Synthesis and structural elucidation of a trifluoromethylated cyclopentene hydrazone: a combined X-ray and computational study Elizaveta V. Panova, Bakhtiyor Sh. Ganiev, Kuvondik G. Avezov, Bako B. Umarov, Julia K. Voronina, et al. New Journal of Chemistry, 2026 We report on benzoylhydrazo-2-trifluoroacetylcyclopent-1-ene ( 1 ), which structural and electronic properties were studied, and a prediction was made regarding its potential activity against hemoglobin S, which is a key protein in sickle cell anemia.
SYNTHESIS AND STUDY OF AN ADHESIVE COMPOSITION BASED ON OXALIC ACID, FORMALDEHYDE AND PHTHALIMIDE USING IR, UV SPECTROSCOPY AND DFT CALCULATIONS Sayfulla I. Nazarov, Bakhtiyor Sh. Ganiev, Dana S. Belgibayeva, Muzafar S. Sharipov, Khasan K. Razzokov, et al. Journal of Chemistry and Technologies, 2026 Developing environmentally friendly and highly effective adhesive compositions is a pressing challenge in modern materials science. This study synthesized and comprehensively characterized a new adhesive based on oxalic acid, formaldehyde, and phthalimide. These compounds were chosen as starting materials due to their expected adhesive properties and relative environmental friendliness. The resulting sample was analyzed using infrared (IR) and ultraviolet-visible (UV-Vis) spectroscopy to identify characteristic functional groups and intermolecular interactions. Additionally, a quantum-chemical analysis using density functional theory (DFT) was performed to evaluate the electronic structure, chemical bonding characteristics, and molecular stability. IR spectroscopy confirmed the presence of absorption bands corresponding to esterification and amide bonds, while UV-Vis spectroscopy data indicated the formation of conjugated systems that provide structural strength. Theoretical calculations are consistent with experimental observations and confirm the favorable electronic properties of the molecule. A combined experimental and theoretical approach provided a comprehensive understanding of the molecular architecture and potential adhesive properties. Thus, the adhesive based on oxalic acid, formaldehyde, and phthalimide exhibits good adhesion strength and is environmentally friendly to synthesize, making it promising for a wide range of industrial and sustainable applications.
FLAME-RETARDANT BEHAVIOR OF UREA–METAPHOSPHORIC ACID COMPLEXES ON CELLULOSE-BASED MATERIALS Gulyayra K. Kholikova, Uktam M. Mardonov, Bakhtiyor Sh. Ganiyev, Dilshoda A. Khazratova, Sevda H. Aliyeva, et al. Journal of Chemistry and Technologies, 2025 In this study, novel urea metaphosphate complexes were synthesized at 1:1, 1:2, and 1:3 molar ratios using urea and metaphosphoric acid to obtain mono-, di-, and trimetaphosphate derivatives (UMP, UDP, and UTP). The synthesized compounds were comprehensively characterized through FTIR spectroscopy, powder X-ray diffraction (XRD), and elemental analysis, confirming their structural frameworks, protonation levels, and compositional features. Crystallographic analysis revealed distinct variations in unit-cell symmetry and packing as the phosphate chain length increased, indicating the formation of progressively more complex hydrogen-bonding networks. The flame-retardant performance of the complexes was examined using treated cellulose-based substrates, including paper, cardboard, and cotton fabric, in accordance with GOST R 50810-95 and GOST 12.1.004-91 standards. Experimental results demonstrated a clear enhancement in flame-retardant efficiency with increasing phosphate content, with UTP exhibiting the highest thermal stability and char-forming capability. Overall, the findings highlight the potential of urea metaphosphate complexes as multifunctional materials with promising applications in both agrochemistry and fire-protection technologies.
