Exploring the tetragonal crystal structure of perovskites BaLa2Cu1−x Ba xTi2O9 (x = 0.00, 0.15, 0.30) via X-ray diffraction and the Rietveld method Abdelhadi El Hachmi Powder Diffraction, 2025 BaLa 2 Cu 1− x Ba x Ti 2 O 9 ( x = 0.00, 0.15, and 0.30) ceramics were synthesized in polycrystalline form via the conventional solid-state reaction techniques in air. The crystal structure of the title compositions was characterized by room-temperature X-ray powder diffraction and analyzed using the Rietveld refinement method. All the compositions crystallize in the tetragonal symmetry of space group I 4/ mcm (No. 140) with cell volumes: 249.43(1) Å 3 for x = 0.00, 249.42(1) Å 3 for x = 0.15, and 250.05(1) Å 3 for x = 0.30. The tilt system of the M O 6 octahedra ( M = Cu(Ba2)/Ti) corresponds to the notation a 0 a 0 c − . The M O 6 octahedra share the corners via oxygen atoms in 3 D. Along the c -axis, the octahedra are connected by O(1) atoms of (0, 0, 1/4) positions; while in the ab -plane, they are linked by O(2) atoms of ( x , x + 1/2, 0) positions. The bond angle of M –O2– M is 168.6(7)° for x = 0.00, 168.6(6)° for x = 0.15, and 166.8(6)° for x = 0.30, whereas the bond angle of M –O1– M is constrained to be 180° by space group I 4/ mcm.
Crystal chemistry and structural phase transition in CaLa2Zn1–xCaxTi2O9 (x = 0.00, 0.15, 0.30, 0.45, 0.90 and 1.00) Abdelhadi El Hachmi, Leila Loubbidi, Brahim El Ghmari, Brahim Arfoy, El Hossain Chtoun, et al. Zeitschrift Fur Naturforschung Section B Journal of Chemical Sciences, 2025 Polycrystalline materials with the compositions CaLa2Zn1−x Ca x Ti2O9 (x = 0.00, 0.15, 0.30, 0.45, 0.90 and 1.00) were synthesized via the conventional solid-state reaction method under ambient conditions. Their crystal structures were determined at room temperature from powder X-ray diffraction (XRPD) using the Rietveld method. For compositions with x = 0.00, 0.15, 0.30, and 0.45, the structures crystallize in the orthorhombic space group Pbnm, with the octahedra tilting in-phase along the [001] direction, and out-of-phase along the [100] and [010] directions of the pseudocubic cell; corresponding to the tilt system a − a − c +. Compositions with x = 0.90 and 1.00 adopt the monoclinic space group P21/n, with the octahedra tilting in-phase along the c axis and out-of-phase along the a and b axes, consistent with the tilt system a − b − c +. In both structural models, the frameworks consist of corner-sharing BO6 octahedra in three dimensions. The structural distortion of the monoclinic phases indicates partial 1:1 B-site ordering between Ti4+ (occupying the 2c site) and a random mixture of 2/3 (Zn2+ 1−x Ca2+ x ) and 1/3 Ti4+ (occupying the 2d site). Along the c axis, the B–O1–B bond angles in the orthorhombic phases (B = Zn(Ca2)/Ti) were calculated to be 156.3° (x = 0.00), 157.3° (x = 0.15), 154.8° (x = 0.30), and 157.2° (x = 0.45). In contrast, the Ti1–O3–B′ bond angles in the monoclinic phases (B′ = Zn(Ca2)/Ti2) were found to be 158.5° (x = 0.90) and 158.3° (x = 1.00). These materials could have promising potential for applications in electrical and dielectric devices.
Linear and non-linear optical properties of FeSnO(OH)5 oxyhydroxide perovskite Abdelhadi El Hachmi, Goutam Biswas, Subhadeep Sen, Bouchaib Manoun, Khalid Draoui, et al. Journal of Materials Chemistry C, 2025 This work investigates the optical parameters of jeanbandyite to assess its potential applications for optoelectronic devices.
