Surface Chemistry and Catalysis / "Ilie Murgulescu" Institute of Physical Chemistry of Romanian Academy "Ilie Murgulescu" Institute of Physical Chemistry of Romanian Academy
Mono-(Ni, Au) and Bimetallic (Ni-Au) Nanoparticles-Loaded ZnAlO Mixed Oxides as Sunlight-Driven Photocatalysts for Environmental Remediation Monica Pavel, Liubovi Cretu, Catalin Negrila, Daniela C. Culita, Anca Vasile, et al. Molecules, 2025 A facile and versatile strategy to obtain NPs@ZnAlO nanocomposite materials, comprising controlled-size nanoparticles (NPs) within a ZnAlO matrix is reported. The mono-(Au, Ni) and bimetallic (Ni-Au) NPs serving as an active phase were prepared by the polyol-alkaline method, while the ZnAlO support was obtained via the thermal decomposition of its corresponding layered double hydroxide (LDH) precursors. X-ray diffraction (XRD) patterns confirmed the successful fabrication of the nanocomposites, including the synthesis of the metallic NPs, the formation of LDH-like structure, and the subsequent transformation to ZnO phase upon LDH calcination. The obtained nanostructures confirmed the nanoplate-like morphology inherited from the original LDH precursors, which tended to aggregate after the addition of gold NPs. According to the UV-Vis spectroscopy, loading NPs onto the ZnAlO support enhanced the light absorption and reduced the band gap energy. ATR-DRIFT spectroscopy, H2-TPR measurements, and XPS analysis provided information about the functional groups, surface composition, and reducibility of the materials. The catalytic performance of the developed nanostructures was evaluated by the photodegradation of bisphenol A (BPA), under simulated solar irradiation. The conversion of BPA over the bimetallic Ni-Au@ZnAlO reached up to 95% after 180 min of irradiation, exceeding the monometallic Ni@ZnAlO and Au@ZnAlO catalysts. Its enhanced activity was correlated with good dispersion of the bimetals, narrower band gap, and efficient charge carrier separation of the photo-induced e−/h+ pairs.
The Effect of the Metal Oxide as the Support for Silver Nanoparticles on the Catalytic Activity for Ammonia Ozonation Razvan-Nicolae State, Maria-Alexandra Morosan, Liubovi Cretu, Alexandru-Ioan Straca, Anca Vasile, et al. Catalysts, 2025 Ammonia is one of the common inorganic pollutants in surface waters. It can come from a wide range of sources through the discharge of wastewater (industry, agriculture, and municipal waters). Catalytic ozonation reaction can efficiently remove ammonia nitrogen without introducing other pollutants and improve the nitrogen selectivity of reaction products by controlling the reaction conditions. Catalysts based on silver nanoparticles (Ag NPs) have shown excellent O3 decomposition performance; therefore, they are promising catalysts for catalytic ammonia ozonation due to their high reactivity, stability, and selectivity to N2. In this study, we synthesized well-defined silver nanoparticles (Ag NPs) using a modified alkaline polyol method and then dispersed them on solid oxide supports (Fe3O4, TiO2, and WO3). Before being deposited on the oxide support, the silver nanoparticles were characterized by X-ray diffraction (XRD), transmission electron microscopy (TEM), and UV-VIS spectroscopy. The obtained catalysts, Ag_Fe3O4, Ag_TiO2, and Ag_WO3 were characterized using X-ray diffraction (XRD), scanning electron microscopy (SEM), BET surface area analysis, UV-VIS spectroscopy, temperature-programmed reduction (H2-TPR), and temperature-programmed desorption (TPD) of CO2 and NH3. It has been demonstrated that the nature of the support significantly influences the physicochemical properties of the catalysts, as well as their catalytic performance in ammonia ozonation reaction.
Correlation of the Sr-dopant content in La1-XSrXCoO3 with catalytic activity for hydrogen peroxide decomposition Revue Roumaine De Chimie, 2018
Oxide powders from tartaric acid Mg/Zr coordination compounds with CO2 adsorption properties Revista Romana De Materiale Romanian Journal of Materials, 2018
Enhanced photocatalytic activity of ZnO nanoparticles obtained by “green” synthesis with well dispersed Pd-Au bimetallic nanoparticles Revue Roumaine De Chimie, 2018
Impact of RbLaTa2O7 layered perovskite synthesis conditions on their activity for photocatalytic abatement of trichloroethylene Revue Roumaine De Chimie, 2018
Thermosensitive triblock copolymer templated synthesis of Pt-Cu supported on TiO2: Investigation of their catalytic activity for CO oxidation reaction Revue Roumaine De Chimie, 2018
Synthesis and characterization of pvp (Polyvinyl pyrrolidone) stabilized gold nanoparticles Revista Romana De Materiale Romanian Journal of Materials, 2015