Marie Van de Sande
@leeds.ac.uk
University of Leeds
Scopus Publications
Scholar Citations
Scholar h-index
Scholar i10-index
Scopus Publications
T. J. Millar, C. Walsh, M. Van de Sande, and A. J. Markwick
EDP Sciences
Context. Detailed astrochemical models are a key component to interpret the observations of interstellar and circumstellar molecules since they allow important physical properties of the gas and its evolutionary history to be deduced. Aims. We update one of the most widely used astrochemical databases to reflect advances in experimental and theoretical estimates of rate coefficients and to respond to the large increase in the number of molecules detected in space since our last release in 2013. Methods. We present the sixth release of the UMIST Database for Astrochemistry (UDfA), a major expansion of the gas-phase chemistry that describes the synthesis of interstellar and circumstellar molecules. Since our last release, we have undertaken a major review of the literature which has increased the number of reactions by over 40% to a total of 8767 and increased the number of species by over 55% to 737. We have made a particular attempt to include many of the new species detected in space over the past decade, including those from the QUIJOTE and GOTHAM surveys, as well as providing references to the original data sources. Results. We use the database to investigate the gas-phase chemistries appropriate to both O-rich and C-rich conditions in TMC-1 and to the circumstellar envelope of the C-rich AGB star IRC+10216 and identify successes and failures of gas-phase only models. Conclusions. This update is a significant improvement to the UDfA database. For both the dark cloud and C-rich circumstellar envelope models, calculations match around 60% of the abundances of observed species to within an order of magnitude. There are a number of detected species, however, that are not included in the model either because their gas-phase chemistry is unknown or because they are likely formed via surface reactions on icy grains. Future laboratory and theoretical work is needed to include such species in reaction networks.
P. Royer, T. Merle, K. Dsilva, S. Sekaran, H. Van Winckel, Y. Frémat, M. Van der Swaelmen, S. Gebruers, A. Tkachenko, M. Laverick,et al.
EDP Sciences
Aims. Over the past decades, libraries of stellar spectra have been used in a large variety of science cases, including as sources of reference spectra for a given object or a given spectral type. Despite the existence of large libraries and the increasing number of projects of large-scale spectral surveys, there is to date only one very high-resolution spectral library offering spectra from a few hundred objects from the southern hemisphere (UVES-POP). We aim to extend the sample, offering a finer coverage of effective temperatures and surface gravity with a uniform collection of spectra obtained in the northern hemisphere. Methods. Between 2010 and 2020, we acquired several thousand echelle spectra of bright stars with the Mercator-HERMES spectrograph located in the Roque de Los Muchachos Observatory in La Palma, whose pipeline offers high-quality data reduction products. We have also developed methods to correct for the instrumental response in order to approach the true shape of the spectral continuum. Additionally, we have devised a normalisation process to provide a homogeneous normalisation of the full spectral range for most of the objects. Results. We present a new spectral library consisting of 3256 spectra covering 2043 stars. It combines high signal-to-noise and high spectral resolution over the entire range of effective temperatures and luminosity classes. The spectra are presented in four versions: raw, corrected from the instrumental response, with and without correction from the atmospheric molecular absorption, and normalised (including the telluric correction).
S. H. J. Wallström, T. Danilovich, H. S. P. Müller, C. A. Gottlieb, S. Maes, M. Van de Sande, L. Decin, A. M. S. Richards, A. Baudry, J. Bolte,et al.