Electrochemical hydrogen storage in tunable oxide frameworks: Advances and prospects in pyrochlore and perovskite materials B Arfoy, M Elmourabit, M Douma, A El Hachmi, L Loubbidi, EH Chtoun International Journal of Hydrogen Energy 226, 154602 , 2026 2026
Study of the structural, optical, and electronic properties of gadolinium orthophosphate: a combination of experimental and theoretical studies I Abdelrhafor, LH Omari, M Lassri, S Tarik, A El Hachmi, H Lassri, EK Hlil, ... Materials Advances , 2026 2026
Correction: Structural, optical, and electronic properties of europium orthophosphate: a combination of experimental and theoretical studies I Abdelrhafor, LH Omari, M Lassri, L Abbassi, A El Hachmi, S Tarik, ... Journal of Materials Chemistry C 14 (13), 5570-5570 , 2026 2026
Structural, optical, and electronic properties of europium orthophosphate: a combination of experimental and theoretical studies I Abdelrhafor, LH Omari, M Lassri, L Abbassi, A El Hachmi, S Tarik, ... Journal of Materials Chemistry C , 2026 2026 Citations: 1
Synthesis and investigation of structural and linear/non-linear optical properties of T’- cuprate A Elgharbi, M Sadik, M Lassri, AE Hachmi, M Oubla, H Lassri, M Abid, ... Journal of Materials Science: Materials in Electronics 37 (2), 153 , 2026 2026
Exploring the tetragonal crystal structure of perovskites BaLa2Cu1− xBaxTi2O9 (x= 0.00, 0.15, 0.30) via X-ray diffraction and the Rietveld method A El Hachmi Powder Diffraction, 1-7 , 2025 2025
Photocatalytic degradation of tetracycline using ZnO-modified Y2Ti2O7 nanoparticles B Arfoy, I Khaddodi, L Loubbidi, M Elmourabit, O El Haddade, I Allaoui, ... Micro and Nanostructures, 208508 , 2025 2025
Comprehensive Structural and Optical Characterization of Zinc-Doped Gadolinium Titanate Pyrochlore Solid Solutions O El Haddade, B Arfoy, M Douma, A El Hachmi, L Loubbidi, A Lamhamdi, ... Moroccan Journal of Chemistry 13 (4), J. Chem. 13 (4)-1950 , 2025 2025
Large reversible magnetocaloric effect in GdPO4 nano-spherical particles at ultralow temperatures M Lassri, S El Ouahbi, I Abdelrhafore, LEH Omari, A El Hachmi, ... Journal of Magnetism and Magnetic Materials 629, 173291 , 2025 2025 Citations: 1
Floatable clay-alginate beads for water treatment: Experimental and molecular modeling approaches to Pb (II) and malachite green removal H Abara, J Raissouni, H Saadani, A El Hachmi, M Hadri, K Draoui International Journal of Biological Macromolecules, 146481 , 2025 2025 Citations: 3
Crystal chemistry and structural phase transition in CaLa2Zn1–x Ca x Ti2O9 (x= 0.00, 0.15, 0.30, 0.45, 0.90 and 1.00) A El Hachmi, L Loubbidi, B El Ghmari, B Arfoy, EH Chtoun, B Manoun Zeitschrift für Naturforschung B 80 (6-7), 223-232 , 2025 2025 Citations: 1
Linear and non-linear optical properties of FeSnO (OH) 5 oxyhydroxide perovskite A El Hachmi, G Biswas, S Sen, B Manoun, K Draoui, Z Sadoune Journal of Materials Chemistry C 13 (13), 6630-6640 , 2025 2025 Citations: 6
Synthesis and structural characterization of new perovskite phases, Ba2Bi0. 572TeO6±δ and SrLa2NiFeNbO9 A El Hachmi, Z Sadoune Powder Diffraction 39 (4), 235-244 , 2024 2024 Citations: 2
