Stabilizing the Solid Electrolyte Interphase with Phenyl Isothiocyanate for Long-Cycle Lithium Metal Batteries Bushra Khan, Mohammad Nasir, Jae‐won Lee, Hee Jung Park Batteries and Supercaps, 2025 Lithium metal batteries possess great potential for portable electronic devices as a next‐generation secondary battery owing to their high specific capacity and energy density. However, their cycling stability is hindered by the formation of an unstable solid‐electrolyte interphase between the electrolyte and the Li anode, leading to poor cycling performance. Herein, phenyl isothiocyanate (PITC) has been introduced as an additive in a propylene carbonate (PC) electrolyte to stabilize the solid‐electrolyte interphase layer on the Li metal anode. The addition of PITC significantly improves the electrochemical performance of Li||Cu half‐cells, exhibiting a coulombic efficiency of 82%, and enhances cycling stability in Li||Li symmetric cells, with low polarization and a uniform solid‐electrolyte interface, as confirmed by scanning electron microscopy (SEM) analysis. In Li||LFP full cells, the optimized electrolyte demonstrated excellent cycling stability, maintaining a discharge capacity of 150 mAh g−1 after 650 cycles at a 1C rate. These results verify that PITC is an effective additive for PC‐based electrolytes, enhancing the longevity and stability of lithium metal batteries.
Multiscale magnetic correlations in : Role of crystal structure in double perovskites AK Bera, KS Chikara, B Saha, SM Yusuf, M Nasir, S Sen Physical Review B 112 (13), 134455 , 2025 2025
Excess-Lithium-Free LLZO Enabling Fast Ion Conduction and Ultra-Low Interfacial Resistance for Solid-State Lithium Metal Batteries M Nasir, J Seo, JI Song, YS Choi, HJ Park Energy Storage Materials, 104482 , 2025 2025 Citations: 3
Ultrastable Cycling in Li 1.5 Al 0.5 Ge 1.5 (PO 4 ) 3 -Based Solid Electrolytes via Pt-Engineered Interfaces SI Jung, M Nasir, HJ Park ACS Applied Energy Materials , 2025 2025 Citations: 3
Stabilizing the Solid Electrolyte Interphase with Phenyl Isothiocyanate for Long‐Cycle Lithium Metal Batteries B Khan, M Nasir, J Lee, HJ Park Batteries & Supercaps, e202500227 , 2025 2025
Lithium-Optimized Ga-Doped Li7La3Zr2O12 with Enhanced Conductivity and Interface Stability for Solid-State Lithium Batteries M Nasir, J Seo, HJ Park 247th ECS Meeting (May 18-22, 2025) , 2025 2025
Layered Two-Dimensional TiO 2 -PEO Composite Solid Electrolyte with High Lithium-Ion Conductivity for All-Solid-State Lithium Batteries J Seo, M Nasir, HJ Park 247th ECS Meeting (May 18-22, 2025) , 2025 2025
Lithium-Ion Conduction Pathways in LLZO-PEO Composite Solid Electrolytes J Seo, M Nasir, HJ Park ACS Applied Energy Materials 8 (3), 1518–1525 , 2025 2025 Citations: 19
Calcination-Driven Enhancement of LAGP for High-Performance Solid-State Lithium Metal Batteries SI Jung+, M Nasir+, HJ Park Journal of Materials Chemistry A 13 (6), 4624-4633 , 2025 2025 Citations: 9
Liquid Electrolyte-Assisted Stabilization of the LLZO/Li Interface for Stable Lithium Metal Batteries M Nasir, J Seo, SI Jung, HJ Park EES Batteries , 2025 2025 Citations: 3
Engineering Current Collector with 2D TiO2 Nanosheets for Stable Lithium Metal Batteries JS Park, M Nasir, D Kim, HM Jeong, HJ Park Batteries & Supercaps, e202400741 , 2025 2025 Citations: 1