Synthesis, Spectroscopic Characterization and DFT Analysis of Schiff Bases Derived from Benzalacetone and Benzalacetophenone with Alanine Sardor Karomatov, Bakhtiyor Ganiyev, Zarnigor Aymatova, Xanifa Xaydarova, Fotima Xodjayeva E3s Web of Conferences, 2025 This comprehensive study investigates the synthesis, characterization, and potential biological activities of novel Schiff bases derived from the condensation reactions of benzalacetone and benzalacetophenone with alanine. The compounds were synthesized via condensation reactions between the respective carbonyl compounds and alanine, yielding stable inline derivatives. The structures of the synthesized Schiff bases were confirmed using proton nuclear magnetic resonance (1H NMR). carbon-13 nuclear magnetic resonance (13C NMR). and infrared (IR) spectroscopy. The IR spectra revealed characteristic inline (C=N) stretching vibrations, indicating successful Schiff base formation. DFT (Density Functional Theory) calculations were performed at the B3LYP/6-31 lG(d.p) level to optimize the molecular geometries and to compute vibrational frequencies, which were found to be in good agreement with experimental data. Additionally, frontier molecular orbital (HOMO-LUMO) analysis was earned out to assess the electronic properties and chemical reactivity of the compounds. The results contribute to a deeper understanding of the structural and electronic characteristics of amino acid-derived Schiff bases, highlighting their potential for applications in coordination chemistry and materials science.
Chemical Composition and In Silico Study of the Biological Activities of Alkaloids from Peganum harmala Gulbakhor Khudoynazarova, Zulfiya Kodirova, Bakhtiyor Ganiev, Sherali Jalilov, Rakhmonova Mavluda E3s Web of Conferences, 2025 Peganum harmala is employed extensively in ethnopharmacology but little literature has been done on the bioactive alkaloids of this plant. This paper gives an experimental finding on the chemical composition of P. harmala. It analyzes by quantum-chemical and in silico the biological characteristics of its primary alkaloids, peganine and deoxypyganine. The analysis of the samples by HPLC at various stages of growth showed that the quantity of peganine peaks at the stage when the branching occurs (up to 83% in the sample on May 14, 2023). DFT results indicated that the two alkaloids have good electronic behavior and peganine has high index of electrophilicity and high electron affinity. The active sites were determined by molecular electrostatic potential (MEP) mapping, whereas system-level activity was proved by density of states (DOS) spectra. Molecular docking of human 6s5a protein showed that peganine and deoxypeganine bind with an affinity of -7.59 kcal/mol as well as -8.13 kcal/mol. respectively, which are strong molecular affinities. These findings indicate that the alkaloid of P. harmala especially peganine has promising pharmacological activities that should be further confirmed in the context of in vitro and in vivo experiments.
Novel [5-Hdroxy-3-phenyl-5-(trifluoromethyl)-4, 5-dihydro-1H-pyrazol-1-yl](phenyl) methanone: Synthesis, Characterization and Computational Analysis NQQ Savriyeva, MA Tursunov, B Shukrulloyevich Advanced Journal of Chemistry, Section A 9 (2), 192-207 , 2026 2026 Citations: 3
FLAME-RETARDANT BEHAVIOR OF UREA–METAPHOSPHORIC ACID COMPLEXES ON CELLULOSE-BASED MATERIALS GK Kholikova, UM Mardonov, BS Ganiyev, DA Khazratova, SH Aliyeva, ... Journal of Chemistry and Technologies 33 (4), 1136-1148 , 2025 2025
rac-Diethyl-4-methyl-2-phenyl-6-(2-carbamothioylhydrazineylidene) cyclohex-4-en-1, 3-dicarboxylate: Synthesis, characterization and computational studies EV Panova, BS Ganiev, NG Sevinchov, BB Umarov, JK Voronina, ... Journal of Molecular Structure, 144668 , 2025 2025
