Bioleaching as an Eco-Friendly Nano-Factory for Sustainable Inorganic Waste Management: Current Advancements, Challenges, and Opportunities Adhish Jaiswal, S. Irudhaya Raj, Adegoke Isiaka Adetunji, Latifa Negadi, Sangeeta Singh, et al. Chemistryopen, 2025 Inorganic waste management and metal recovery technology pose significant challenges to the global research community and policymakers. Bioleaching is an economical, eco‐friendly, and sustainable technology used for extracting metals and nanoparticles from inorganic waste streams, including e‐waste, fly ash, ore, spent batteries, and petroleum catalysts. Valuable metals are recovered from these waste materials by microbial action. Bioleaching occurs by redoxolysis, acidolysis, and complexolysis processes. The present review provides insights into global trends and hazards of e‐waste while also discussing the bioleaching of metals and nanoparticles from various inorganic wastes. In addition, the review focuses on the mechanistic pathway of the bioleaching process and computational aspects, such as the response surface method employed for enhanced recovery of metals from solid waste materials. Various physicochemical and biological parameters influencing metal bioleaching, as well as economic impacts and challenges affecting the bioleaching of metals from solid wastes, are discussed.
Density, Speed of Sound, Refractive Index, and the Derived Properties of Binary Mixtures of N,N-Dimethylacetamide with 1-Butanol, 1-Pentanol, Furfural, or Furfuryl Alcohol at Different Temperatures Joan Chepkoech Kilele, Amal Ayad, Joseph Saab, Amina Negadi, Ariel Hernández, et al. Journal of Chemical and Engineering Data, 2025 The density (ρ), speed of sound (c), and refractive index (nD) of N,N-dimethylacetamide (DMA) with 1-butanol, 1-pentanol, furfural (FFL), or furfuryl alcohol (FA) as a function of composition and at T = 293.15 to 323.15 K with an interval of 10 K and atmospheric pressure were measured. From the experimental data, the excess molar volume (VmE), isentropic compressibility (κs), intermolecular free length (Lf), specific acoustic impedance (Ζ), relative association (RA), relaxation strength (r), Rao’s molar sound function (R), excess isentropic compressibility (ksE), and excess refractive index (nDE) properties were calculated. These results were successfully fitted to the Redlich–Kister polynomial equation. The obtained results were discussed in terms of the nature of molecular interactions. The perturbed chain statistical associating fluid theory equation of state (PC-SAFT EoS) as a predictive approach was used for modeling the density of the binary mixtures. Schaaffs's collision factor theory (SCFT) and Nomoto’s relation (NR) were successfully applied for predictive modeling the speed of sound of the binary mixtures, and four mixing rules were used for the modeling of the refractive index of the mixtures.
Excess thermodynamic properties of the binary mixtures Carbitol + n-hydrocarbon as fuel representative ECOS 2018 Proceedings of the 31st International Conference on Efficiency Cost Optimization Simulation and Environmental Impact of Energy Systems, 2018
Thermophysical Properties of Biofuel Components Furfural or Furfuryl Alcohol with Alcohols: Experimental and Thermodynamic Modeling Z Boudellal, A Ayad, A Belabbaci, WM Nelson, A Negadi, I Bahadur, ... Journal of Chemical & Engineering Data , 2026 2026