EDP Sciences
Context. The dusty winds of cool evolved stars are a major contributor of the newly synthesised material enriching the Galaxy and future generations of stars. However, the details of the physics and chemistry behind dust formation and wind launching have yet to be pinpointed. Recent spatially resolved observations show the importance of gaining a more comprehensive view of the circumstellar chemistry, but a comparative study of the intricate interplay between chemistry and physics is still difficult because observational details such as frequencies and angular resolutions are rarely comparable. Aims. Aiming to overcome these deficiencies, ATOMIUM is an ALMA Large Programme to study the physics and chemistry of the circumstellar envelopes of a diverse set of oxygen-rich evolved stars under homogeneous observing conditions at three angular resolutions between ~0.02″−1.4″. Here we summarize the molecular inventory of these sources, and the correlations between stellar parameters and molecular content. Methods. Seventeen oxygen-rich or S-type asymptotic giant branch (AGB) and red supergiant (RSG) stars have been observed in several tunings with ALMA Band 6, targeting a range of molecules to probe the circumstellar envelope and especially the chemistry of dust formation close to the star. We systematically assigned the molecular carriers of the spectral lines and measured their spectroscopic parameters and the angular extent of the emission of each line from integrated intensity maps. Results. Across the ATOMIUM sample, we detect 291 transitions of 24 different molecules and their isotopologues. This includes several first detections in oxygen-rich AGB/RSG stars: PO v = 1, SO2 v1 = 1 and v2 = 2, and several high energy H2O transitions. We also find several first detections in S-type AGB stars: vibrationally excited HCN v2 = 2,3 and SiS v = 4,5,6, as well as first detections of the molecules SiC, AlCl, and AlF in W Aql. Overall, we find strong correlations between the following molecular pairs: CS and SiS, CS and AlF, NaCl and KCl, AlO and SO, SO2 and SO, and SO2 and H2O; meaning both molecules tend to have more detected emission lines in the same sources. The measured isotopic ratios of Si and S are found to be consistent with previous measurements, except for an anomalously high 29Si/30Si ratio of 4 ± 1 in the RSG VX Sgr. Conclusions. This paper presents the overall molecular inventory and an initial analysis of the large ATOMIUM dataset, laying the groundwork for future work deriving molecular abundances and abundance profiles using radiative transfer modeling which will provide more rigorous tests for chemical models.
T. Danilovich, J. Malfait, M. Van de Sande, M. Montargès, P. Kervella, F. De Ceuster, A. Coenegrachts, T. J. Millar, A. M. S. Richards, L. Decin,et al.
Springer Science and Business Media LLC
Stefan T. Bromley, Sandra Brünken, Cecilia Ceccarelli, Martin Cordiner, Kristen Darnell, Gwenaëlle Dufour, Athena Flint, Robin T. Garrod, Murthy S. Gudipati, Joshua Halpern,et al.
Royal Society of Chemistry (RSC)
S Maes, M Van de Sande, T Danilovich, F De Ceuster, and L Decin
Oxford University Press (OUP)
ABSTRACT Asymptotic giant branch (AGB) stars shed a significant amount of their mass in the form of a stellar wind, creating a vast circumstellar envelope (CSE). Owing to the ideal combination of relatively high densities and cool temperatures, CSEs serve as rich astrochemical laboratories. While the chemical structure of AGB outflows has been modelled and analysed in detail for specific physical setups, there is a lack of understanding regarding the impact of changes in the physical environment on chemical abundances. A systematic sensitivity study is necessary to comprehend the nuances in the physical parameter space, given the complexity of the chemistry. This is crucial for estimating uncertainties associated with simulations and observations. In this work, we present the first sensitivity study of the impact of varying outflow densities and temperature profiles on the chemistry. With the use of a chemical kinetics model, we report on the uncertainty in abundances, given a specific uncertainty on the physical parameters. In addition, we analyse the molecular envelope extent of parent species and compare our findings to observational studies. Mapping the impact of differences in physical parameters throughout the CSE on the chemistry is a strong aid to observational studies.
Marie Van de Sande, Catherine Walsh, and Tom J. Millar
Royal Society of Chemistry (RSC)
The first AGB chemical kinetics model that includes porosity, dust–gas chemistry and companion UV photons, allows us to unravel the interplay of the complexities and identify suites of molecules to determine the presence of a companion star.
M. Montargès, E. Cannon, A. de Koter, T. Khouri, E. Lagadec, P. Kervella, L. Decin, I. McDonald, W. Homan, L. B. F. M. Waters,et al.
