@poliupg.ac.id
Jurusan Teknik Kimia, Prodi Analisis Kimia
Politeknik Negeri Ujung Pandang
Electrochemistry, Inorganic Chemistry, Chemical Engineering, Materials Chemistry
Scopus Publications
Scholar Citations
Scholar h-index
Scholar i10-index
Mohamed Nasreldin, Roger Delattre, Cyril Calmes, Marc Ramuz, Vinsensia Ade Sugiawati, et al.
Energy Storage Materials, 2020
The recent advances in wearable technologies had caused a surge in the demand for stretchable Li-ion microbatteries. Herein, a special design based on micropillar electrodes supported on metallic serpentines has been investigated to achieve the fabrication of a functionning device. Besides achieving high areal capacity values like 2.5 mA h cm−2 at C/10 (i.e. 0.07 mA cm−2), the micropillars make the system reversibly stretchable. Electrochemical tests revealed excellent performance when the stretchable micropower source was subjected to different mechanical strains. Indeed, 73% of the capacity is retained over 100 cycles under 30% strain and all fatigue tests showed that capacity retention remain higher than 70%.
Vinsensia Ade Sugiawati, Florence Vacandio, Thierry Djenizian
Molecules, 2020
All-solid-state batteries were fabricated by assembling a layer of self-organized TiO2 nanotubes grown on as anode, a thin-film of polymer as an electrolyte and separator, and a layer of composite LiFePO4 as a cathode. The synthesis of self-organized TiO2 NTs from Ti-6Al-4V alloy was carried out via one-step electrochemical anodization in a fluoride ethylene glycol containing electrolytes. The electrodeposition of the polymer electrolyte onto anatase TiO2 NTs was performed by cyclic voltammetry. The anodized Ti-6Al-4V alloys were characterized by scanning electron microscopy and X-ray diffraction. The electrochemical properties of the anodized Ti-6Al-4V alloys were investigated by cyclic voltammetry and chronopotentiometry techniques. The full-cell shows a high first-cycle Coulombic efficiency of 96.8% with a capacity retention of 97.4% after 50 cycles and delivers a stable discharge capacity of 63 μAh cm−2 μm−1 (119 mAh g−1) at a kinetic rate of C/10.
Vinsensia Ade Sugiawati, Florence Vacandio, Neta Yitzhack, Yair Ein-Eli, Thierry Djenizian
Polymers, 2020
Carbon nanotubes (CNT) are used as anodes for flexible Li-ion micro-batteries. However, one of the major challenges in the growth of flexible micro-batteries with CNT as the anode is their immense capacity loss and a very low initial coulombic efficiency. In this study, we report the use of a facile direct pre-lithiation to suppress high irreversible capacity of the CNT electrodes in the first cycles. Pre-lithiated polymer-coated CNT anodes displayed good rate capabilities, studied up to 30 C and delivered high capacities of 850 mAh g−1 (313 μAh cm−2) at 1 C rate over 50 charge-discharge cycles.
V. A. Sugiawati, F. Vacandio, C. Perrin-Pellegrino, A. Galeyeva, A. P. Kurbatov, et al.
Scientific Reports, 2019
The increasing demands from micro-power applications call for the development of the electrode materials for Li-ion microbatteries using thin-film technology. Porous Olivine-type LiFePO4 (LFP) and NASICON-type Li3Fe2(PO4)3 have been successfully fabricated by radio frequency (RF) sputtering and post-annealing treatments of LFP thin films. The microstructures of the LFP films were characterized by X-ray diffraction and scanning electron microscopy. The electrochemical performances of the LFP films were evaluated by cyclic voltammetry and galvanostatic charge-discharge measurements. The deposited and annealed thin film electrodes were tested as cathodes for Li-ion microbatteries. It was found that the electrochemical performance of the deposited films depends strongly on the annealing temperature. The films annealed at 500 °C showed an operating voltage of the porous LFP film about 3.45 V vs. Li/Li+ with an areal capacity of 17.9 µAh cm−2 µm−1 at C/5 rate after 100 cycles. Porous NASICON-type Li3Fe2(PO4)3 obtained after annealing at 700 °C delivers the most stable capacity of 22.1 µAh cm−2 µm−1 over 100 cycles at C/5 rate, with an operating voltage of 2.8 V vs. Li/Li+. The post-annealing treatment of sputtered LFP at 700 °C showed a drastic increase in the electrochemical reactivity of the thin film cathodes vs. Li+, leading to areal capacity ~9 times higher than as-deposited film (~27 vs. ~3 µAh cm−2 µm−1) at C/10 rate.