Large magnetocaloric effect and magnetic properties of EuRhO3 M Lassri, M Sajieddine, A Elouafi, A El Hachmi, S El Ouahbi, R Moubah Journal of Rare Earths 42 (9), 1724-1729 , 2024 2024 Citations: 19
Electrical resistivity and magnetoresistance of Sr3Fe2+ xMo1–xO9–3x/2 (x= 0.45, 0.60, and 1.00) prepared by the solid-state reaction A El Hachmi, S El Ouahbi, Y Ounza, G Biswas, H Lassri, B Manoun, ... Solid State Communications 387, 115534 , 2024 2024 Citations: 4
Optical properties investigation of Sr2CaFe2WO9 triple perovskite for optoelectronic applications Y Arba, Z Yamkane, J Louafi, A Elouafi, A El Hachmi, S El Ouahbi, ... Optik 288, 171153 , 2023 2023 Citations: 32
Structural, morphological, magnetic and optical properties of Jeanbandyite prepared by the co-precipitation method A El Hachmi, S Sen, R Mondal, M Paul, A Saha, J Im, G Biswas Materials Today Communications 34, 105358 , 2023 2023 Citations: 12
Complex dielectric, electric modulus, impedance, and optical conductivity of Sr 3− x Pb x Fe 2 TeO 9 ( x = 1.50, 1.88 and 2.17) A El Hachmi, B Manoun International Journal of Materials Research 114 (2), 100-111 , 2023 2023 Citations: 24
Magnetic, Magnetocaloric Properties and Phenomenological Model of Perovskite Type: Sr 3 Fe 2+ x Mo 1− x O 9−3 x /2 ( x = 0.45, 0.60, and 1.00) AE Hachmi, SE Ouahbi, B Manoun, H Lassri Journal of Superconductivity and Novel Magnetism 35 (5), 1299-1306 , 2022 2022 Citations: 12
Structural, magnetic and optical properties study of tellurium–based: Sr3–xPbxFe2TeO9 (0≤ x≤ 2.25) double perovskites A El Hachmi, B Manoun, M Sajieddine, P Lazor Acta Cryst 77, C496 , 2021 2021
MOST CITED SCHOLAR PUBLICATIONS
Optical properties investigation of Sr2CaFe2WO9 triple perovskite for optoelectronic applications Y Arba, Z Yamkane, J Louafi, A Elouafi, A El Hachmi, S El Ouahbi, ... Optik 288, 171153 , 2023 2023 Citations: 32
Complex dielectric, electric modulus, impedance, and optical conductivity of Sr 3− x Pb x Fe 2 TeO 9 ( x = 1.50, 1.88 and 2.17) A El Hachmi, B Manoun International Journal of Materials Research 114 (2), 100-111 , 2023 2023 Citations: 24
Large magnetocaloric effect and magnetic properties of EuRhO3 M Lassri, M Sajieddine, A Elouafi, A El Hachmi, S El Ouahbi, R Moubah Journal of Rare Earths 42 (9), 1724-1729 , 2024 2024 Citations: 19
Temperature induced structural phase transition in Sr3-xCaxFe2TeO9 (0≤ x≤ 1) probed by Raman and Mossbauer techniques A El Hachmi, B Manoun, Y Tamraoui, F Mirinioui, R Abkar, I Saadoune, ... Journal of Molecular Structure 1141, 484-494 , 2017 2017 Citations: 17
Temperature and composition induced phase transitions in Sr2− xCa1+ xTeO6 (0≤ x≤ 2) double perovskite oxides Y Tamraoui, B Manoun, F Mirinioui, I Saadoune, R Haloui, A Elhachmi, ... Journal of Molecular Structure 1131, 103-113 , 2017 2017 Citations: 17
Synthesis, structural and optical properties of perovskites-type: Sr3Fe2+ xMo1− xO9− 3x/2 (x= 0.30, 0.45, 0.60, 0.75 and 1.00) A El Hachmi, B Manoun, M Sajieddine, Y Tamraoui, S El Ouahbi Polyhedron 200, 115133 , 2021 2021 Citations: 14
Synthesis and Rietveld refinements of new ceramics Sr2CaFe2WO9 and Sr2PbFe2TeO9 perovskites A El Hachmi, Y Tamraoui, B Manoun, R Haloui, MA Elaamrani, ... Powder Diffraction 33 (2), 134-140 , 2018 2018 Citations: 13
