Understanding the nonlinear reactive transport model in porous catalysts D. Sujatha, R.Usha Rani, G. Vennila, A. Marimuthu, M. Renugadevi, L. Rajendran International Journal of Electrochemical Science, 2024 This paper discusses the steady-state nonlinear reaction-diffusion processes in porous catalysts. This model is based on a nonlinear second-order differential equation that includes a nonlinear term associated with the Michaelis-Menten and non-Michaelis-Menten kinetics of the reaction. The nonlinear equations can be approximately solved using the Taylors series, modified Taylors series and Akabri-Ganji technique to obtain the concentration of dissolved species. The influence of the half-saturation parameter and the characteristic reaction rate on concentration is explored. Sensitivity analysis of parameters is discussed. Our analytical findings were compared with numerical solutions.
Theoretical analysis of the enzyme reaction processes within the multiscale porous biocatalytic electrodes: Akbari–Ganji's and Taylor's series method S. Krishnakumar, R. Usha Rani, K. Lakshmi Narayanan, L. Rajendran International Journal of Electrochemical Science, 2024 We discuss a theoretical model that describes glucose oxidation in a multiscale porous biocatalytic electrode. The model under consideration consists of two nonlinear differential equations that describe diffusion and reaction in the hydrogel film. The Akbari–Ganji's and Taylor series methods have been used in this communication to obtain the analytical expressions for the concentrations of the oxidized mediator, Glucose, and current. Additionally, the optimal electrode thickness of the film is calculated analytically. The impact of parameters on current is also explored. The parameter with the most significant effect on the current is the ratio of the oxidized mediator's diffusion to the enzymatic process occurring within the film. The numerical solution (Matlab) validates our analytical results.
Theoretical analysis of amperometric response towards PPO-based rotating disk bioelectrodes: Taylors series and hyperbolic function method Vannathamizhan Silambuselvi, Sekar Rekha, Ramu Usha Rani, Lakshmanan Rajendran, Karuppiah Angaleeswari, Michael E.G. Lyons International Journal of Electrochemical Science, 2023 A mathematical model for the electroenzymatic process of a rotating disk electrode in which polyphenol oxidase occurs is discussed. The model is related to a system of reaction-diffusion equations that includes a nonlinear factor relating to the enzymatic reaction's Michaelis-Menten kinetics. The approximate analytical techniques (Taylor's series and Hyperbolic function) are used to solve the nonlinear differential equations describing the diffusion-coupled enzymatic reactions. For all parameter values γE(=γL2) and α1(αS∞). Closed analytical equations for the concentration of the substrate, the concentration of the product, and the related current response have been obtained. These analytical results are in good agreement when compared to simulation results ( Matlab program). The findings are reliable over the whole solution domain.
Analytical Expressions for Steady-State Current and Estimation of Kinetic Parameters in an Amperometric Biosensor with The Product Inhibition: Power Series Method J. Saranya, R. Usha Rani, M. E. G. Lyons, M. Abukhaled, L. Rajendran Aip Conference Proceedings, 2022 A theoretical model of an amperometric biosensor with a modified electrode that inhibits the substance is addressed. The solution of a system of reaction-diffusion equations in a bounded region with a non-linear term similar to non-Michaelis- Menten kinetics of the enzymatic reaction is the basis for this model. The estimated analytical expression for the steady-state concentration profiles of reactant and product inside the thin film is provided in this paper, and it applies to all parameter values. In this paper, the power series method is used to find the given mathematical model, concentrations of substrate, product and current. The approximate analytical results are compared to numerical simulation results. It is noted that a satisfactory agreement has been reached. For the calculation of kinetic parameters and sensitivity analysis of established parameters, an analytic approach is proposed.
