Impact of deep eutectic solvents on cetyltrimethylammonium bromide: a comparative study Benvikram Barman, Manoj Kumar Banjare, Bhupendra Singh Banjare, Dolly Baghel, Dinesh Tandon, Amit Kumar Chaturwedi Journal of Dispersion Science and Technology, 2026 Study the micellization characteristics of cetyltrimethylammonium bromide (CTAB) in three deep eutectic solvents (DESs)—L-tyrosine (DES-1), L-glutamine (DES-2), and L-aspartic acid (DES-3)—by using surface tension, viscosity, fluorescence UV–vis spectrophotometry, and FTIR spectroscopy. Prepared DESs are made by mixing choline chloride with three different amino acids in 1:2 M. Study the DESs Effect on the critical micellar concentration (CMC) of CTAB. When increasing the weight percentage of DESs, the CMC value of the CTAB falls. Calculate the CMC and interfacial parameters such as surface tension at CMC (γcmc), the minimum area per molecule (Amin), the minimum surface activity (πcmc), the efficiency of adsorption (PC20), critical packing parameter (CPP), and the maximum surface excess concentration (Γmax). A decrease in the Γmax and Amin and an increase in the micellization systems when the weight present of amino acid-based DESs increases. FTIR spectroscopy was used to examine the self-assembly interactions between the DESs and surfactant (DESs:CTAB) that led to modifications in their structure and function. Furthermore, it is important to note that the micellization process for three AAs based on DESs with CTAB in the following order (with 5 wt% DESs) DES-3 > DES-2 > DES-1 and (with 10 wt% DESs) DES-3 > DES-1 > DES-2. Besides surface tension investigations, micellization of CTAB with the three amino acid-based DESs was also validated using fluorescence and UV–vis spectrophotometry, which indicated a consistent decrease in CMC with an increase in DES concentration. The measurements of viscosity showed that there was an increase in structural arrangement and intermolecular interactions in the CTAB:DES systems, which led to the improvement of the micelle formation. Combined, these methods show that DESs greatly support the process of micellization and alter the physicochemical behavior of CTAB.
Influence of Organic Solvents on the Micellization Behavior of Conventional Surfactants: A Comparative Study by Spectroscopic Methods Dolly Baghel, Manoj Kumar Banjare, Bhupendra Singh Banjare, Kamalakanta Behera, Benvikram Barman, Malik Abdul Rub, Kallol Kumar Ghosh Journal of Surfactants and Detergents, 2026 Influence of organic solvents, such as nitrobenzene, chlorobenzene, and aniline, on the micellization behavior of two conventional surfactants, that is, sodium dodecyl sulfate (SDS) and Triton X‐100 (TX100), was investigated using stalagmometry, viscosity, colorimetry, and FTIR spectroscopy. Several surface adsorption parameters, that is, the maximum surface excess concentration (Γ max ), the minimum area per molecule ( A min ), the surface pressure at CMC ( π CMC ), and the efficiency of adsorption (pC 20 ), including the CMC, were determined through stalagmometry. The results demonstrated significant alterations in CMC and γ CMC values upon the introduction of different v/v percentages of organic solvents, following this order of decrease: water > 30 v/v% > 70 v/v% for nitrobenzene, chlorobenzene, and aniline. A min values decreased with increasing v/v% of organic solvent for TX100 but increased for SDS. Additionally, pC 20 was observed to be higher for TX100 compared to SDS, indicating greater efficiency of TX100 in reducing CMC. The relative viscosity of the surfactants and organic solvents was determined using the viscosity method, and the CMC values for all the systems were confirmed through colorimetry. FTIR spectroscopy was employed to identify the functional groups involved in the complexation between nitrobenzene, chlorobenzene, aniline, and surfactants. The current agreements will incorporate pharmaceutical sciences, cosmetics, medicinal delivery, and household goods.