Vinsensia Ade Sugiawati, Florence Vacandio, Alina Galeyeva, Andrey P. Kurbatov, Thierry Djenizian
Frontiers in Physics, 2019
Self-organized TiO2 nanotubes grown on Ti grid acting as anode for Li-ion microbatteries were prepared via an electrochemical anodization. By tuning the anodization time, the morphology and length of the nanotubes were investigated by scanning electron microscope. When the anodization time reached 1.5 h, the TiO2nts/Ti grid anode showed a well-defined nanotubes, which are stable, well adherent ~90 nm with a length of 1.88 µm. Due to their high surface utilization, surface area and material loading per unit area, TiO2nts /Ti grid anode using polymer electrolyte exhibited a high areal capacity of 376 µAh cm-2 at C/10 rate and a stable discharge plateau at 1.8 V without using a polymer binder and conductive additive. The storage capacity of the TiO2nts/Ti grid after 10 cycles is fifteen times higher compared to previous reports using planar Ti foils.
Vinsensia Ade Sugiawati, Florence Vacandio, Yair Ein-Eli, Thierry Djenizian
APL Materials, 2019
Polymer-coated Carbon Nanotube (CNT) tissues are very flexible and lightweight and have high potential as an anode material for flexible Li-ion microbatteries. The electrochemical deposition of p-sulfonated poly(allyl phenyl ether) (SPAPE) polymer electrolyte into CNT tissues has been accomplished using a cyclic voltammetry (CV) technique. When compared to a pristine CNT tissue, the capacity of SPAPE-coated CNT tissue after 10 cycles of CV is improved about 67% at 1C rate. The enhancement of electrochemical performance is obtained when the CNT tissues are coated with the SPAPE polymer electrolyte. The higher capacity of the SPAPE-coated CNT tissue is attributed to the increased surface area and the improved quality of the electrode/electrolyte interfaces between the nanotubes and the polymer electrolyte. The SPAPE-coated CNT tissue delivers a higher reversible capacity of 750 mAh g−1 (276 µAh cm−2) compared to a pristine CNT tissue, which solely provides a reversible capacity of 450 mAh g−1 (166 µAh cm−2) after 110 cycles at 1C rate. Remarkably, the SPAPE-coated CNT tissue reaches a high capacity up to 12C rate while observing that the capacity can be significantly recovered.Polymer-coated Carbon Nanotube (CNT) tissues are very flexible and lightweight and have high potential as an anode material for flexible Li-ion microbatteries. The electrochemical deposition of p-sulfonated poly(allyl phenyl ether) (SPAPE) polymer electrolyte into CNT tissues has been accomplished using a cyclic voltammetry (CV) technique. When compared to a pristine CNT tissue, the capacity of SPAPE-coated CNT tissue after 10 cycles of CV is improved about 67% at 1C rate. The enhancement of electrochemical performance is obtained when the CNT tissues are coated with the SPAPE polymer electrolyte. The higher capacity of the SPAPE-coated CNT tissue is attributed to the increased surface area and the improved quality of the electrode/electrolyte interfaces between the nanotubes and the polymer electrolyte. The SPAPE-coated CNT tissue delivers a higher reversible capacity of 750 mAh g−1 (276 µAh cm−2) compared to a pristine CNT tissue, which solely provides a reversible capacity of 450 mAh g−1 (166 µAh cm−2)...
Henia Fraoucene, Vinsensia Ade Sugiawati, Djedjiga Hatem, Mohammed Said Belkaid, Florence Vacandio, et al.
