INVESTIGATION OF ADSORPTION OF BENTONITE SAMPLES WITH IONOGENIC OLIGOMER BY PHYSICO-CHEMICAL METHODS N.A. Imanova, , F.M. Sadykhov, I.A. Zarbaliyeva, S.G. Mammadova, , , and Azerbaijan Chemical Journal, 2024 The adsorption process of natural and modified Co+2-, Ni+2-bentonite samples taken from Dash-Salahli field with ionogenic oligomer modifiers was carried out and studied by x-ray and infrared spectral analysis methods. Important components that ensure the stability of bentonite suspensions are polymers, ions and surfactants. The main goal of the work is to obtain an organic mineral sorbent using an ionogenic oligomer modifier to stabilize polymer-dispersed systems. The most suitable surfactants are substances with a hydrophilic and hydrophobic statistical distribution in the molecule. The prepared sorbent has both cationic and anionic properties and can adsorb various harmful organic substances. As a result of the research, certain changes were observed in the structure of the sorbents. Depending on the ionic radii of substituted metal ions in natural bentonite, weak, medium. strong intensities are observed
COMPARATIVE ANALYSIS OF NEW MONOMER AND GEMINI SURFACTANTS SYNTHESIZED ON THE BASIS OF DODECANOIC ACID AND ETHANE-1,2DIAMINE DEPENDING ON THEIR MOLAR RATIO Ilhama Zarbaliyeva, , Hajar Nabiyeva, Amina Alimova, Sevda Zargarova, , , and Chemical Problems, 2023 This article includes thorough information on the synthesis process and physicochemical properties of the products generated from the reaction of dodecanoic acid and ethane-1,2-diamine IR spectroscopy was used to confirm the structure and composition of the reaction products. Several parameters of the obtained surfactants were distinguished, including surface tension, electrical conductivity, and petro-dispersing parameters. Comparative analysis has been given based on the properties of the mono and gemini surfactant. At last, final suggestions were made, taking into account the salts' applicable qualities.
Petroleum-collecting and dispersing chemicals for cleaning sea surface from thin petroleum slicks Z. H. Asadov, I. A. Zarbaliyeva, R. A. Rahimov, N. V. Salamova, S. K. Eyyubova, G. A. Ahmadova, A. Z. Asadova Bulletin of the Chemical Society of Ethiopia, 2014 Monoethylolamide, diethylolamide and triethanolamine ester synthesized by us based on fish oil and their phosphate derivatives being surface-active and ecologically safe possess a high capacity of petroleum collecting and dispersing. When introducing phosphate group, a tendency to replacement of petroleum slick dispersing by its collection (accumulation into a spot) is observed. Efficiency of the chemicals change depends on the type and concentration of ions in the water. Such salts as NaCl, KI, KBr, and MgSO 4 positively influence petroleum-collecting activity whereas K 2 CO 3 and NaHCO 3 cause petroleum dispersing. KEY WORDS : Oil slicks, Petroleum-collecting, Petroleum-dispersing, Ethylolamides, Ester, Phosphate, Surfactant Bull. Chem. Soc. Ethiop. 2014 , 28(2), 205-214. DOI: http://dx.doi.org/10.4314/bcse.v28i2.5
Synthesis of new surface-active ammonium-type complexes based on palmitic acid for removing thin petroleum films from water surface Ziyafaddin H. Asadov, Ahmed H. Tantawy, Ilhama A. Zarbaliyeva, Ravan A. Rahimov Egyptian Journal of Petroleum, 2013 Complexes based on palmitic acid and nitrogen-containing compounds (monoethanolamine and triethylenetetramine) were synthesized. The synthesized complexes were taken to react with different moles of propylene oxide (1, 2 and 3) to form propoxylated compounds (surfactants). Some of physico-chemical indices of the prepared compounds such as solubility, acid and amine numbers as well as electrical conductivity have been determined. Surface-active properties (interfacial tension) of the obtained complexes were investigated by the stalagmometric method. Surface properties studied included critical micelle concentration (CMC), maximum surface excess (Γmax), and minimum surface area (Amin). Free energies of micellization (ΔGmic°) and adsorption (ΔGads°) were calculated. Petroleum-collecting and dispersing properties of the synthesized and propoxylated complexes in diluted (5 wt.% aq. solution) and undiluted form in waters of varying salinity have been studied. FTIR spectra, C13 and H1NMR spectra confirm the compound structure.
Petroleum-collecting and dispersing complexes based on oleic acid and nitrogenous compounds as surface-active agents for removing thin petroleum films from water surface Ziyafaddin H. Asadov, Ahmed H. Tantawy, Ilhama A. Zarbaliyeva, Ravan A. Rahimov Journal of Oleo Science, 2012 Petroleum-collecting and dispersing complexes were synthesized on the basis of oleic acid and nitrogen-containing compounds. Surface-active properties (interfacial tension) of the obtained complexes were investigated by stalagmometric method. Petroleum-collecting and dispersing properties of the oleic acid complexes in diluted (5% wt. water or alcoholic solution) and undiluted form have been studied in waters of varying salinity (distilled, fresh and sea waters). Some of physico-chemical indices of the prepared compounds such as solubility, acid and amine numbers as well as electrical conductivity have been determined. The ability of oleic acid complex with ethylenediamine as petro-collecting and dispersing agent towards different types of petroleum has been studied. The influence of thickness and "age" of the petroleum slick on collecting and dispersing capacity of this complex has been clarified. Surface properties studied included critical micelle concentration (CMC), maximum surface excess (Γ(max)), and minimum surface area (A(min)). Free energies of micellization (ΔG°(mic)) and adsorption (ΔG°(ads)) were calculated.
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