EDP Sciences
Context. Low- and intermediate-mass asymptotic giant stars and massive red supergiant stars are important contributors to the chemical enrichment of the Universe. They are among the most efficient dust factories of the Galaxy, harboring chemically rich circumstellar environments. Yet, the processes that lead to dust formation or the large-scale shaping of the mass loss still escape attempts at modeling. Aims. Through the ATOMIUM project, we aim to present a consistent view of a sample of 17 nearby cool evolved stars. Our goals are to unveil the dust-nucleation sites and morphologies of the circumstellar envelope of such stars and to probe ambient environments with various conditions. This will further enhance our understanding of the roles of stellar convection and pulsations, and that of companions in shaping the dusty circumstellar medium. Methods. Here we present and analyze VLT/SPHERE-ZIMPOL polarimetric maps obtained in the visible (645–820 nm) of 14 out of the 17 ATOMIUM sources. They were obtained contemporaneously with the ALMA high spatial resolution data. To help interpret the polarized signal, we produced synthetic maps of light scattering by dust, through 3D radiative transfer simulations with the RADMC3D code. Results. The degree of linear polarization (DoLP) observed by ZIMPOL spreads across several optical filters. We infer that it primarily probes dust located just outside of the point spread function of the central source, and in or near the plane of the sky. The polarized signal is mainly produced by structures with a total optical depth close to unity in the line of sight, and it represents only a fraction of the total circumstellar dust. The maximum DoLP ranges from 0.03–0.38 depending on the source, fractions that can be reproduced by our 3D pilot models for grains composed of olivine, melilite, corundum, enstatite, or forsterite. The spatial structure of the DoLP shows a diverse set of shapes, including clumps, arcs, and full envelopes. Only for three sources do we note a correlation between the ALMA CO υ = 0, J = 2−1 and SiO υ = 0, J = 5−4 lines, which trace the gas density, and the DoLP, which traces the dust. Conclusions. The clumpiness of the DoLP and the lack of a consistent correlation between the gas and the dust location show that, in the inner environment, dust formation occurs at very specific sites. This has potential consequences for the derived mass-loss rates and dust-to-gas ratio in the inner region of the circumstellar environment. Except for π1 Gru and perhaps GY Aql, we do not detect interactions between the circumstellar wind and the hypothesized companions that shape the wind at larger scales. This suggests that the orbits of any other companions are tilted out of the plane of the sky.
Niclas A. West, Lok Hin Desmond Li, Tom J. Millar, Marie Van de Sande, Edward Rutter, Mark A. Blitz, Julia H. Lehman, Leen Decin, and Dwayne E. Heard
Royal Society of Chemistry (RSC)
Rate coefficients for the reaction of CN with CH2O were measured for the first time below room temperature in the range 32–103 K using a pulsed Laval nozzle apparatus together with the Pulsed Laser Photolysis–Laser-Induced Fluorescence technique.
Mark A. Siebert, Marie Van de Sande, Thomas J. Millar, and Anthony J. Remijan
American Astronomical Society
Abstract In recent years, many questions have arisen regarding the chemistry of photochemical products in the carbon-rich winds of evolved stars. To address them, it is imperative to constrain the distributions of such species through high-angular-resolution interferometric observations covering multiple rotational transitions. We used archival Atacama Large Millimeter/submillimeter Array observations to map rotational lines involving high energy levels of cyanoacetylene (HC3N) toward the inner envelope (radius < 8″/1000 au) of the carbon star IRC+10216. The observed lines include the J = 28 − 27, J = 30 − 29, and J = 38 − 37 transitions of HC3N in its ground vibrational state. In contrast to previous observations of linear carbon chains toward this asymptotic giant branch (AGB) star that show extended, hollow emission at 15″–20″ radii (e.g., C4H, C6H, and HC5N), the maps of the HC3N lines here show compact morphologies comprising various arcs and density enhancements, with significant emission from gas clumps at an angular distance of ∼3″ (350 au) from the central AGB star. We compared visibility sampled non-LTE radiative transfer models with the observed brightness distributions, and derive a fractional abundance with respect to H2 of 10−8 for HC3N at the radii probed by these lines. These results are consistent with enhanced photochemistry occurring in warm (∼200 K) regions of the circumstellar envelope. After application of a specialized chemical model for IRC+10216, we find evidence that the enhanced HC3N abundances in the inner wind are most likely due to a solar-type binary companion initiating photochemistry in this region.