Experimental vapor-liquid equilibria of pure compounds and binary systems (furfural+ γ-valerolactone or γ-butyrolactone) and (5-methylfurfural+ γ-valerolactone or γ … I Guennoun, I Mokbel, L Negadi, J Jose, J Saab Fluid Phase Equilibria 602, 114617 , 2026 2026 Citations: 3
Bioleaching as an Eco‐Friendly Nano‐Factory for Sustainable Inorganic Waste Management: Current Advancements, Challenges, and Opportunities A Jaiswal, SI Raj, A Isiaka Adetunji, L Negadi, S Singh, K Tumba, ... ChemistryOpen 14 (9), e202500104 , 2025 2025 Citations: 3
VLE Measurements and Modelling for Binary Systems of Hydrogen or Ethylene with Methylcyclohexane WM Nelson, L Negadi, K Moodley, P Naidoo The Journal of Supercritical Fluids, 106764 , 2025 2025
Thermodynamic, ultrasonic, and transport study of binary mixtures containing 1-hexene and alcohols at 293.15–303.15 K KN Abdellaoui, A Belabbaci, A Ayad, A Negadi, A Hernández, M Aslam, ... Journal of Chemical & Engineering Data 70 (8), 2961-2984 , 2025 2025 Citations: 4
An in-depth evaluation and comprehensive analysis of Algeria’s waste management system H Hachemi, C Seladji, L Negadi, MR Haddouche, N Bensaber Euro-Mediterranean Journal for Environmental Integration 10 (4), 2567-2580 , 2025 2025 Citations: 4
Experimental and predicted aqueous solubility and vapor pressures of food packaging migrants: 4-n-octylphenol, 4-tert-octylphenol and 4-n-nonylphenol J Farhat, I Mokbel, G Bassil, BFZ Sari-Ali, L Negadi, J Jose, J Saab The Journal of Chemical Thermodynamics 201, 107410 , 2025 2025 Citations: 1
High-pressure phase equilibrium for carbon dioxide solubility with biofuels: Experimental and thermodynamic insights in 2, 5-dimethylfuran and methyl levulinate A Ayad, M Ebrahiminejadhasanabadi, WM Nelson, L Negadi, P Naidoo The Journal of Supercritical Fluids 214, 106378 , 2024 2024
Density, Speed of Sound, Refractive Index, and the Derived Properties of Binary Mixtures of N , N -Dimethylacetamide with 1-Butanol, 1-Pentanol, Furfural, or … JC Kilele, A Ayad, J Saab, A Negadi, A Hernandez, I Bahadur, V Kumar, ... Journal of Chemical & Engineering Data 70 (1), 67-86 , 2024 2024 Citations: 7
contribution to the extraction of furfural from fermentation broth by studying phase equilibria: VLE (furfural+ ethyl octanoate); LLE of binary systems (furfural+ water),(ethyl … I Mokbel, O Khelidj, L Negadi, J Jose E2DT 2023-2nd International conference on energy, environment & digital … , 2024 2024
Isothermal Vapor–Liquid Equilibria of Binary Mixtures Containing N , N -Dimethylacetamide with 1,3,5-Trimethylbenzene or Propan-2-ol or Dimethyl Sulfoxide D Belhadj, J Saab, I Mokbel, J Jose, A Negadi, I Bahadur, M Rahaman, ... Journal of Chemical & Engineering Data 69 (11), 3952-3963 , 2024 2024 Citations: 3
Phase Equilibria (VLE and LLE) of Platform Molecules for the Optimization of Separation Processes I Mokbel, I Guennoun, O Khelidj, L Negadi, J Saab, J Jose CAT 2024-3rd International Conference on Oil, Gas & petroleum Engineering … , 2024 2024
Improving municipal solid waste management in Algeria and exploring energy recovery options H Hachemi, C Seladji, L Negadi, R Bhandari, S Aryal Renewable Energy 230, 120861 , 2024 2024 Citations: 20
Isothermal vapor–liquid equilibria of binary mixtures containing (methanol, or propan-1-ol, or water, or acetonitrile) and 1-ethyl-3-methylimidazolium thiocynate ionic liquid … BFZ Sari-Ali, I Mokbel, F Mutelet, O Khelidj, J Jose, I Bahadur, ... Journal of Molecular Liquids 399, 124433 , 2024 2024 Citations: 2