Physicochemical insight of phosphonium-based ionic liquid with carbocyclic sugar-based inositol derivative Bhupendra Singh Banjare, Manoj Kumar Banjare, Nitai Sarkar, Kamalakanta Behera, Dolly Baghel, Benvikram Barman, Swati Chandrawanshi, Roman Kumar Aneshwari, Indrapal Karbhal, Manmohan Lal Satnami, Kallol Kumar Ghosh Cleaner Chemical Engineering, 2025 Ionic liquids (ILs) are widely utilized as solubilizers, transporters, and agents for enhancing the efficacy of various components. In this study, the phosphonium-based ionic liquid (PIL) trihexyltetradecylphosphonium bis(2,4,4-trimethylpentyl)phosphinate ([P666(14)][TMPP]) was investigated for its synergic interaction with synthesized carbocyclic sugar-based inositol derivative 4-O-Tosyl-6-O-benzyl- myo -inositol-1,3,5-orthoformate (referred to as the tosyl derivative). These interactions were explored using a range of techniques including FTIR spectroscopy, dynamic light scattering (DLS), surface tension, conductivity, colorimetry, and viscometry at 299.0±0.5 K temperature. Key parameters in physicochemical insight, such as the zeta potential, particle size distribution, critical micelle concentrations (CMC) and various thermodynamic parameters (ΔG ° ads , ΔG ° trans , ∆G s min , ΔG ° m , ΔG ° m,tail ) and interfacial parameters (Г max , A min , π CMC , pC 20 , γ CMC ) were calculated. A significant reduction in CMC values of the PIL was observed with increasing concentrations (mM) of the tosyl derivative. The findings of the interfacial parameters indicated that when the concentration of tosyl derivative increased, the values of A min , π CMC , and pC 20 enhanced while the values of γ CMC , Γ max , and CPP undergo reduction. Further, conductometric and colorimetric studies give similar results for CMC value. The higher negative values of ΔG ° m and ΔG ° ads have been shown the micellization and adsorption properties became more spontaneous. The rheological characteristics of PIL, such as reducing, intrinsic, and relative viscosities, are more significantly impacted by higher concentrations of the tosyl derivative. The FTIR spectral response confirmed shifts in different stretching and bending modes indicating strong intermolecular interactions. DLS data further indicated that the polar nature of the tosyl derivative promotes the formation of significantly larger micelles in the PIL–tosyl derivative system (particularly at 2.0 mM) compared to the pure due to the tosyl derivative showing co-solvent character. These findings suggest potential applications for such synergistic systems in household products, pharmaceutical sciences, cosmetics, and drug delivery.
Synergic Interaction of a Phosphonium-Based Ionic Liquid with a Synthesized Carbocyclic Sugar-Based Inositol Derivative Bhupendra Singh Banjare, Manoj Kumar Banjare, Nitai Sarkar, Kamalakanta Behera, Dolly Baghel, Benvikram Barman, Dinesh Tandon, Indrapal Karbhal, Manmohan Lal Satnami, Kallol Kumar Ghosh Chemistryselect, 2025 Ionic liquids (ILs) have several applications, such as solubilizers, transporters, and enhancing component efficacy. The phosphonium‐based ionic liquid (IL), i.e., trihexyltetradecylphosphonium bis(2,4,4‐trimethylpentyl)phosphinate ([P666(14)][TMPP]), might be affected by synergic interaction with synthesized carbocyclic sugar‐based inositol derivative, i.e., 1,2‐cis‐ketal,1,4‐dibenzoyl‐myo‐inositol (cis‐ketal), were investigated with dynamic light scattering (DLS), surface tension, FTIR, conductivity, colorimetry, and viscometry at 299.0 ± 0.5 K temperature. The zeta potential, particle size distribution, critical micelle concentrations (CMC), and various thermodynamic parameters, viz., ΔG°ads, ΔG°trans, ∆Gsmin, ΔG°m, ΔG°m, tail and interfacial parameters, i.e., Гmax, Amin, πCMC, pC20, and γCMC, have been calculated. A substantial drop in IL CMC values was observed at various cis‐ketal concentrations (mM), and their conformational study was conducted by conductometric and colorimetric techniques. For IL‐cis‐ketal systems, rheological behavior based on reduced, intrinsic, and relative viscosity was computed. Self‐aggregation of IL with cis‐ketal was affected by electrostatic, hydrophilic, and hydrophobic interactions. The IL with cis‐ketal shows various types of stretching and bending frequencies that were characterized by the FTIR method. The DLS data displayed that the IL with 2.0 mM cis‐ketal system has generated significantly larger micelles than pure IL due to the polar character of cis‐ketal. The current investigation can find potential applications in pharmaceutical sciences, cosmetics, medicinal delivery, etc.