Transport and Kinetics in Biofiltration Membranes: New Analytical Expressions for Concentration Profiles of Hydrophilic and Hydrophobic VOCs Using Taylor’s Series and Akbari- Ganji methods Singaravel Anandhar Salai Sivasundari and International Journal of Electrochemical Science, 2022 The mathematical models of biofiltration of mixtures of hydrophilic (methanol) and hydrophobic ( pinene) volatile organic compounds (VOCs) are explored in this paper. This model is based on diffusion equations that contain a nonlinear term linked to the enzymatic reaction's Michaelis-Menten kinetics. An approximate analytical expression of methanol and pinene concentration profiles in the air and biofilm phase were derived using Taylor's series and Akbari-Ganji's methods. In addition, the numerical simulation of the problem using the Matlab programme to investigate the system's dynamics is reported in this work. Graphic results are presented to illustrate the solution, and numerical data is analyzed. The analytical and numerical data are in good agreement.
Theoretical Analysis of Nonlinear Process in Amperometric Biosensor Using Akbari–Ganji and Hyperbolic Function Method SD Rajachelin, RU Rani, L Rajendran Chemistry Africa 8 (7), 3213-3227 , 2025 2025 Citations: 1
Unraveling nonlinear, transient nth-order reaction–diffusion processes within porous catalysts of arbitrary shapes: Analytical and numerical perspective RU Rani, L Rajendran Chemical Engineering Science, 122431 , 2025 2025 Citations: 1
Understanding the nonlinear reactive transport model in porous catalysts D Sujatha, RU Rani, G Vennila, A Marimuthu, M Renugadevi, ... International Journal of Electrochemical Science 19 (12), 100852 , 2024 2024 Citations: 5
Analytical and numerical solutions of nonlinear heat diffusion model for the thermal energy storage problem V Silambuselvi, K Angaleeswari, S Rekha, L Rajendran, RU Rani AIP Conference Proceedings 3160 (1), 020001 , 2024 2024 Citations: 1
Theoretical analysis of the enzyme reaction processes within the multiscale porous biocatalytic electrodes: Akbari–Ganji's and Taylor’s series method S Krishnakumar, RU Rani, KL Narayanan, L Rajendran International Journal of Electrochemical Science 19 (4), 100527 , 2024 2024 Citations: 3
A theoretical and computational analysis of the concentration of substrate and product in enzyme-based electrochemical biosensors: Akbari-Ganji’s method RU Rani, N Jha, L Rajendran Journal of Electroanalytical Chemistry 956, 118077 , 2024 2024 Citations: 4
Theoretical analysis of homogeneous catalysis of electrochemical reactions: steady-state current–potential RU Rani, L Rajendran, M Abukhaled Reaction Kinetics, Mechanisms and Catalysis 136 (3), 1229-1242 , 2023 2023 Citations: 12
Theoretical analysis of amperometric response towards PPO-based rotating disk bioelectrodes: Taylors series and hyperbolic function method V Silambuselvi, S Rekha, RU Rani, K Angaleeswari International Journal of Electrochemical Science 18 (4), 100083 , 2023 2023 Citations: 10
A New Method to Study the Nonlinear Reaction-Diffusion Process in the Electroactive Polymer Film using Hyperbolic Function Method * Sekar Rekha1 , Ramu Usha Rani2 , Lakshmanan Rajendran1,*, Michael E.G. Lyons3 International Journal of ELECTROCHEMICAL SCIENCE 17, 221261 , 2022 2022 Citations: 10
Analytical expressions for steady-state current and estimation of kinetic parameters in an amperometric biosensor with the product inhibition: Power series method J Saranya, RU Rani, MEG Lyons, M Abukhaled, L Rajendran AIP Conference Proceedings 2516 (1), 250017 , 2022 2022 Citations: 1