DEVELOPMENT AND PERFORMANCE ANALYSIS OF BIOPOLYMER-BASED FLOCCULANTS FOR SUSTAINABLE WASTEWATER TREATMENT. MM Amonova, MR Amonov, BS Ganiev Rasayan Journal of Chemistry 18 (4) , 2025 2025
Synthesis, Spectroscopic Characterization and Theoretical Investigation of Biuret-Metaphosphate Molecular Complexes: A Combined Experimental and DFT Study KG Kuldoshevna, MU Mardonovich, GB Shukurulloyevich ORIENTAL JOURNAL OF MEDICINE AND NATURAL SCIENCES 2 (4), 34-45 , 2025 2025
Synthesis and study of phsysico-chemical properties of oligo (poly)-mer sorbents based on urotropine and cyanuric acid BS Ganiyev, DK Sayfillayeva, MS Sharipov, BG Ramazanov Journal of Chemistry and Technologies 33 (2), 391-400 , 2025 2025 Citations: 3
PASS И ADME АНАЛИЗ БИС (N-САЛИЦИЛИДЕН-4, 4-ДИФЕНИЛАМИН) БШ ГАНИЕВ, АА АМРИЛЛОЕВ Москва 21, 24 , 2025 2025
Synergetic method of organizing classes for foreign students of non-chemical specialties VS Nazarova, SS Kosmodemyanskaya, BS Ganiev Bulletin of Pedagogical Sciences, 218-225 , 2025 2025
Synthesis, characterization and computational studies of the triangle shape complex of silver nitrate with 2-amino-1, 3, 4-thiadiazole KS Husenov, BB Umarov, KK Turgunov, SS Sharipov, BS Ganiev, ... Polyhedron 267, 117259 , 2025 2025 Citations: 8
ESR SPECTROSCOPIC STUDIES OF HOMOAND HETEROLIGAND COMPLEXES OF COPPER (II) AND OXOVANADIUM (IV) WITH GLUTAMINE BS Ganiyev, UM Mardonov, GK Kholikova, JM Ashurov Azerbaijan Chemical Journal, 126-140 , 2025 2025
Chemical Composition and In Silico Study of the Biological Activities of Alkaloids from Peganum harmala G Khudoynazarova, Z Kodirova, B Ganiev, S Jalilov, R Mavluda E3S Web of Conferences 661, 05003 , 2025 2025
Synthesis, Spectroscopic Characterization and DFT Analysis of Schiff Bases Derived from Benzalacetone and Benzalacetophenone with Alanine S Karomatov, B Ganiyev, Z Aymatova, X Xaydarova, F Xodjayeva E3S Web of Conferences 661, 05004 , 2025 2025
SPECTROSCOPIC INVESTIGATION OF THE Cu (II) HETEROLIGAND COMPLEXES WITH 2, 4-DIHYDROXYBENZOIC ACID M Nigora, A Kuvondik, G Bakhtiyor Universum: химия и биология 3 (7 (133)), 29-34 , 2025 2025
Спектроскопическое (ИК-и ЯМР), DFT, предсказание PASS, ADMET и молекулярное докинг-исследование тиосемикарбазонов монокарбонилов KG Avezov, BS Ganiev, GK Kholikova, MO Tukhtaeva BULLETIN of the LN Gumilyov Eurasian National University. Chemistry … , 2024 2024 Citations: 1
PEGANUM HARMALA O’SIMLIGI TARKIBIDAGI ALKALOIDLAR VA VA PEGANIN MOLEKULYAR DOKINGI GB Shukurulloyevich Научный Фокус 2 (19), 762-779 , 2024 2024
Synthesis, Characterization, and Computational Studies of the Zinc Bromide Complex with 2-Amino-1, 3, 4-thiadiazole KS Husenov, BB Umarov, KK Turgunov, BS Ganiev, UM Mardonov, ... Russian Journal of Inorganic Chemistry 69 (8), 1173-1183 , 2024 2024 Citations: 2
Жол жабынының құрылымдық қабаттарында жүн және мұнай қалдықтарын геотордың толтырғышы ретінде пайдалану (шолу) TT Mashan, OM Zholymbaev, NB Kazangapova, DR Ontagarova, ... BULLETIN of the LN Gumilyov Eurasian National University. Chemistry … , 2024 2024
L-Leysin Aminokislotasining Kimyoviy Xossalari Va Kvant-Kimyoviy Hisoblashlari GB Shukurulloyevich, XG Qoldoshevna, SS Nasimovich, JS Tolibjon o‘g‘li Journal of Innovation in Education and Social Research 2 (1), 92-96 , 2024 2024
Анализ результатов изучения антипиреновые эффективности продуктов кислотной переработки образцов НСФ Z Rakhmatov ЦЕНТР НАУЧНЫХ ПУБЛИКАЦИЙ (buxdu. uz) 45 (45) , 2024 2024
MOST CITED SCHOLAR PUBLICATIONS
Molecular structure, HOMO-LUMO, MEP-–Analysis of triazine compounds using DFT (B3LYP) calculations B Ganiev, U Mardonov, G Kholikova Materials Today: Proceedings , 2023 2023 Citations: 46
Viscosity characteristics compositions based on PAA, PVS and NA-CMS M Amonov, S Shodiyeva, R Ismatova, B Ganiev E3S Web of Conferences 389, 01021 , 2023 2023 Citations: 16