C. A. Gottlieb, L. Decin, A. M. S. Richards, F. De Ceuster, W. Homan, S. H. J. Wallström, T. Danilovich, T. J. Millar, M. Montargès, K. T. Wong,et al.
EDP Sciences
This overview paper presents ATOMIUM, a Large Programme in Cycle 6 with the Atacama Large Millimeter/submillimeter Array (ALMA). The goal of ATOMIUM is to understand the dynamics and the gas phase and dust formation chemistry in the winds of evolved asymptotic giant branch (AGB) and red supergiant (RSG) stars. A more general aim is to identify chemical processes applicable to other astrophysical environments. Seventeen oxygen-rich AGB and RSG stars spanning a range in (circum)stellar parameters and evolutionary phases were observed in a homogeneous observing strategy allowing for an unambiguous comparison. Data were obtained between 213.83 and 269.71 GHz at high (∼0″.025–0″.050), medium (∼0″.13–0″.24), and low (∼1″) angular resolution. The sensitivity per ∼1.3 km s−1 channel was 1.5–5 mJy beam−1, and the line-free channels were used to image the millimetre wave continuum. Our primary molecules for studying the gas dynamics and dust formation are CO, SiO, AlO, AlOH, TiO, TiO2, and HCN; secondary molecules include SO, SO2, SiS, CS, H2O, and NaCl. The scientific motivation, survey design, sample properties, data reduction, and an overview of the data products are described. In addition, we highlight one scientific result – the wind kinematics of the ATOMIUM sources. Our analysis suggests that the ATOMIUM sources often have a slow wind acceleration, and a fraction of the gas reaches a velocity which can be up to a factor of two times larger than previously reported terminal velocities assuming isotropic expansion. Moreover, the wind kinematic profiles establish that the radial velocity described by the momentum equation for a spherical wind structure cannot capture the complexity of the velocity field. In fifteen sources, some molecular transitions other than 12CO v = 0 J = 2 − 1 reach a higher outflow velocity, with a spatial emission zone that is often greater than 30 stellar radii, but much less than the extent of CO. We propose that a binary interaction with a (sub)stellar companion may (partly) explain the non-monotonic behaviour of the projected velocity field. The ATOMIUM data hence provide a crucial benchmark for the wind dynamics of evolved stars in single and binary star models.
M Van de Sande and T J Millar
Oxford University Press (OUP)
ABSTRACT Spherical asymmetries are prevalent within the outflows of AGB stars. Since binary interaction with a stellar or planetary companion is thought to be the underlying mechanism behind large-scale structures, we included the effects of UV radiation originating from a stellar companion in our chemical kinetics model. The one-dimensional model provides a first approximation of its effects on the chemistry throughout the outflow. The presence of a close-by stellar companion can strongly influence the chemistry within the entire outflow. Its impact depends on the intensity of the radiation (set by the stellar radius and blackbody temperature) and on the extinction, the UV radiation experiences (set by the outflow density, density structure, and assumed radius of dust formation). Parent species can be photodissociated by the companion, initiating a rich photon-driven chemistry in the inner parts of the outflow. The outcome depends on the balance between two-body reactions and photoreactions. If two-body reactions dominate, chemical complexity within the outflow increases. This can make the abundance profiles of daughters appear like those of parents, with a larger inner abundance and a Gaussian decline. If photoreactions dominate, the outflow can appear molecule-poor. We model three stellar companions. The impact of a red dwarf companion is limited. Solar-like companions show the largest effect, followed by a white dwarf. A stellar companion can also lead to the formation of unexpected species. The outflow’s molecular content, especially combined with abundance profiles, can indicate a stellar companion’s presence. Our results pave the way for further outflow-specific (three-dimensional) model development.