Excellent electrochemical response of Ce stabilized cubic Li7La3Zr2O12 M Nasir, J Seo, JS Park, HJ Park Journal of the European Ceramic Society 44 (7), 4606-4611 , 2024 2024 Citations: 14
Investigating the Effect of Co-doping on Structural and Electrical Properties of Li7La3Zr2O12 Solid Electrolyte HJP Mohammad Nasir, Jun Seo, Jun Seo Park, Seo In Jung, Hee Jin Kim Ceramist 27 (1), 1-8 , 2024 2024 Citations: 6
Li‐La‐Zr‐O Garnets with High Li‐Ion Conductivity and Air‐Stability by Microstructure‐Engineering (Adv. Funct. Mater. 35/2023) M Nasir, JY Park, P Heo, KH Choi, HJ Park Advanced Functional Materials 33 (35), 2370208 , 2023 2023
Li‐La‐Zr‐O Garnets with High Li‐Ion Conductivity and Air‐Stability by Microstructure‐Engineering M Nasir, JY Park, P Heo, KH Choi, HJ Park Advanced Functional Materials 33 (35), 2303397 , 2023 2023 Citations: 55
Exploring complex magnetic behavior induced by Mn in LaNiO 3 perovskite A Ahmed, M Nasir, HJ Park, M Furquan, M Hashim, BS Choi Applied Physics A 129 (8), 581 , 2023 2023 Citations: 9
Synthesis of ultra-thin nanobelt-like vanadium-oxide and its abnormal optical-electrical properties HJ Park, JM Lee, M Nasir, SJ Yoo, CJ Choi, K Lee Ceramics International 49 (4), 6419-6428 , 2023 2023 Citations: 2
Study on the decisive factor for metal–insulator transitions in a LaVO 3 Mott–Hubbard insulator M Nasir, I Kim, K Lee, S Kim, KH Lee, HJ Park Physical Chemistry Chemical Physics 25 (5), 3942-3949 , 2023 2023 Citations: 5
Anomalous Optoelectric Properties of an Ultrathin Ruthenium Film with a Surface Oxide Layer for Flexible Transparent Conducting Electrodes JM Oh+, M Nasir+, B Ryu, HJ Yun, CJ Choi, JS Bae, HJ Park Advanced Functional Materials 32 (14), 2109330 , 2022 2022 Citations: 14
Enhanced B-site cation ordering and improved magnetic properties: Role of A-site Bi substitution in La2NiMnO6 double perovskites M Nasir, AK Pathak, J Kubik, D Malaviya, V Krupa, A Dasgupta, S Sen Journal of Alloys and Compounds 896, 162713 , 2022 2022 Citations: 19
Improved Room-Temperature Ferromagnetism in Nd-Doped SnO 2 Nanostructures through Defect Engineering A Ahmed, M Nasir, M Hashim, P Tripathi, BS Choi The Journal of Physical Chemistry C 125 (40), 22175-22187 , 2021 2021 Citations: 22
MOST CITED SCHOLAR PUBLICATIONS
Role of Antisite Disorder, Rare-Earth Size, and Superexchange Angle on Band Gap, Curie Temperature, and Magnetization of R 2 NiMnO 6 Double Perovskites M Nasir, S Kumar, N Patra, D Bhattacharya, SN Jha, DR Basaula, S Bhatt, ... ACS Applied Electronic Materials 1 (1), 141-153 , 2019 2019 Citations: 157
Influence of samarium doping on structural, elastic, magnetic, dielectric, and electrical properties of nanocrystalline cobalt ferrite M Hashim, N Boda, A Ahmed, SK Sharma, D Ravinder, E Sumalatha, ... Applied Physics A 127 (7), 526 , 2021 2021 Citations: 75
The effect of high temperature annealing on the antisite defects in ferromagnetic La2NiMnO6 double perovskite M Nasir, M Khan, S Kumar, S Bhatt, N Patra, D Bhattacharya, SN Jha, ... Journal of Magnetism and Magnetic Materials 483, 114-123 , 2019 2019 Citations: 56
Li‐La‐Zr‐O Garnets with High Li‐Ion Conductivity and Air‐Stability by Microstructure‐Engineering M Nasir, JY Park, P Heo, KH Choi, HJ Park Advanced Functional Materials 33 (35), 2303397 , 2023 2023 Citations: 55