Mathematical modelling of Amperometric Glucose biosensor based on immobilized Enzymes: New approach of Taylors series method KL Narayanan, J Kavitha, RU Rani, MEG Lyons, L Rajendran International Journal of Electrochemical Science 17 (10), 221064 , 2022 2022 Citations: 17
Mathematical modelling of forced convection in a porous medium for a general geometry: Solution of thermal energy equation via Taylor’s series with Ying Buzu algorithms KL Narayanan, R Shanthi, RU Rani, MEG Lyons, L Rajendran International Journal of Electrochemical Science 17 (6), 220623 , 2022 2022 Citations: 14
Transport and Kinetics in Biofiltration Membranes: New Analytical Expressions for Concentration Profiles of Hydrophilic and Hydrophobic VOCs Using Taylor’s Series and Akbari … SAS Sivasundari, RU Rani, MEG Lyons, L Rajendran International Journal of Electrochemical Science 17 (4), 220447 , 2022 2022 Citations: 20
Approximations for the Concentration and Effectiveness Factor in Porous Catalysts of Arbitrary Shape: Taylor Series and Akbari-Ganji’s Methods MA Ramu Usha Rani 1 , Lakshmanan Rajendran 1* Mathematical Modelling of Engineering Problems 8 (4), 527-537 , 2021 2021 Citations: 8
Diffusion indicator for hemispheroidal and ring ultramicroelectrode geometries for E and ECʹ reactions RU Rani, L Rajendran Electrochemistry Communications 128, 107071 , 2021 2021 Citations: 8
Steady-state current in product inhibition kinetics in an amperometric biosensor: Adomian decomposition and Taylor series method RU Rani, L Rajendran, MEG Lyons Journal of Electroanalytical Chemistry 886, 115103 , 2021 2021 Citations: 45
Taylor’s Series Solution of a Singular BVP of Reaction cum Diffusion in a Biocatalyst LR • R. Usha Rani Emerging Technologies and Innovative Research in Science, Engineering and … , 2021 2021
Nonlinear mass transfer at the electrodes with reversible homogeneous; reactions: taylor'sseries and hyperbolic function method LC Mary, RU Rani, A Meena, L Rajendran International Journal of Electrochemical Science 16 (1), 151037 , 2021 2021 Citations: 26
Approximate analytical solution of nonlinear equations in cubic auto-catalytic reaction-diffusion process RU Rani, L Rajendran AIP Conference Proceedings 2277 (1), 130006 , 2020 2020 Citations: 4
Taylor’s series method for solving the nonlinear reaction-diffusion equation in the electroactive polymer film RU Rani, L Rajendran Chemical Physics Letters 754, 137573 , 2020 2020 Citations: 70
MOST CITED SCHOLAR PUBLICATIONS
Taylor’s series method for solving the nonlinear reaction-diffusion equation in the electroactive polymer film RU Rani, L Rajendran Chemical Physics Letters 754, 137573 , 2020 2020 Citations: 70
Steady-state current in product inhibition kinetics in an amperometric biosensor: Adomian decomposition and Taylor series method RU Rani, L Rajendran, MEG Lyons Journal of Electroanalytical Chemistry 886, 115103 , 2021 2021 Citations: 45
Nonlinear mass transfer at the electrodes with reversible homogeneous; reactions: taylor'sseries and hyperbolic function method LC Mary, RU Rani, A Meena, L Rajendran International Journal of Electrochemical Science 16 (1), 151037 , 2021 2021 Citations: 26
Transport and Kinetics in Biofiltration Membranes: New Analytical Expressions for Concentration Profiles of Hydrophilic and Hydrophobic VOCs Using Taylor’s Series and Akbari … SAS Sivasundari, RU Rani, MEG Lyons, L Rajendran International Journal of Electrochemical Science 17 (4), 220447 , 2022 2022 Citations: 20
Mathematical modelling of Amperometric Glucose biosensor based on immobilized Enzymes: New approach of Taylors series method KL Narayanan, J Kavitha, RU Rani, MEG Lyons, L Rajendran International Journal of Electrochemical Science 17 (10), 221064 , 2022 2022 Citations: 17