T. Danilovich, M. Van de Sande, J. M. C. Plane, T. J. Millar, P. Royer, M. A. Amor, K. Hammami, L. Decock, C. A. Gottlieb, L. Decin,et al.
EDP Sciences
Context. S-type asymptotic giant branch (AGB) stars are thought to be intermediates in the evolution of oxygen- to carbon-rich AGB stars. The chemical compositions of their circumstellar envelopes are also intermediate but have not been studied in as much detail as their carbon- and oxygen-rich counterparts. W Aql is a nearby S-type star, with well-known circumstellar parameters, making it an ideal object for in-depth study of less common molecules. Aims. We aim to determine the abundances of AlCl and AlF from rotational lines, which have been observed for the first time towards an S-type AGB star. In combination with models based on PACS observations, we aim to update our chemical kinetics network based on these results. Methods. We analyse ALMA observations towards W Aql of AlCl in the ground and first two vibrationally excited states and AlF in the ground vibrational state. Using radiative transfer models, we determine the abundances and spatial abundance distributions of Al35Cl, Al37Cl, and AlF. We also model HCl and HF emission and compare these models to PACS spectra to constrain the abundances of these species. Results. AlCl is found in clumps very close to the star, with emission confined within 0′′.1 of the star. AlF emission is more extended, with faint emission extending 0′′.2 to 0′′.6 from the continuum peak. We find peak abundances, relative to H2, of 1.7 × 10−7 for Al35Cl, 7 × 10−8 for Al37Cl, and 1 × 10−7 for AlF. From the PACS spectra, we find abundances of 9.7 × 10−8 and ≤10−8, relative to H2, for HCl and HF, respectively. Conclusions. The AlF abundance exceeds the solar F abundance, indicating that fluorine synthesised in the AGB star has already been dredged up to the surface of the star and ejected into the circumstellar envelope. From our analysis of chemical reactions in the wind, we conclude that AlF may participate in the dust formation process, but we cannot fully explain the rapid depletion of AlCl seen inthe wind.
W. Homan, B. Pimpanuwat, T. Danilovich, I. McDonald, S. H. J. Wallstrom, A. de Koter, A. M. S. Richards, A. Baudry, R. Sahai, T. J. Millar,et al.
EDP Sciences
Evolved lowto intermediate-mass stars are known to shed their gaseous envelope into a large, dusty, molecule-rich circumstellar nebula which typically develops a high degree of structural complexity. Most of the large-scale, spatially correlated structures in the nebula are thought to originate from the interaction of the stellar wind with a companion. As part of the Atomium large programme, we observed the M-type asymptotic giant branch (AGB) star R Hydrae with the Atacama Large Millimeter/submillimeter Array (ALMA). The morphology of the inner wind of R Hya, which has a known companion at ∼3500 au, was determined from maps of CO and SiO obtained at high angular resolution. A map of the CO emission reveals a multi-layered structure consisting of a large elliptical feature at an angular scale of ∼10” that is oriented along the north–south axis. The wind morphology within the elliptical feature is dominated by two hollow bubbles. The bubbles are on opposite sides of the AGB star and lie along an axis with a position angle of ∼115◦. Both bubbles are offset from the central star, and their appearance in the SiO channel maps indicates that they might be shock waves travelling through the AGB wind. An estimate of the dynamical age of the bubbles yields an age of the order of 100 yr, which is in agreement with the previously proposed elapsed time since the star last underwent a thermal pulse. When the CO and SiO emission is examined on subarcsecond angular scales, there is evidence for an inclined, differentially rotating equatorial density enhancement, strongly suggesting the presence of a second nearby companion. The position angle of the major axis of this disc is ∼70◦ in the plane of the sky. We tentatively estimate that a lower limit on the mass of the nearby companion is ∼0.65 M on the basis of the highest measured speeds in the disc and the location of its inner rim at ∼6 au from the AGB star.
