Mikhailov Ilya
@iopc.ru
Arbuzov Institute of Organic and Physical Chemistry of FRC Kazan Scientific Center of RAS Arbuzov IOPC FRC Kazan Scientific Center of RAS
RESEARCH, TEACHING, or OTHER INTERESTS
Chemistry, Physical and Theoretical Chemistry, Electrochemistry, Catalysis
Scopus Publications
Scopus Publications
Z. N. Gafurov, I. F. Sakhapov, A. A. Kagilev, A. O. Kantyukov, I. K. Mikhailov, G. R. Ganeev, R. R. Faizullin, K. R. Khayarov, A. V. Gerasimov, and D. G. Yakhvarov
Pleiades Publishing Ltd
I. F. Sakhapov, A. A. Kagilev, A. O. Kantyukov, I. K. Mikhailov, O. S. Sof’icheva, D. R. Islamov, Z. N. Gafurov, and D. G. Yakhvarov
Pleiades Publishing Ltd
Ilya K. Mikhailov, Zufar N. Gafurov, Alexey A. Kagilev, Vladimir I. Morozov, Artyom O. Kantyukov, Ekaterina M. Zueva, Gumar R. Ganeev, Ilyas F. Sakhapov, Asiya V. Toropchina, Igor A. Litvinov,et al.
MDPI AG
A Pt(II) complex bearing chelating tridentate bis-aryloxide tetrahydropyrimidinium-based N-heterocyclic carbene (NHC) was synthesized and characterized by using different techniques. Both cyclic voltammetry and differential pulse voltammetry were used to study the electrochemical properties of the complex, revealing two reversible one-electron oxidation processes. The chemical generation and isolation of one-electron-oxidized species were performed oxidizing the initial complex by means of AgBF4. A combination of spectroscopic (UV-Vis/NIR- and EPR-) and theoretical (density functional theory (DFT)) studies suggests the formation of a Pt(II)-phenoxyl radical complex. The latter open-shell derivative was structurally characterized by means of X-ray diffraction analysis. Finally, the neutral platinum complex was tested as a mediator in the process of electrocatalytic oxidation of 2-(methylamino)ethanol (MEA).
Alexey A. Kagilev, Zufar N. Gafurov, Artyom O. Kantyukov, Ilya K. Mikhailov, and Dmitry G. Yakhvarov
Springer Science and Business Media LLC
Z. N. Gafurov, I. F. Sakhapov, A. A. Kagilev, A. O. Kantyukov, I. K. Mikhailov, G. R. Ganeev, R. R. Faizullin, K. R. Khayarov, A. V. Gerasimov, and D. G. Yakhvarov
Pleiades Publishing Ltd
A. A. Kagilev, Z. N. Gafurov, I. F. Sakhapov, D. R. Islamov, A. O. Kantyukov, I. K. Mikhailov, and D. G. Yakhvarov
Pleiades Publishing Ltd
I. F. Sakhapov, Z. N. Gafurov, A. O. Kantyukov, A. A. Kagilev, I. K. Mikhailov, E. M. Zueva, D. N. Buzyurova, V. M. Babaev, S. A. Shteingolts, R. R. Faizullin,et al.
Pleiades Publishing Ltd
Alexey A. Kagilev, Vladimir I. Morozov, Ekaterina M. Zueva, Zufar N. Gafurov, Ilya K. Mikhailov, Artyom O. Kantyukov, Il'yas F. Sakhapov, Nataliya A. Zhukova, Milyausha S. Kadyrova, Vakhid A. Mamedov,et al.
Elsevier BV
Zufar N. Gafurov, Ekaterina M. Zueva, Giyjaz E. Bekmukhamedov, Alexey A. Kagilev, Artyom O. Kantyukov, Ilya K. Mikhailov, Khasan R. Khayarov, Maria M. Petrova, Alexey P. Dovzhenko, Andrea Rossin,et al.
Elsevier BV
Zufar N. Gafurov, Artyom O. Kantyukov, Alexey A. Kagilev, Alina A. Kagileva, Il’yas F. Sakhapov, Ilya K. Mikhailov, and Dmitry G. Yakhvarov
MDPI AG
Pincer complexes play an important role in organometallic chemistry; in particular, their use as homogeneous catalysts for organic transformations has increased dramatically in recent years. The high catalytic activity of such bis-cyclometallic complexes is associated with the easy tunability of their properties. Moreover, the phosphorus-based unsymmetrical pincers showed higher catalytic activity than the corresponding symmetrical analogues in several catalytic reactions. However, in modern literature, an increasing interest in the development of catalysts based on non-precious metals is observed. For example, nickel, which is an affordable and sustainable analogue of platinum and palladium, known for its low toxicity, has attracted increasing attention in the catalytic chemistry of transition metals in recent years. Thus, this mini-review is devoted to the recent advances in the chemistry of unsymmetrical phosphorus-based pincer nickel complexes, including the ligand design, the synthesis of nickel complexes and their catalytic applications.
Zufar N. Gafurov, Giyjaz E. Bekmukhamedov, Alexey A. Kagilev, Artyom O. Kantyukov, Il’yas F. Sakhapov, Ilya K. Mikhailov, Khasan R. Khayarov, Ruslan B. Zaripov, Daut R. Islamov, Konstantin S. Usachev,et al.
Elsevier BV