Intermolecular Interactions of Binary Mixtures Comprising 2‐Benzylaminoethanol with Alcohols (C 1 −C 3 ) at Different Temperatures: Experiments and Modelling A Belabbaci, A Ayad, A Negadi, A Hernandez, B Kabane, I Bahadur, ... ChemistrySelect 9 (8), e202302523 , 2024 2024 Citations: 2
CO2 capture by N, N’, N’-tetramethylethylene diamine (TMEDA) in aqueous solution at different loading and temperatures I Mokbel, MR Mahi, L Negadi, J Jose Energy, Environment and Digital transition, E2DT , 2023 2023
Phase Equilibrium Properties of Binary Systems (Furfural+ Ethanol or Butan-2-ol) at Several Temperatures NCB Ahmed, I Mokbel, A Negadi, A Hernandez, J Jose, T Mohale, ... Journal of Chemical & Engineering Data 68 (11), 2888-2897 , 2023 2023
Measurements and Modeling of Thermodynamic Properties of Binary Systems Comprising (2-Amino-2-methyl-1-propanol with Acetonitrile, Toluene, 1-Pentanol or 1-Hexanol) at … A Ayad, A Belabbaci, A Negadi, A Hernandez, B Kabane, I Bahadur, ... Journal of Chemical & Engineering Data 68 (11), 2789-2806 , 2023 2023 Citations: 8
A study on mixing properties of binary mixtures of 1-hexene with alkoxyethanols at different temperatures D Belhadj, A Negadi, A Hernández, I Mokbel, I Bahadur, L Negadi The Journal of Chemical Thermodynamics 172, 106820 , 2022 2022 Citations: 16
Investigate oxoazolidine-2, 4-dione based eutectic mixture via DFT calculations and SAR APS Raman, P Jain, A Kumar, J Tomar, N Kaushik, EH Choi, NK Kaushik, ... Journal of the Indian Chemical Society 99 (8), 100570 , 2022 2022 Citations: 23
MOST CITED SCHOLAR PUBLICATIONS
Isothermal vapor− liquid equilibria of (monoethanolamine+ water) and (4-methylmorpholine+ water) binary systems at several temperatures A Belabbaci, A Razzouk, I Mokbel, J Jose, L Negadi Journal of Chemical & Engineering Data 54 (8), 2312-2316 , 2009 2009 Citations: 62
Effect of temperature on density, sound velocity, and their derived properties for the binary systems glycerol with water or alcohols L Negadi, B Feddal-Benabed, I Bahadur, J Saab, ... The Journal of Chemical Thermodynamics 109, 124-136 , 2017 2017 Citations: 61
Anti-agglomeration in cyclopentane hydrates from bio-and co-surfactants X Li, L Negadi, A Firoozabadi Energy & fuels 24 (9), 4937-4943 , 2010 2010 Citations: 52
Investigation of the isothermal (vapour+ liquid) equilibria of aqueous 2-amino-2-methyl-1-propanol (AMP), N-benzylethanolamine, or 3-dimethylamino-1-propanol solutions at … A Belabbaci, NCB Ahmed, I Mokbel, L Negadi The Journal of Chemical Thermodynamics 42 (9), 1158-1162 , 2010 2010 Citations: 51
Effects of alkyl group and temperature on the interactions between furfural and alcohol: Insight from density and sound velocity studies L Bendiaf, I Bahadur, A Negadi, P Naidoo, D Ramjugernath, L Negadi Thermochimica acta 599, 13-22 , 2015 2015 Citations: 46
Liquid-vapor equilibria, excess Gibbs energies, and excess volumes of dimethyl carbonate+ heptane,+ 1-hexene,+ cyclohexane, or+ benzene L Negadi, A Blondel, I Mokbel, A Ait-Kaci, J Jose Int. DATA Ser., Sel. Data Mixtures, Ser. A 21 (3), 164-194 , 1993 1993 Citations: 42
(Vapor-liquid) equilibria and excess Gibbs free energy functions of (ethanol+ glycerol), or (water+ glycerol) binary mixtures at several temperatures M Zaoui-Djelloul-Daouadji, A Negadi, I Mokbel, L Negadi The Journal of Chemical Thermodynamics 69, 165-171 , 2014 2014 Citations: 41
Liquid–vapor equilibria of binary systems containing alcohols (1-butanol, or 2-butanol or 1-hexanol) present in the production by chemical process of 2, 5-dimethyl furan from … LK Zaitri, L Negadi, I Mokbel, N Msakni, J Jose Fuel 95, 438-445 , 2012 2012 Citations: 41