Effect of L-tyrosine on the micellar characteristics of various surfactants: a comparative study of the amino acid–surfactant interactions Manoj Kumar Banjare, Dinesh Kumar Tandon, Kamalakanta Behera, Bhupendra Singh Banjare, Indrapal Karbhal, Malik Abdul Rub, Manmohan L. Satnami, Kallol Kumar Ghosh Journal of Dispersion Science and Technology, 2025 In the present study, the aggregation process of three surfactants i.e., sodium dodecyl sulfate (SDS), Triton X-100 (TX-100), and cetyltrimethylammonium bromide (CTAB) with and without L-tyrosine (L-Tyr) has been investigated using viscosity, fluorescence, surface tension, UV–vis spectroscopy, dynamic light scattering (DLS), and FTIR methods at a temperature of 298 K. Different physio-chemical parameters, such as, critical micelles concentration (CMC), Γmax, γCMC, πCMC, pC20 and Amin are computed and discussed thoroughly. Using a surface tensiometer, the surface characteristics and interfacial parameters of the surfactant systems in presence and absence of the L-Tyr amino acid (AA) are investigated. Measurements of the CMC using stalagmometric, fluorescence, and UV–visible spectrophotometry reveal the same pattern with differences in the following order: SDS > TX-100 > CTAB. Relative viscosity-based rheological behavior was calculated for three surfactant-L-Tyr systems. FTIR spectral analysis was done to reveal the micellization behavior of CTAB, SDS, TX-100, and L-Tyr systems. The FTIR data showed that the CTAB-L-Tyr and SDS- L-Tyr systems have significantly influenced the stretching frequency as compared to the TX-100-L-Tyr system. Pure surfactants average radius has demonstrated a bimodal distribution were observed and adding on 0.02 M of L-Tyr following the size shift, a polymodal distribution was observed in all surfactant systems. The effect of AA additions on the colloidal size and stability of surfactant aggregates was also examined.
Influence of Amino Acid-Based Deep Eutectic Solvents on the Micellization Behavior of Triton X-100: A Comparative Spectroscopic Study B Barman, MK Banjare, BS Banjare, D Baghel Journal of the Indian Chemical Society, 102463 , 2026 2026.0
Impact of deep eutectic solvents on cetyltrimethylammonium bromide: a comparative study B Barman, MK Banjare, BS Banjare, D Baghel, D Tandon, AK Chaturwedi Journal of Dispersion Science and Technology, 1-15 , 2026 2026.0
Influence of Organic Solvents on the Micellization Behavior of Conventional Surfactants: A Comparative Study by Spectroscopic Methods D Baghel, MK Banjare, BS Banjare, K Behera, B Barman, MA Rub, ... Journal of Surfactants and Detergents , 2026 2026.0
Physicochemical insight of phosphonium-based ionic liquid with carbocyclic sugar-based inositol derivative BS Banjare, MK Banjare, N Sarkar, K Behera, D Baghel, B Barman, ... Cleaner Chemical Engineering 11, 100179 , 2025 2025.0 Citations: 3