M Van de Sande, C Walsh, and T J Millar
Oxford University Press (OUP)
ABSTRACT To explain the properties of dust in the interstellar medium (ISM), the presence of a refractory organic mantle is necessary. The outflows of AGB stars are among the main contributors of stellar dust to the ISM. We present the first study of the refractory organic contribution of AGB stars to the ISM. Based on laboratory experiments, we included a new reaction in our extended chemical kinetics model: the photoprocessing of volatile complex ices into inert refractory organic material. The refractory organic feedback of AGB outflows to the ISM is estimated using observationally motivated parent species and grids of models of C-rich and O-rich outflows. Refractory organic material is mainly inherited from the gas phase through accretion on to the dust and subsequent photoprocessing. Grain-surface chemistry, initiated by photodissociation of ices, produces only a minor part and takes place in a sub-monolayer regime in almost all outflows. The formation of refractory organic material increases with outflow density and depends on the initial gas-phase composition. While O-rich dust is negligibly covered by refractory organics, C-rich dust has an average coverage of $3\\!-\\!9{{\\ \\rm per\\ cent}}$, but can be as high as $8\\!-\\!22{{\\ \\rm per\\ cent}}$. Although C-rich dust does not enter the ISM bare, its average coverage is too low to influence its evolution in the ISM or significantly contribute to the coverage of interstellar dust. This study opens up questions on the coverage of other dust-producing environments. It highlights the need for an improved understanding of dust formation and for models specific to density structures within the outflow.
Ward Homan, Miguel Montargès, Bannawit Pimpanuwat, Anita M. S. Richards, Sofia H. J. Wallström, Pierre Kervella, Leen Decin, Albert Zijlstra, Taissa Danilovich, Alex de Koter,et al.
EDP Sciences
The nebular circumstellar environments of cool evolved stars are known to harbour a rich morphological complexity of gaseous structures on different length scales. A large part of these density structures are thought to be brought about by the interaction of the stellar wind with a close companion. The S-type asymptotic giant branch (AGB) star π1Gruis, which has a known companion at ∼440 au and is thought to harbour a second, closer-by (< 10 au) companion, was observed with the Atacama Large Millimeter/submillimeter Array as part of the ATOMIUM Large programme. In this work, the brightest CO, SiO, and HCN molecular line transitions are analysed. The continuum map shows two maxima, separated by 0.04″ (6 au). The CO data unambiguously reveal that π1Gru’s circumstellar environment harbours an inclined, radially outflowing, equatorial density enhancement. It contains a spiral structure at an angle of ∼38 ± 3° with the line-of-sight. The HCN emission in the inner wind reveals a clockwise spiral, with a dynamical crossing time of the spiral arms consistent with a companion at a distance of 0.04″ from the AGB star, which is in agreement with the position of the secondary continuum peak. The inner wind dynamics imply a large acceleration region, consistent with a beta-law power of ∼6. The CO emission suggests that the spiral is approximately Archimedean within 5″, beyond which this trend breaks down as the succession of the spiral arms becomes less periodic. The SiO emission at scales smaller than 0.5″ exhibits signatures of gas in rotation, which is found to fit the expected behaviour of gas in the wind-companion interaction zone. An investigation of SiO maser emission reveals what could be a stream of gas accelerating from the surface of the AGB star to the companion. Using these dynamics, we have tentatively derived an upper limit on the companion mass to be ∼1.1 M⊙.
M. Van de Sande and T. J. Millar
Cambridge University Press (CUP)
AbstractBinary interaction with a stellar or planetary companion has been proposed to be the driving mechanism behind large-scale asymmetries, such as spirals and disks, observed within AGB outflows. We developed the first chemical kinetics model that takes the effect of a stellar companions’s UV radiation into account. The presence of a stellar companion can initiate a rich photochemistry in the inner wind. Its impact is determined by the intensity of the UV radiation and the extinction the radiation experiences. The outcome of the inner wind photochemistry depends on the balance between two-body reactions and photoreactions. If photoreactions dominate, the outflow can appear molecule-poor. If two-body reactions dominate, chemical complexity within the outflow can increase, yielding daughter species with a large inner wind abundance. A comprehensive view on the molecular content of the outflow, especially combined with abundance profiles, can point towards the presence of a stellar companion.
