The Influence of the Molecular Architecture of the Peg: Ppg Triblock Copolymer on the Properties of Epoxy Nanocomposites Bruna L. Silva, Marcia B. Schuster, Daniela Becker, Luiz A.F. Coelho Materials Research, 2022 11, 2022. This work focuses on characterizing the role of different triblock copolymers on the dispersion of nanoparticles in an epoxy matrix and in the thermal and mechanical properties of the resulting nanocomposites, using Poly (ethylene glycol) - block-poly (propylene glycol) - block-poly (ethylene glycol) (PEG-b-PPG- b-PEG) with 30% PEG, and poly (propylene glycol) - block-poly (ethylene glycol) - block-poly (propylene glycol) (PPG-b-PEG-b-PPG) with 50% PEG. The nanoparticles employed have different geometries: carbon nanotubes, graphene nanoplatelets and carbon black (spherical). Both copolymers were miscible in epoxy. The results suggest that the copolymers viscosity may be interfering with the dispersion of the nanoparticles in the matrix: the PPG-b- PEG-b-PPG50% copolymer has a higher viscosity than the PEG b-PPG-b-PEG30%, which facilitates their dispersion and an increase in mechanical properties. The PEG fraction was an important factor in the dispersion of nanoparticles in the epoxy matrix. The higher the PEG content in the copolymer block, the greater the synergy shown in the mechanical properties, since the nanoparticles inhibited the plasticizing effect of the
The role of carbon nanoparticles in epoxy-based nanocomposites modified with (poly[polypropylene oxide]-block-poly[ethylene oxide]-block-poly[propylene oxide]) triblock copolymers on phase morphology and mechanical properties Bruna L. Silva, Marcia B. Schuster, Roger H. Bello, Daniela Becker, Luiz A. F. Coelho Polymer Composites, 2020 The main goal of this work is to show the role of carbon nanoparticle geometry and poly(ethylene oxide):poly(propylene oxide) (PEG:PPG) ratio on the miscibility, morphology, and final properties of an epoxy resin modified with triblock copolymers PPG‐block‐PEG‐block‐PPG (PPG‐b‐PEG‐b‐PPG). The employed copolymers have different PEG:PPG ratios in their molecular structure. One of them is miscible and the other is immiscible in epoxy resin. The used carbon nanoparticles were multiwalled carbon nanotubes, graphene nanoplatelets, and carbon black in a concentration of 0.5 wt/wt% for all nanoparticles. Adding the nanoparticles did not influence the miscibility of the PPG‐b‐PEG‐b‐PPG copolymer in the resin. However, the different geometries of the nanoparticles interfered in the dispersion, reflecting on the mechanical and thermal properties of the epoxy‐based nanocomposites. Nanocomposites in a miscible system with graphene nanoparticles showed a 10% increase in Young's modulus over the neat resin. Immiscible systems with carbon black nanoparticles presentedKIcvalues 81% higher than the neat matrix, while the numerical valueKIcwas only 6.5% higher than the neat resin for the miscible ones. Besides, a synergistic effect was observed between the copolymer/nanoparticles on the toughness of the nanocomposites. Finally, the nanoparticles minimized the negative effect of the block copolymer on Young's modulus and the glass transition temperature of the neat resin.