Structural, morphological, magnetic and optical properties of Jeanbandyite prepared by the co-precipitation method A El Hachmi, S Sen, R Mondal, M Paul, A Saha, J Im, G Biswas Materials Today Communications 34, 105358 , 2023 2023 Citations: 12
Magnetic, Magnetocaloric Properties and Phenomenological Model of Perovskite Type: Sr 3 Fe 2+ x Mo 1− x O 9−3 x /2 ( x = 0.45, 0.60, and 1.00) AE Hachmi, SE Ouahbi, B Manoun, H Lassri Journal of Superconductivity and Novel Magnetism 35 (5), 1299-1306 , 2022 2022 Citations: 12
Structural, Magnetic and Optical Properties Study of Tellurium-Based Perovskites: Sr 3−x Pb x Fe 2 TeO 9 (0 ≤ x ≤ 2.25) A El Hachmi, F El Bachraoui, S Louihi, Y Tamraoui, S Benmokhtar, L Bih, ... Journal of Inorganic and Organometallic Polymers and Materials 30 (6), 1990-2006 , 2020 2020 Citations: 11
Argile et minéraux argileux: propriétés physico-chimiques et propriétés et propriétés colloàdes A EL HACHMI Mémoire Online , 2013 2013 Citations: 11
Linear and non-linear optical properties of FeSnO (OH) 5 oxyhydroxide perovskite A El Hachmi, G Biswas, S Sen, B Manoun, K Draoui, Z Sadoune Journal of Materials Chemistry C 13 (13), 6630-6640 , 2025 2025 Citations: 6
Structural and Mössbauer Studies of Sr 1.5 Ca 1.5 Fe 2.25 Mo 0.75 O 9−δ and Sr 1.92 Ca 1.08 Fe 2.04 W 0.96 O 9−δ Double Perovskites A El Hachmi, B Manoun, Y Tamraoui, S Louihi, L Bih, M Sajieddine, ... Journal of Structural Chemistry 61 (6), 861-872 , 2020 2020 Citations: 5
Electrical resistivity and magnetoresistance of Sr3Fe2+ xMo1–xO9–3x/2 (x= 0.45, 0.60, and 1.00) prepared by the solid-state reaction A El Hachmi, S El Ouahbi, Y Ounza, G Biswas, H Lassri, B Manoun, ... Solid State Communications 387, 115534 , 2024 2024 Citations: 4
Crystal structure and phase transitions in new series of double perovskite oxides Ba2-xSrxCaTeO6 (0≤ x≤ 2): X-ray diffraction and Raman spectroscopy studies R Haloui, B Manoun, S Louihi, M Jahid, A El Hachmi, R Abkar Journal of Applied Surfaces and Interfaces 1 (1-3) , 2017 2017 Citations: 4
Floatable clay-alginate beads for water treatment: Experimental and molecular modeling approaches to Pb (II) and malachite green removal H Abara, J Raissouni, H Saadani, A El Hachmi, M Hadri, K Draoui International Journal of Biological Macromolecules, 146481 , 2025 2025 Citations: 3
On the structural phase transitions and optical properties of Sr 2 Sr 1-x Ca x TeO 6 (0 ≤ x ≤ 1) ceramics Y Tamraoui, F El Bachraoui, F Mirinioui, S Louihi, J Alami, I Saadoune, ... Journal of Electroceramics 46 (1), 1-13 , 2021 2021 Citations: 3
Synthesis and structural characterization of new perovskite phases, Ba2Bi0. 572TeO6±δ and SrLa2NiFeNbO9 A El Hachmi, Z Sadoune Powder Diffraction 39 (4), 235-244 , 2024 2024 Citations: 2
Structural, optical, and electronic properties of europium orthophosphate: a combination of experimental and theoretical studies I Abdelrhafor, LH Omari, M Lassri, L Abbassi, A El Hachmi, S Tarik, ... Journal of Materials Chemistry C , 2026 2026 Citations: 1
Large reversible magnetocaloric effect in GdPO4 nano-spherical particles at ultralow temperatures M Lassri, S El Ouahbi, I Abdelrhafore, LEH Omari, A El Hachmi, ... Journal of Magnetism and Magnetic Materials 629, 173291 , 2025 2025 Citations: 1