Thickening the polymer composition for printing on cotton fabric MR Amonov, FB Ibragimova, MM Amonova, AK Niyozov, BS Ganiev Izvestiya Vysshikh Uchebnykh Zavedenii, Seriya Teknologiya Tekstil'noi … , 2023 2023 Citations: 13
Physical and chemical properties of yarn sized with a composition based on starch, PVA and HYPAN M Amonov, R Ismatova, O Nurova, S Shodieva, B Ganiev E3S Web of Conferences 389, 01018 , 2023 2023 Citations: 13
Chemical and thermal Properties Properties of compositions based on PAA, PVA and Na-CMS for printing flowers on silk fiber fabrics M Amonov, S Shodiyeva, E Niyozov, R Ismatova, B Ganiev, N Ochilova E3S Web of Conferences 389, 01019 , 2023 2023 Citations: 13
Study of chemical properties combination chemical method of wastewater treatment by methods IR-spectroscopy and X-ray diffraction MR Amonov, ED Niyozov, MM Amonova, SI Nazarov, BS Ganiev E3S Web of Conferences 389, 01020 , 2023 2023 Citations: 12
Physico-chemical properties of calendula flower extract in bitter almond oil elemental composition and microbiological purity OJ Khamidov, HM Vapayev, SI Nazarov, S Boltaeva, BS Ganiyev E3S Web of Conferences 389, 03008 , 2023 2023 Citations: 11
Calculations of quantum chemical parameters of the compound of isocyanuric acid with semicarbazide B Ganiyev, F Ostonov, G Kholikova, F Salimv International independent scientific journal 2 (16), 3-9 , 2020 2020 Citations: 11
Synthesis and study of the agrochemical properties of urea salts with nitric and orthophosphoric acid UM Mardonov, GK Kholikova, BS Ganiev, IN Tursunova, ST Khozhiev E3S Web of Conferences 389, 03005 , 2023 2023 Citations: 10
The importance of applying “Multi-Intelligence Theory” to the educational process AG Ganiev, SA Ganieva, GB Bahodirova The American Journal of Applied Sciences 3 (03), 93-103 , 2021 2021 Citations: 10
Investigation of thermal properties and composition on basalts of the Aydarkul deposit by methods DTA/DTG and X-ray diffraction S Nazarov, K Razzokov, G Shirinov, E Niyozov, R Rashidova, M Rasulov, ... E3S Web of Conferences 389, 01023 , 2023 2023 Citations: 9
Синтез и исследование биядерных комплексов ванадила (II) на основе бис-5-оксипиразолинов СФ Абдурахмонов, БШ Ганиев, ЭА Худоярова, ГК Холикова, ... Universum: химия и биология, 50-55 , 2019 2019 Citations: 9
Synthesis, characterization and computational studies of the triangle shape complex of silver nitrate with 2-amino-1, 3, 4-thiadiazole KS Husenov, BB Umarov, KK Turgunov, SS Sharipov, BS Ganiev, ... Polyhedron 267, 117259 , 2025 2025 Citations: 8
Синтез и исследование методами ИК-спектроскопии и квантовой химии-6-((2, 4-динитрофенил) гидразон-1, 3, 5-триазинан-2, 4-диона БШ Ганиев, ГК Холикова, ФГУ Салимов Universum: химия и биология, 68-73 , 2020 2020 Citations: 8
Использование циануровой кислоты в качестве дезинфицирующих средств для окружающей среды БШ Ганиев, ГК Холикова, ФГ Салимов Материалы международной научной конференции «Инновационные решения инженерно … , 2019 2019 Citations: 8
Synthesis and study sorption properties oligo (poly)-mer sorbents based on urea-formaldehyde and cyanuric acid A Amrullaev, S Boltaeva, S Rashitova, B Ganiev BIO Web of Conferences 130, 06004 , 2024 2024 Citations: 7
Использование программы CHEMSKETCH в процессе изучения органической химии для повышения успеваемости учащихся БШ Ганиев, ГК Холикова, ГГ Садуллаева, ФГУ Салимов, ФС Аслонова Universum: психология и образование, 14-17 , 2021 2021 Citations: 7
Синтез, строения, таутомрия и исследование некоторых квантово-химических параметров соединения 2-(4, 6-диоксо-1, 3, 5-триазинан-2-илиден) гидразинкарбоксиамида БШ Ганиев, ББ Умаров, ГК Холикова, ФГУ Салимов, ФС Аслонова Евразийский Союз Ученых, 65-68 , 2020 2020 Citations: 7