Correlation of octahedral distortion with vibrational and electronic properties of LaFe1-xTixO3 nanoparticles EG Rini, A Paul, M Nasir, R Amin, MK Gupta, R Mittal, S Sen Journal of Alloys and Compounds 830, 154594 , 2020 2020 Citations: 37
Evidence of cluster-glass and Griffiths-like phases in partially ordered La2FeMnO6 double perovskite M Nasir, M Khan, SA Agbo, S Bhatt, S Kumar, S Sen Journal of Physics D: Applied Physics 53 (37), 375003 , 2020 2020 Citations: 33
Exploring the role of Fe substitution on electronic, structural, and magnetic properties of La 2 NiMnO 6 double perovskites M Nasir, M Khan, EG Rini, SA Agbo, S Sen Applied Physics A 127, 1-14 , 2021 2021 Citations: 30
Role of compensating Li/Fe incorporation in Cu 0.945 Fe 0.055− x Li x O: structural, vibrational and magnetic properties M Nasir, N Patra, MA Ahmed, DK Shukla, S Kumar, D Bhattacharya, ... RSC Advances 7 (51), 31970-31979 , 2017 2017 Citations: 28
Improved Room-Temperature Ferromagnetism in Nd-Doped SnO 2 Nanostructures through Defect Engineering A Ahmed, M Nasir, M Hashim, P Tripathi, BS Choi The Journal of Physical Chemistry C 125 (40), 22175-22187 , 2021 2021 Citations: 22
Influence of Cation Order and Valence States on Magnetic Ordering in La 2 Ni 1− x Mn 1+ x O 6 M Nasir, M Khan, S Bhatt, AK Bera, M Furquan, S Kumar, SM Yusuf, ... physica status solidi (b) 256 (11), 1900019 , 2019 2019 Citations: 22
Lithium-Ion Conduction Pathways in LLZO-PEO Composite Solid Electrolytes J Seo, M Nasir, HJ Park ACS Applied Energy Materials 8 (3), 1518–1525 , 2025 2025 Citations: 19
Enhanced B-site cation ordering and improved magnetic properties: Role of A-site Bi substitution in La2NiMnO6 double perovskites M Nasir, AK Pathak, J Kubik, D Malaviya, V Krupa, A Dasgupta, S Sen Journal of Alloys and Compounds 896, 162713 , 2022 2022 Citations: 19
X-ray structural studies on solubility of Fe substituted CuO M Nasir, N Patra, DK Shukla, D Bhattacharya, S Kumar, DM Phase, ... RSC advances 6 (105), 103571-103578 , 2016 2016 Citations: 19
Excellent electrochemical response of Ce stabilized cubic Li7La3Zr2O12 M Nasir, J Seo, JS Park, HJ Park Journal of the European Ceramic Society 44 (7), 4606-4611 , 2024 2024 Citations: 14
Anomalous Optoelectric Properties of an Ultrathin Ruthenium Film with a Surface Oxide Layer for Flexible Transparent Conducting Electrodes JM Oh+, M Nasir+, B Ryu, HJ Yun, CJ Choi, JS Bae, HJ Park Advanced Functional Materials 32 (14), 2109330 , 2022 2022 Citations: 14
Zn1− xSixO: Improved optical transmission and electrical conductivity T Srivastava, A Sadanandan, G Bajpai, S Tiwari, R Amin, M Nasir, ... Ceramics International 43 (7), 5668-5673 , 2017 2017 Citations: 14
Cluster spin-glass-like dynamics in Mn-rich La2Ni0. 5Mn1. 5O6 ferromagnetic insulator M Nasir, S Kumar, AK Bera, M Khan, SM Yusuf, S Sen Journal of Physics: Condensed Matter 33 (22), 225803 , 2021 2021 Citations: 11
Calcination-Driven Enhancement of LAGP for High-Performance Solid-State Lithium Metal Batteries SI Jung+, M Nasir+, HJ Park Journal of Materials Chemistry A 13 (6), 4624-4633 , 2025 2025 Citations: 9
Exploring complex magnetic behavior induced by Mn in LaNiO 3 perovskite A Ahmed, M Nasir, HJ Park, M Furquan, M Hashim, BS Choi Applied Physics A 129 (8), 581 , 2023 2023 Citations: 9
Cu 1– x Fe x O: hopping transport and ferromagnetism M Nasir, R Islam, MA Ahmed, S Ayaz, G Kumar, S Kumar, CL Prajapat, ... Royal Society Open Science 4 (9), 170339 , 2017 2017 Citations: 9