Frontiers in Chemistry, 2019
Due to their high specific surface area and advanced properties, TiO2 nanotubes (TiO2 NTs) have a great significance for production and storage of energy. In this paper, TiO2 NTs were synthesized from anodization of Ti-6Al-4V alloy at 60 V for 3 h in fluoride ethylene glycol electrolyte by varying the water content and further annealing treatment. The morphological, structural, optical and electrochemical performances of TiO2 NTs were investigated by scanning electron microscope (SEM), energy dispersive X-ray spectroscopy (EDS), X-ray diffraction (XRD), UV-Visible spectroscopy and electrochemical characterization techniques. By varying the water content in the solution, a honeycomb and porous structure was obtained at low water content and the presence of (α + β) phase in Ti-6Al-4V alloy caused not uniform etching. With an additional increase in water content, a nanotubular structure is formed in the (α + β) phases with different morphological parameters. The anatase TiO2 NTs synthesized with 20 wt% H2O shows an improvement in absorption band that extends into the visible region due the presence of vanadium oxide in the structure and the effective band gap energy (Eg) value of 2.25 eV. The TiO2 NTs electrode also shows a good cycling performance, delivering a reversible capacity of 82 mAh.g−1 (34 μAh.cm−2.μm−1) at 1C rate over 50 cycles.
Vinsensia Ade Sugiawati, Florence Vacandio, Philippe Knauth, Thierry Djenizian
Chemistryselect, 2018
Vinsensia Ade Sugiawati, Florence Vacandio, Marielle Eyraud, Philippe Knauth, Thierry Djenizian
Nanoscale Research Letters, 2016
We report the electrochemical performance of porous NASICON-type Li3Fe2(PO4)3 thin films to be used as a cathode for Li-ion microbatteries. Crystalline porous NASICON-type Li3Fe2(PO4)3 layers were obtained by radio frequency sputtering with an annealing treatment. The thin films were characterized by XRD, SEM, and electrochemical techniques. The chronoamperometry experiments showed that a discharge capacity of 88 mAhg−1 (23 μAhcm−2) is attained for the first cycle at C/10 to reach 65 mAhg−1 (17 μAhcm−2) after 10 cycles with a good stability over 40 cycles.
A Sukasri, J Manga, R Ridhawati, M Mahyati, MAN Ole, M Septiani, ...
Seminar Nasional Hasil Penelitian & Pengabdian Kepada Masyarakat (SNP2M) 9 … , 2025
2025
L Marlina, Z Anisa, C Cengristitama, MW Sari, VA Sugiawati, Z Azizah, ...
CV. Gita Lentera , 2024
2024
Citations: 1
E Novra, SST Par, M Par
Fun English Club Activities in 21st Century, 124 , 2024
2024
LM Bambang Suhartawan,Hasmah, Ifan Wiranto, Cengristitama, Sestry Misfadhila ...
CV. Gita Lentera , 2024
2024
S Mahaly, D Misnawati, AP Farahdiansari, T Ernawati, F Hasnah, ...
CV. Gita Lentera , 2024
2024
Citations: 2
VAS Sawal Mahaly, Desy Misnawati. Ardana Putri Farahdiansari, Tati Ernawati ...
https://gitalentera.com/book-published/menulis-karya-ilmiah/ , 2024
2024
F Vacandio
240th ECS Meeting (October 10-14, 2021) , 2021
2021
M Nasreldin, R Delattre, C Calmes, M Ramuz, VA Sugiawati, S Maria, ...
Energy Storage Materials 33, 108-115 , 2020
2020
Citations: 65
MAS Nasreldin
Université de Lyon , 2020
2020
VA Sugiawati, F Vacandio, T Djenizian
Molecules 25 (9), 2121 , 2020
2020
Citations: 18
T Djenizian, NH Voelcker
Frontiers Media SA , 2020
2020
VA Sugiawati, F Vacandio, N Yitzhack, Y Ein-Eli, T Djenizian
Polymers 12 (2), 406 , 2020
2020
Citations: 48
M Nasreldin, R Delattre, C Calmes, M Ramuz, VA Sugiawati, S Maria
Energy Storage Mater 33, 108-115 , 2020
2020
Citations: 10
VA Sugiawati, F Vacandio, A Galeyeva, AP Kurbatov, T Djenizian
Frontiers in Physics 7, 179 , 2019
2019
Citations: 31
VA Sugiawati, F Vacandio, C Perrin-Pellegrino, A Galeyeva, AP Kurbatov, ...