T. Danilovich, M. Van de Sande, A. M. S. Richards, and
Cambridge University Press (CUP)
AbstractS-type AGB stars, with C/O ratios close to 1, are expected to have a mixed circumstellar chemistry as they transition from being oxygen-rich stars to carbon-rich stars. Recently, several different carbonaceous molecules, thought to be more characteristic of carbon stars, have been found in the circumstellar envelope of the S-type AGB star W Aql. We have obtained new high spatial resolution ALMA images of some of these molecules, specifically HC3N, SiC2 and SiC, and SiN, which we present here. We report diverse behaviour for these molecules, with SiC2 being seen with a symmetric spatial distribution around the star, SiN and SiC being asymmetrically distributed to the north-east of the star, and HC3N being seen in a broken shell to the south-west. These differing distributions point to complex dynamics in the circumstellar envelope of W Aql.
Amy Wolstenholme-Hogg, Alexander D. James, John M. C. Plane, and Marie Van de Sande
Cambridge University Press (CUP)
AbstractAstrochemical models treat dust surfaces as ice covered. We investigate the effects of implementing increased bare dust binding energies of CO and S-bearing species on the chemistry in the outflows of asymptotic giant branch (AGB) stars. We demonstrate the potential for improving agreement with observations in the outflow of IK Tau.Increasing the binding energies to measured and computationally derived values in high mass-loss AGB outflows increased the production of daughter species. Switching from a high binding energy on bare dust to weaker binding to ice, the gas phase abundance increased at a radius in agreement with observations of IK Tau, suggesting that displacement of bound species could contribute to this observational puzzle. Using a strong binding to bare dust, a gas phase increase was not observed, however parent species concentrations had to be increased by around a factor of four to explain observed concentrations.
L. Decin, M. Montargès, A. M. S. Richards, C. A. Gottlieb, W. Homan, I. McDonald, I. El Mellah, T. Danilovich, S. H. J. Wallström, A. Zijlstra,et al.
American Association for the Advancement of Science (AAAS)
Complex stellar winds from evolved stars Stars less than eight times the mass of the Sun end their lives as planetary nebulae, structures of ionized gas thrown off by the star and heated by the exposed stellar core. Planetary nebulae are often bipolar in shape or contain complex morphological features such as rings or spirals. Decin et al. observed the stellar winds of 14 stars during their asymptotic giant branch (AGB) phase of stellar evolution, which immediately precedes the planetary nebula phase. They found morphologies in the AGB winds similar to planetary nebulae and demonstrated that they are produced by the influence of a binary companion on the AGB wind. Science , this issue p. 1497
M Van de Sande, C Walsh, and T Danilovich
Oxford University Press (OUP)
ABSTRACT Asymptotic giant branch (AGB) stars are, together with supernovae, the main contributors of stellar dust to the interstellar medium (ISM). Dust grains formed by AGB stars are thought to be large. However, as dust nucleation and growth within their outflows are still not understood, the dust-grain size distribution (GSD) is unknown. This is an important uncertainty regarding our knowledge of the chemical and physical history of interstellar dust, as AGB dust forms ${\\sim} 70{{\\ \\rm per\\ cent}}$ of the starting point of its evolution. We expand on our chemical kinetics model, which uniquely includes a comprehensive dust–gas chemistry. The GSD is now allowed to deviate from the commonly assumed canonical Mathis, Rumpl & Nordsieck distribution. We find that the specific GSD can significantly influence the dust–gas chemistry within the outflow. Our results show that the level of depletion of gas-phase species depends on the average grain surface area of the GSD. Gas-phase abundance profiles and their possible depletions can be retrieved from observations of molecular emission lines when using a range of transitions. Because of degeneracies within the prescription of GSD, specific parameters cannot be retrieved, only (a lower limit to) the average grain surface area. None the less, this can discriminate between dust composed of predominantly large or small grains. We show that when combined with other observables such as the spectral energy distribution and polarized light, depletion levels from molecular gas-phase abundance profiles can constrain the elusive GSD of the dust delivered to the ISM by AGB outflows.