Mathematical modelling of forced convection in a porous medium for a general geometry: Solution of thermal energy equation via Taylor’s series with Ying Buzu algorithms KL Narayanan, R Shanthi, RU Rani, MEG Lyons, L Rajendran International Journal of Electrochemical Science 17 (6), 220623 , 2022 2022 Citations: 14
Theoretical analysis of homogeneous catalysis of electrochemical reactions: steady-state current–potential RU Rani, L Rajendran, M Abukhaled Reaction Kinetics, Mechanisms and Catalysis 136 (3), 1229-1242 , 2023 2023 Citations: 12
Theoretical analysis of amperometric response towards PPO-based rotating disk bioelectrodes: Taylors series and hyperbolic function method V Silambuselvi, S Rekha, RU Rani, K Angaleeswari International Journal of Electrochemical Science 18 (4), 100083 , 2023 2023 Citations: 10
A New Method to Study the Nonlinear Reaction-Diffusion Process in the Electroactive Polymer Film using Hyperbolic Function Method * Sekar Rekha1 , Ramu Usha Rani2 , Lakshmanan Rajendran1,*, Michael E.G. Lyons3 International Journal of ELECTROCHEMICAL SCIENCE 17, 221261 , 2022 2022 Citations: 10
Approximations for the Concentration and Effectiveness Factor in Porous Catalysts of Arbitrary Shape: Taylor Series and Akbari-Ganji’s Methods MA Ramu Usha Rani 1 , Lakshmanan Rajendran 1* Mathematical Modelling of Engineering Problems 8 (4), 527-537 , 2021 2021 Citations: 8
Diffusion indicator for hemispheroidal and ring ultramicroelectrode geometries for E and ECʹ reactions RU Rani, L Rajendran Electrochemistry Communications 128, 107071 , 2021 2021 Citations: 8
Understanding the nonlinear reactive transport model in porous catalysts D Sujatha, RU Rani, G Vennila, A Marimuthu, M Renugadevi, ... International Journal of Electrochemical Science 19 (12), 100852 , 2024 2024 Citations: 5
A theoretical and computational analysis of the concentration of substrate and product in enzyme-based electrochemical biosensors: Akbari-Ganji’s method RU Rani, N Jha, L Rajendran Journal of Electroanalytical Chemistry 956, 118077 , 2024 2024 Citations: 4
Approximate analytical solution of nonlinear equations in cubic auto-catalytic reaction-diffusion process RU Rani, L Rajendran AIP Conference Proceedings 2277 (1), 130006 , 2020 2020 Citations: 4
Theoretical analysis of the enzyme reaction processes within the multiscale porous biocatalytic electrodes: Akbari–Ganji's and Taylor’s series method S Krishnakumar, RU Rani, KL Narayanan, L Rajendran International Journal of Electrochemical Science 19 (4), 100527 , 2024 2024 Citations: 3
Theoretical Analysis of Nonlinear Process in Amperometric Biosensor Using Akbari–Ganji and Hyperbolic Function Method SD Rajachelin, RU Rani, L Rajendran Chemistry Africa 8 (7), 3213-3227 , 2025 2025 Citations: 1
Unraveling nonlinear, transient nth-order reaction–diffusion processes within porous catalysts of arbitrary shapes: Analytical and numerical perspective RU Rani, L Rajendran Chemical Engineering Science, 122431 , 2025 2025 Citations: 1
Analytical and numerical solutions of nonlinear heat diffusion model for the thermal energy storage problem V Silambuselvi, K Angaleeswari, S Rekha, L Rajendran, RU Rani AIP Conference Proceedings 3160 (1), 020001 , 2024 2024 Citations: 1
Analytical expressions for steady-state current and estimation of kinetic parameters in an amperometric biosensor with the product inhibition: Power series method J Saranya, RU Rani, MEG Lyons, M Abukhaled, L Rajendran AIP Conference Proceedings 2516 (1), 250017 , 2022 2022 Citations: 1
Taylor’s Series Solution of a Singular BVP of Reaction cum Diffusion in a Biocatalyst LR • R. Usha Rani Emerging Technologies and Innovative Research in Science, Engineering and … , 2021 2021