Textbook of Basic Analytical Chemistry Discipline Specific Elective (DSE) Based on Syllabus of NEP 2020 BS Banjare, B Barman, S Chandrawanshi, T Yadav Chyren Publication , 2025 2025.0 Citations: 1
Synergic Interaction of a Phosphonium‐Based Ionic Liquid with a Synthesized Carbocyclic Sugar‐Based Inositol Derivative BS Banjare, MK Banjare, N Sarkar, K Behera, D Baghel, B Barman, ... ChemistrySelect 10 (37), e01819 , 2025 2025.0
Environmental Chemistry (Volume-I): DSE, Based on Syllabus of NEP-2020 B Barman, BS Banjare, DK Sahu, S Chandrawanshi, S Ramteke, ... Shashwat Publication , 2025 2025.0
Chemistry in Daily Life: Value Added Course Based on Syllabus of NEP-2020 B Barman, BS Banjare, D Baghel, DK Tandan, MN kumar Verma, ... Shashwat Publication , 2025 2025.0
Deep Eutectic Solvents in Green Chemistry: A Review B Barman, MK Banjare, BS Banjare, D Baghel Journal of Ravishankar University 38 (1), 90-128 , 2025 2025.0 Citations: 7
Effect of L-tyrosine on the micellar characteristics of various surfactants: a comparative study of the amino acid–surfactant interactions MK Banjare, DK Tandon, K Behera, BS Banjare, I Karbhal, MA Rub, ... Journal of Dispersion Science and Technology, 1-14 , 2025 2025.0 Citations: 1
Micellar Characteristics Study of Ionic Liquids-Surfactants-Inositol System and Its Application MKB BS Banjare Department of Chemistry, MATS University Raipur, CG, IND , 2024 2024.0
SURFACTANTS CHALLENGES, METHODOLOGY AND ITS VERSATILE APPLICATION MKB BS Banjare SURFACTANTS CHALLENGES, METHODOLOGY AND ITS VERSATILE APPLICATION 3, 125-154 , 2024 2024.0 Citations: 4
EXPLORING THE SYNERGY OF IONIC LIQUIDS AND INOSITOL: A CHAPTER ON NOVEL APPLICATIONS AND MOLECULAR INTERACTIONS BS Banjare, MK Banjare EXPLORING THE SYNERGY OF IONIC LIQUIDS AND INOSITOL: A CHAPTER ON NOVEL … , 2024 2024.0 Citations: 3
Study of the molecular interaction of a phosphonium-based ionic liquid within myo-inositol and non-steroidal anti-inflammatory drugs MK Banjare, BS Banjare RSC advances 14 (5), 2961-2974 , 2024 2024.0 Citations: 11
Impact of carbocyclic sugar-based myo-inositol on conventional surfactants BS Banjare, MK Banjare Journal of Molecular Liquids 384, 122278 , 2023 2023.0 Citations: 17
Impact of E-resources on Higher education: A review MKB BS Banjare Impact of E-resources on Higher education: A review 1, 53-66 , 2023 2023.0
Need and Application of Technology in Modern Education System BSB BR Dhritlahare Need and Application of Technology in Modern Education System 1, 7-18 , 2023 2023.0
MEPTIC and machine learning approaches of corrosion inhibition BS Banjare, MK Banjare Computational Modelling and Simulations for Designing of Corrosion … , 2023 2023.0 Citations: 3
Cleaner Chemical Engineering BS Banjare, MK Banjare, N Sarkar, K Behera, D Baghel, B Barman, ...