Scientific Reports 9 (1), 11172 , 2019
2019
Citations: 38
VA Sugiawati, F Vacandio, Y Ein-Eli, T Djenizian
Electrochemical Society Meeting Abstracts 235, 303-303 , 2019
2019
Citations: 1
VA Sugiawati, F Vacandio, T Djenizian
Electrochemical Society Meeting Abstracts 235, 154-154 , 2019
2019
G GAUTIER
Aix-Marseille Université , 2019
2019
VA Sugiawati
Aix-Marseille , 2019
2019
VA Sugiawati, F Vacandio, Y Ein-Eli, T Djenizian
APL Materials 7 (3) , 2019
2019
Citations: 17
M Nasreldin, R Delattre, C Calmes, M Ramuz, VA Sugiawati, S Maria, ...
Energy Storage Materials 33, 108-115 , 2020
2020
Citations: 65
H Fraoucene, VA Sugiawati, D Hatem, MS Belkaid, F Vacandio, M Eyraud, ...
Frontiers in chemistry 7, 66 , 2019
2019
Citations: 53
VA Sugiawati, F Vacandio, N Yitzhack, Y Ein-Eli, T Djenizian
Polymers 12 (2), 406 , 2020
2020
Citations: 48
VA Sugiawati, F Vacandio, C Perrin-Pellegrino, A Galeyeva, AP Kurbatov, ...
Scientific Reports 9 (1), 11172 , 2019
2019
Citations: 38
VA Sugiawati, F Vacandio, A Galeyeva, AP Kurbatov, T Djenizian
Frontiers in Physics 7, 179 , 2019
2019
Citations: 31
VA Sugiawati, F Vacandio, M Eyraud, P Knauth, T Djenizian
Nanoscale research letters 11 (1), 365 , 2016
2016
Citations: 27
VA Sugiawati, F Vacandio, T Djenizian
Molecules 25 (9), 2121 , 2020
2020
Citations: 18
VA Sugiawati, F Vacandio, Y Ein-Eli, T Djenizian
APL Materials 7 (3) , 2019
2019
Citations: 17
VA Sugiawati
Jurnal Nalar Pendidikan 1 (1), 554643 , 2013
2013
Citations: 16
VA Sugiawati, F Vacandio, P Knauth, T Djenizian
ChemistrySelect 3 (2), 405-409 , 2018
2018
Citations: 12
M Nasreldin, R Delattre, C Calmes, M Ramuz, VA Sugiawati, S Maria
Energy Storage Mater 33, 108-115 , 2020
2020
Citations: 10
H Fraoucene, VA Sugiawati, D Hatem, MS Belkaid, F Vacandio, M Eyraud, ...
2019
Citations: 6
S Mahaly, D Misnawati, AP Farahdiansari, T Ernawati, F Hasnah, ...
CV. Gita Lentera , 2024
2024
Citations: 2
L Marlina, Z Anisa, C Cengristitama, MW Sari, VA Sugiawati, Z Azizah, ...
CV. Gita Lentera , 2024
2024
Citations: 1
VA Sugiawati, F Vacandio, Y Ein-Eli, T Djenizian
Electrochemical Society Meeting Abstracts 235, 303-303 , 2019
2019
Citations: 1
VA Sugiawati
ECS Meeting Abstract , 2019
2019
Citations: 1
A Sukasri, J Manga, R Ridhawati, M Mahyati, MAN Ole, M Septiani, ...
Seminar Nasional Hasil Penelitian & Pengabdian Kepada Masyarakat (SNP2M) 9 … , 2025
2025
E Novra, SST Par, M Par
Fun English Club Activities in 21st Century, 124 , 2024
2024
LM Bambang Suhartawan,Hasmah, Ifan Wiranto, Cengristitama, Sestry Misfadhila ...
CV. Gita Lentera , 2024
2024
VAS Sawal Mahaly, Desy Misnawati. Ardana Putri Farahdiansari, Tati Ernawati ...
https://gitalentera.com/book-published/menulis-karya-ilmiah/ , 2024
2024