Chemistry, Inorganic Chemistry, Physical and Theoretical Chemistry, Catalysis
2
Scopus Publications
20
Scholar Citations
3
Scholar h-index
1
Scholar i10-index
Scopus Publications
Catalytic and efficient synthesis of optically active terminal epoxides and 1,2-diols using a new lanthanum triflate assisted c1-symmetric bimetallic chiral salen cobalt complex Deepak Patel, Santosh Singh Thakur, Sandip S. Shinde, Pradeep Kumar Letters in Organic Chemistry, 2018 The catalytic asymmetric synthesis of terminal epoxides and 1,2-diols via a hydrolytic kinetic resolution of racemic terminal epoxides using a new bimetallic chiral salen CoIII complex incorporated with La(OTf)3 as a catalyst is reported. The new bimetallic chiral salen CoIII complex bearing La(OTf)3 was prepared in a one-pot procedure by activation and bimetallic complex formation from the inactive Jacobsen chiral salen CoII complex (salen = N, N′-bis(3,5-di-tert-butylsalicylidene)-1,2- cyclohexane-diamine). We observed that C1-symmetric chiral bimetallic Co-complex coordinated with La(OTf)3 works as a chiral catalyst and remarkably increased the reactivity and enantioselectivity in the hydrolytic kinetic resolution of terminal epoxides compared to its monometallic analogues. La(OTf)3 plays a crucial role as an achiral Lewis acid in this process, which is supported by the experimental observation presented. To explore the absolute configuration of glycidyl butyrate a vibrational circular dichroism (VCD) spectra was calculated using density functional theory. Keywords: Chiral epoxides, asymmetric catalysis, bimetallic chiral salen complex, hydrolytic kinetic resolution, lewis acid, VCD.
Understanding carbon quantum dots through computational methods in quantum chemistry N Nirmalkar, D Patel, K Shrivas, N Kumari, K Thakur, B Sharma, ... Discover Chemistry 2 (1), 306 , 2025 2025 Citations: 4
Cu complex of 8-hydroxyquinoline Organic phosphor for OLEDs: Synthesis, Characterization & Photoluminescence Studies AR Amit Chatterjee, Deepak Patel Journal of Emerging Technologies and Innovative Research (JETIR) 11 (11 … , 2024 2024
Extraction, Estimation and Characterization of Peperine from Black Pepper AR Kiran Rathore, Deepak Patel Journal of Emerging Technologies and Innovative Research (JETIR) 11 (11 … , 2024 2024
Solid State Synthesis of Nickel Ferrite (NiFe2O4) and their Characterization AR Vijaylaxmi Kaiwartya, Kiran Rathore, Deepak Patel Journal of Emerging Technologies and Innovative Research (JETIR) 11 (11 … , 2024 2024
Synthesis of Cobalt-(Salen) Based Chiral Complexes and Their Applications as a Catalyst SS Thakur, D Patel 2022
Design And Development Of Bimetallic Enantioselective Salen Co Catalysts For The Hydrolytic Kinetic Resolution Of Terminal Epoxides GK Thakur, S. S., Patel, D., Nirmalkar, N., Thakur, K. & Patra Fundamentals and Prospects of Catalysis 1, 16-65 , 2020 2020 Citations: 2
Catalytic and efficient synthesis of optically active terminal epoxides and 1, 2-diols using a new lanthanum triflate assisted C1-symmetric bimetallic chiral salen cobalt complex D Patel, SS Thakur, SS Shinde, P Kumar Letters in Organic Chemistry 15 (11), 960-966 , 2018 2018 Citations: 3
Dinuclear salen cobalt complex incorporating Y (OTf) 3: enhanced enantioselectivity in the hydrolytic kinetic resolution of epoxides D Patel, GR Kurrey, SS Shinde, P Kumar, GJ Kim, SS Thakur RSC advances 5 (101), 82699-82703 , 2015 2015 Citations: 11
MOST CITED SCHOLAR PUBLICATIONS
Dinuclear salen cobalt complex incorporating Y (OTf) 3: enhanced enantioselectivity in the hydrolytic kinetic resolution of epoxides D Patel, GR Kurrey, SS Shinde, P Kumar, GJ Kim, SS Thakur RSC advances 5 (101), 82699-82703 , 2015 2015 Citations: 11
Understanding carbon quantum dots through computational methods in quantum chemistry N Nirmalkar, D Patel, K Shrivas, N Kumari, K Thakur, B Sharma, ... Discover Chemistry 2 (1), 306 , 2025 2025 Citations: 4
Catalytic and efficient synthesis of optically active terminal epoxides and 1, 2-diols using a new lanthanum triflate assisted C1-symmetric bimetallic chiral salen cobalt complex D Patel, SS Thakur, SS Shinde, P Kumar Letters in Organic Chemistry 15 (11), 960-966 , 2018 2018 Citations: 3
Design And Development Of Bimetallic Enantioselective Salen Co Catalysts For The Hydrolytic Kinetic Resolution Of Terminal Epoxides GK Thakur, S. S., Patel, D., Nirmalkar, N., Thakur, K. & Patra Fundamentals and Prospects of Catalysis 1, 16-65 , 2020 2020 Citations: 2
Cu complex of 8-hydroxyquinoline Organic phosphor for OLEDs: Synthesis, Characterization & Photoluminescence Studies AR Amit Chatterjee, Deepak Patel Journal of Emerging Technologies and Innovative Research (JETIR) 11 (11 … , 2024 2024
Extraction, Estimation and Characterization of Peperine from Black Pepper AR Kiran Rathore, Deepak Patel Journal of Emerging Technologies and Innovative Research (JETIR) 11 (11 … , 2024 2024
Solid State Synthesis of Nickel Ferrite (NiFe2O4) and their Characterization AR Vijaylaxmi Kaiwartya, Kiran Rathore, Deepak Patel Journal of Emerging Technologies and Innovative Research (JETIR) 11 (11 … , 2024 2024
Synthesis of Cobalt-(Salen) Based Chiral Complexes and Their Applications as a Catalyst SS Thakur, D Patel 2022