MOST CITED SCHOLAR PUBLICATIONS
Impact of carbocyclic sugar-based myo-inositol on conventional surfactants BS Banjare, MK Banjare Journal of Molecular Liquids 384, 122278 , 2023 2023.0 Citations: 17
Study of the molecular interaction of a phosphonium-based ionic liquid within myo-inositol and non-steroidal anti-inflammatory drugs MK Banjare, BS Banjare RSC advances 14 (5), 2961-2974 , 2024 2024.0 Citations: 11
Deep Eutectic Solvents in Green Chemistry: A Review B Barman, MK Banjare, BS Banjare, D Baghel Journal of Ravishankar University 38 (1), 90-128 , 2025 2025.0 Citations: 7
SURFACTANTS CHALLENGES, METHODOLOGY AND ITS VERSATILE APPLICATION MKB BS Banjare SURFACTANTS CHALLENGES, METHODOLOGY AND ITS VERSATILE APPLICATION 3, 125-154 , 2024 2024.0 Citations: 4
Physicochemical insight of phosphonium-based ionic liquid with carbocyclic sugar-based inositol derivative BS Banjare, MK Banjare, N Sarkar, K Behera, D Baghel, B Barman, ... Cleaner Chemical Engineering 11, 100179 , 2025 2025.0 Citations: 3
EXPLORING THE SYNERGY OF IONIC LIQUIDS AND INOSITOL: A CHAPTER ON NOVEL APPLICATIONS AND MOLECULAR INTERACTIONS BS Banjare, MK Banjare EXPLORING THE SYNERGY OF IONIC LIQUIDS AND INOSITOL: A CHAPTER ON NOVEL … , 2024 2024.0 Citations: 3
MEPTIC and machine learning approaches of corrosion inhibition BS Banjare, MK Banjare Computational Modelling and Simulations for Designing of Corrosion … , 2023 2023.0 Citations: 3
Textbook of Basic Analytical Chemistry Discipline Specific Elective (DSE) Based on Syllabus of NEP 2020 BS Banjare, B Barman, S Chandrawanshi, T Yadav Chyren Publication , 2025 2025.0 Citations: 1
Effect of L-tyrosine on the micellar characteristics of various surfactants: a comparative study of the amino acid–surfactant interactions MK Banjare, DK Tandon, K Behera, BS Banjare, I Karbhal, MA Rub, ... Journal of Dispersion Science and Technology, 1-14 , 2025 2025.0 Citations: 1
Influence of Amino Acid-Based Deep Eutectic Solvents on the Micellization Behavior of Triton X-100: A Comparative Spectroscopic Study B Barman, MK Banjare, BS Banjare, D Baghel Journal of the Indian Chemical Society, 102463 , 2026 2026.0
Impact of deep eutectic solvents on cetyltrimethylammonium bromide: a comparative study B Barman, MK Banjare, BS Banjare, D Baghel, D Tandon, AK Chaturwedi Journal of Dispersion Science and Technology, 1-15 , 2026 2026.0
Influence of Organic Solvents on the Micellization Behavior of Conventional Surfactants: A Comparative Study by Spectroscopic Methods D Baghel, MK Banjare, BS Banjare, K Behera, B Barman, MA Rub, ... Journal of Surfactants and Detergents , 2026 2026.0
Synergic Interaction of a Phosphonium‐Based Ionic Liquid with a Synthesized Carbocyclic Sugar‐Based Inositol Derivative BS Banjare, MK Banjare, N Sarkar, K Behera, D Baghel, B Barman, ... ChemistrySelect 10 (37), e01819 , 2025 2025.0
Environmental Chemistry (Volume-I): DSE, Based on Syllabus of NEP-2020 B Barman, BS Banjare, DK Sahu, S Chandrawanshi, S Ramteke, ... Shashwat Publication , 2025 2025.0
Chemistry in Daily Life: Value Added Course Based on Syllabus of NEP-2020 B Barman, BS Banjare, D Baghel, DK Tandan, MN kumar Verma, ... Shashwat Publication , 2025 2025.0
Micellar Characteristics Study of Ionic Liquids-Surfactants-Inositol System and Its Application MKB BS Banjare Department of Chemistry, MATS University Raipur, CG, IND , 2024 2024.0
Impact of E-resources on Higher education: A review MKB BS Banjare Impact of E-resources on Higher education: A review 1, 53-66 , 2023 2023.0
Need and Application of Technology in Modern Education System BSB BR Dhritlahare Need and Application of Technology in Modern Education System 1, 7-18 , 2023 2023.0
Cleaner Chemical Engineering BS Banjare, MK Banjare, N Sarkar, K Behera, D Baghel, B Barman, ...