Density, speed of sound and refractive index of mixtures containing 2-phenoxyethanol with propanol or butanol at various temperatures H Makhlouf, N Muñoz-Rujas, F Aguilar, B Belhachemi, EA Montero, ... The Journal of Chemical Thermodynamics 128, 394-405 , 2019 2019 Citations: 36
Experimental solubility of carbon dioxide in monoethanolamine, or diethanolamine or N-methyldiethanolamine (30 wt%) dissolved in deep eutectic solvent (choline chloride and … MR Mahi, I Mokbel, L Negadi, F Dergal, J Jose Journal of Molecular Liquids 289, 111062 , 2019 2019 Citations: 35
Phase equilibrium properties of binary aqueous solutions containing ethanediamine, 1, 2-diaminopropane, 1, 3-diaminopropane, or 1, 4-diaminobutane at several temperatures NCB Ahmed, L Negadi, I Mokbel, J Jose The Journal of Chemical Thermodynamics 43 (5), 719-724 , 2011 2011 Citations: 31
Vapor–liquid equilibria of binary mixtures containing 1-butanol and hydrocarbons at 313.15 K A Belabbaci, RM Villamanan, L Negadi, CM Martin, A Ait Kaci, ... Journal of Chemical & Engineering Data 57 (1), 114-119 , 2012 2012 Citations: 30
Density, speed of sound, refractive index and related derived/excess properties of binary mixtures (furfural+ dimethyl sulfoxide),(furfural+ acetonitrile) and (furfural+ … D Belhadj, A Negadi, P Venkatesu, I Bahadur, L Negadi Journal of Molecular Liquids 330, 115436 , 2021 2021 Citations: 27
Vapor–liquid equilibria, density, sound velocity, and refractive index for binary mixtures containing 2-(2-ethoxyethoxy) ethanol and 1-propanol or 2-propanol or 1-butanol or 2 … F Ouaar, I Mokbel, A Negadi, F Aguilar, EA Montero, J Jose, I Bahadur, ... Journal of Chemical & Engineering Data 65 (5), 2351-2372 , 2020 2020 Citations: 27
Isothermal Vapor− Liquid Equilibria and Excess Enthalpies of (Propyl Ethanoate+ Heptane),(Propyl Ethanoate+ Cyclohexane), and (Propyl Ethanoate+ 1-Hexene) L Negadi, A Belabbaci, A Ait Kaci, J Jose Journal of Chemical & Engineering Data 52 (1), 47-55 , 2007 2007 Citations: 26
Thermodynamic, ultrasonic, and transport study of binary mixtures containing 2-(2-methoxyethoxy) ethanol and alcohols at (293.15–323.15) K D Belhadj, I Bahadur, A Negadi, N Muñoz-Rujas, E Montero, L Negadi Journal of Chemical & Engineering Data 65 (11), 5192-5209 , 2020 2020 Citations: 25
Volumetric, acoustic and transport properties of mixtures containing dimethyl sulfoxide and some amines or alkanolamines: Measurement and correlation F Ouaar, A Negadi, I Bahadur, R Phadagi, B Feddal-Benabed, L Negadi The Journal of Chemical Thermodynamics 121, 187-198 , 2018 2018 Citations: 24
Volumetric and acoustic properties of binary systems (furfural or furfuryl alcohol+ toluene) and (furfuryl alcohol+ ethanol) at different temperatures M Zaoui-Djelloul-Daouadji, L Bendiaf, I Bahadur, A Negadi, ... Thermochimica Acta 611, 47-55 , 2015 2015 Citations: 24
Investigate oxoazolidine-2, 4-dione based eutectic mixture via DFT calculations and SAR APS Raman, P Jain, A Kumar, J Tomar, N Kaushik, EH Choi, NK Kaushik, ... Journal of the Indian Chemical Society 99 (8), 100570 , 2022 2022 Citations: 23
Isothermal vapor–liquid equilibria of binary systems containing green solvents derived from biomass:(Furfuryl alcohol+ toluene),(furfuryl alcohol+ ethanol), or (furfural+ toluene) L Bendiaf, A Negadi, I Mokbel, L Negadi Fuel 122, 247-253 , 2014 2014 Citations: 23