogen sorption performance of MgH2 NA Ali, NH Idris, MFM Din, MS Yahya, M Ismail Journal of Alloys and Compounds 796, 279-286 , 2019 2019 Citations: 110
LaFeO3 synthesised by solid-state method for enhanced sorption properties of MgH2 NA Sazelee, NH Idris, MFM Din, MS Yahya, NA Ali, M Ismail Results in Physics 16, 102844 , 2020 2020 Citations: 104
Synthesis of BaFe12O19 by solid state method and its effect on hydrogen storage properties of MgH2 NA Sazelee, NH Idris, MFM Din, NS Mustafa, NA Ali, MS Yahya, FAH Yap, ... International Journal of Hydrogen Energy 43 (45), 20853-20860 , 2018 2018 Citations: 103
Influence of Nanosized CoTiO 3 Synthesized via a Solid-State Method on the Hydrogen Storage Behavior of MgH 2 NA Ali, MS Yahya, N Sazelee, MFM Din, M Ismail Nanomaterials 12 (17), 3043 , 2022 2022 Citations: 73
Nanolayer-like-shaped MgFe2O4 synthesised via a simple hydrothermal method and its catalytic effect on the hydrogen storage properties of MgH 2 NA Ali, NH Idris, MFM Din, NS Mustafa, NA Sazelee, FAH Yap, ... RSC advances 8 (28), 15667-15674 , 2018 2018 Citations: 71
Enhancing hydrogen storage performance of MgH2 through the addition of BaMnO3 synthesized via solid-state method NA Sazelee, NA Ali, MS Yahya, MFM Din, M Ismail International Journal of Hydrogen Energy 48 (79), 30844-30857 , 2023 2023 Citations: 54
Ameliorating the re/dehydrogenation behaviour of MgH2 by zinc titanate addition NA Ali, NA Sazelee, MFM Din, MM Nasef, AA Jalil, H Liu, M Ismail Journal of Magnesium and Alloys 11 (6), 2205-2215 , 2023 2023 Citations: 53
Boosting the de-/rehydrogenation properties of MgH2 with the addition of BaCoF4 NY Yusnizam, NA Ali, NA Sazelee, MM Nasef, AA Jalil, M Ismail Journal of Alloys and Compounds 967, 171618 , 2023 2023 Citations: 43
Enhancement of dehydrogenation properties in LiAlH4 catalysed by BaFe12O19 NA Sazelee, MS Yahya, NA Ali, NH Idris, M Ismail Journal of Alloys and Compounds 835, 155183 , 2020 2020 Citations: 43
Catalytic effect of SrTiO3 on the dehydrogenation properties of LiAlH4 M Ismail, NA Sazelee, NA Ali, S Suwarno Journal of Alloys and Compounds 855, 157475 , 2021 2021 Citations: 34
Catalytic effects of MgFe2O4 addition on the dehydrogenation properties of LiAlH4 NA Ali, NH Idris, NA Sazelee, MS Yahya, FAH Yap, M Ismail International Journal of Hydrogen Energy 44 (52), 28227-28234 , 2019 2019 Citations: 33
Dehydrogenation Properties and Catalytic Mechanism of the K 2 NiF 6 -Doped NaAlH 4 System NS Mustafa, MS Yahya, N Sazelee, NA Ali, M Ismail ACS omega 3 (12), 17100-17107 , 2018 2018 Citations: 33
Enhancing the dehydrogenation properties of LiAlH4 using K2NiF6 as additive MAN Ahmad, NA Sazelee, NA Ali, M Ismail International Journal of Hydrogen Energy 47 (59), 24843-24851 , 2022 2022 Citations: 31
An Overview of the Recent Advances of Additive-Improved Mg(BH 4 ) 2 for Solid-State Hydrogen Storage Material MAN Ahmad, N Sazelee, NA Ali, M Ismail Energies 15 (3), 862 , 2022 2022 Citations: 30
Effect of K2NbF7 on the hydrogen release behaviour of NaAlH4 NH Idris, ASK Anuar, NA Ali, M Ismail Journal of Alloys and Compounds 851, 156686 , 2021 2021 Citations: 29