Sustainable use of wastes in building materials, contaminant fate and transport, microplastics
14
Scopus Publications
Scopus Publications
Kinetics of Bioaccumulation of Chromium (VI) in Danio rerio Species Indian Journal of Environmental Protection, 2024
Sorption kinetics of chromium(VI) in synergetic biochar derived from Saccharum officinarum and Prosopis juliflora Srinath Rajagopalan, Aswin Sriram, shobana Purushothaman Indian Journal of Chemical Technology, 2024 This study presents an investigation into the effectiveness of utilizing biomass derived from Prosopis juliflora (Mesquite) and bagasse for the removal of hexavalent chromium -Cr[VI] from water sources. The experimental analysis includes examining the impact of various factors such as adsorbent type, concentration, and temperature on the removal efficiency of Cr[VI]. The obtained data reveal that both Mesquite and bagasse exhibit varying degrees of removal efficiency under different experimental conditions. Mesquite demonstrates higher removal percentages for specific Cr[VI] concentrations, particularly at 100 ppm and a temperature of 60°C. On the other hand, bagasse showcases better removal efficiency for certain concentrations. The comparative analysis of the two adsorbents indicates the influence of their distinct properties on the removal process. The results emphasize the importance of carefully selecting the appropriate adsorbent and optimizing operating conditions to achieve efficient Cr[VI] removal. The findings of this study contribute to the understanding of the potential of Mesquite and bagasse as adsorbents for hexavalent chromium removal and underscore the need for tailored strategies to address diverse water contamination scenarios.
Global patterns and environmental controls of perchlorate and nitrate co-occurrence in arid and semi-arid environments W. Andrew Jackson, J.K. Böhlke, Brian J. Andraski, Lynne Fahlquist, Laura Bexfield, Frank D. Eckardt, John B. Gates, Alfonso F. Davila, Christopher P. McKay, Balaji Rao, Ritesh Sevanthi, Srinath Rajagopalan, Nubia Estrada, Neil Sturchio, Paul B. Hatzinger, Todd A. Anderson, Greta Orris, Julio Betancourt, David Stonestrom, Claudio Latorre, Yanhe Li, Gregory J. Harvey Geochimica Et Cosmochimica Acta, 2015
Perchlorate in wet deposition across North America Srinath Rajagopalan, Todd Anderson, Stephen Cox, Greg Harvey, Qiuqiong Cheng, W. Andrew Jackson Environmental Science and Technology, 2009 Natural perchlorate is believed to be of atmospheric origin, yet no systematic study has been conducted to evaluate perchlorate deposition rate and possible seasonal or spatial variations. This study evaluated perchlorate concentrations in weekly composite wet deposition samples acquired through the National Atmospheric Deposition Program from 26 sites across the continental United States, Alaska, and Puerto Rico for a 1-3 year period. Perchlorate concentrations varied from <5 ng/L to a high of 102 ng/L with a mean of 14.1 +/- 13.5 ng/L for the 1578 total samples. The annual perchlorate flux by site ranged from a low of 12.5 (TX) to 157 mg/ha-year (NE) and averaged 65 +/- 30 mg/ha-year for all sites. Perchlorate concentrations and flux in wet deposition were generally highest in May-August declining to lows in December-February. Average annual perchlorate flux was correlated (r > 0.5; p < 0.001) with Ca2+, K+, NH4+, NO3(-), Cl(-), and SO4(-2). Wet deposition rate of ClO4(-) in the conterminous United States (excluding Alaska, Hawaii, and Puerto Rico) while diffuse, represents a potential annual net mass flux of 51,000 kg, a value comparable to the estimated annual environmental releases from other known ClO4(-) sources.
Widespread natural perchlorate in unsaturated zones of the southwest United States Balaji Rao, Todd A. Anderson, Greta J. Orris, Ken A. Rainwater, Srinath Rajagopalan, Renee M. Sandvig, Bridget R. Scanlon, David A. Stonestrom, Michelle A. Walvoord, W. Andrew Jackson Environmental Science and Technology, 2007 A substantial reservoir (up to 1 kg ha(-1)) of natural perchlorate is present in diverse unsaturated zones of the arid and semi-arid southwestern United States. The perchlorate co-occurs with meteoric chloride that has accumulated in these soils throughout the Holocene [0 to 10-15 ka (thousand years ago)] and possibly longer periods. Previously, natural perchlorate widely believed to be limited to the Atacama Desert, now appears widespread in steppe-to-desert ecoregions. The perchlorate reservoir becomes sufficiently large to affect groundwater when recharge from irrigation or climate change flushes accumulated salts from the unsaturated zone. This new source may help explain increasing reports of perchlorate in dry region agricultural products and should be considered when evaluating overall source contributions.
Alternative water sources in earthwork construction Priyantha W. Jayawickrama, Srinath Rajagopalan Transportation Research Record, 2007 During periods of drought, good-quality water becomes a precious commodity, especially in those parts of the United States that receive little rainfall. One way to reduce the demand for drinking water is to substitute non-drinking-quality water in earthwork construction. If nonpotable water from local sources can be used in construction, then the need for hauling in good-quality water from distant sources and the potential for construction delays because of water rationing can be avoided. A research study investigated the feasibility of using alternative water sources in earthwork construction. As a part of this study, alternative water supplies in Texas were identified and characterized for quality and volume availability. In addition, each proposed water source was evaluated to determine whether there were any adverse environmental impacts from its use in earthwork construction. Potential impact from the use of low-quality water on constructability, material behavior, and performance also were evaluated. Of special interest were the effects on corrosive potential, sulfate heave, and dispersion potential of the soil. Simple predictive models are presented to help when decisions are made regarding acceptance or rejection of water obtained from a specific source.