T Danilovich, A M S Richards, L Decin, M Van de Sande, and C A Gottlieb
Oxford University Press (OUP)
ABSTRACT We present and analyse SO and SO2, recently observed with high angular resolution and sensitivity in a spectral line survey with ALMA, for two oxygen-rich AGB stars: the low mass-loss rate R Dor and high mass-loss rate IK Tau. We analyse 8 lines of SO detected towards both stars, 78 lines of SO2 detected towards R Dor, and 52 lines of SO2 detected towards IK Tau. We detect several lines of 34SO, 33SO, and 34SO2 towards both stars, and tentatively S18O towards R Dor, and hence derive isotopic ratios for these species. The spatially resolved observations show us that the two sulphur oxides are co-located towards R Dor and trace out the same wind structures in the circumstellar envelope. Much of the emission is well reproduced with a Gaussian abundance distribution spatially centred on the star. Emission from the higher energy levels of SO and SO2 towards R Dor provides evidence in support of a rotating inner region of gas identified in earlier work. The new observations allow us to refine the abundance distribution of SO in IK Tau derived from prior observations with single antennas, and confirm that the distribution is shell like with the peak in the fractional abundance not centred on the star. The confirmation of different types of SO abundance distributions will help fine-tune chemical models and allows for an additional method to discriminate between low and high mass-loss rates for oxygen-rich AGB stars.
M. Van de Sande, J. O. Sundqvist, T. J. Millar, D. Keller, W. Homan, A. de Koter, L. Decin, and F. De Ceuster
EDP Sciences
M. Van de Sande, T. Danilovich, and L. Decin
Cambridge University Press (CUP)
AbstractThe outflows of asymptotic giant branch (AGB) stars are important astrochemical laboratories, rich in molecular material and host to various chemical processes, including dust formation. Since the different chemistries are relatively easily probed, AGB outflows are ideal testbeds within the wider astrochemical community. Recent observations are pushing the limits of both our current chemical models and radiative transfer routines. Current chemical models are restricted by the completeness of their chemical networks and the accuracy of the reaction rates. The molecular abundances retrieved by radiative transfer routines are strongly dependent on collisional rates, which are often not measured or calculated for molecules of interest. To further our understanding of the chemistry within the outflow, collaboration with the laboratory astrophysics community is essential. This collaboration is mutually beneficial, as it in turn provides new science questions for laboratory experiments and computations.
M Van de Sande, C Walsh, T P Mangan, and L Decin
Oxford University Press (OUP)
ABSTRACT Chemical modelling of asymptotic giant branch (AGB) outflows is typically focused on either non-thermodynamic equilibrium chemistry in the inner region or photon-driven chemistry in the outer region. We include, for the first time, a comprehensive dust–gas chemistry in our AGB outflow chemical kinetics model, including both dust–gas interactions and grain-surface chemistry. The dust is assumed to have formed in the inner region, and follows an interstellar-like dust-size distribution. Using radiative transfer modelling, we obtain dust temperature profiles for different dust types in an O-rich and a C-rich outflow. We calculate a grid of models, sampling different outflow densities, drift velocities between the dust and gas, and dust types. Dust–gas chemistry can significantly affect the gas-phase composition, depleting parent and daughter species and increasing the abundance of certain daughter species via grain-surface formation followed by desorption/sputtering. Its influence depends on four factors: outflow density, dust temperature, initial composition, and drift velocity. The largest effects are for higher density outflows with cold dust and O-rich parent species, as these species generally have a larger binding energy. At drift velocities larger than ∼10 km s−1, ice mantles undergo sputtering; however, they are not fully destroyed. Models with dust–gas chemistry can better reproduce the observed depletion of species in O-rich outflows. When including colder dust in the C-rich outflows and adjusting the binding energy of CS, the depletion in C-rich outflows is also better reproduced. To best interpret high-resolution molecular line observations from AGB outflows, dust–gas interactions are needed in chemical kinetics models.