Oleksiy Myhkailenko
@univ.kiev.ua
Department of Supramolecular Chemistry, Institute of High Technologies
Taras Shevchenko National University of Kyiv
RESEARCH, TEACHING, or OTHER INTERESTS
Organic Chemistry, Computer Science Applications, Materials Science, Drug Guides
Scopus Publications
Scholar Citations
Scholar h-index
Scopus Publications
O. V. Mykhailenko, Yu I. Prylutskyy, I. V. Кomarov, and A. V. Strungar
Springer Science and Business Media LLC
О. V. Мykhailenko, Yu I. Prylutskyy, І. V. Кomarov, and А. V. Strungar
Springer Science and Business Media LLC
O. V. Mykhailenko, Y. I. Prylutskyy, I. V. Komarov, A. V. Strungar, and N. G. Tsierkezos
Wiley
The positioning of tricarbonyl(cyclopentadienyl)manganese molecules in double‐walled (5.5)@(10.10) carbon nanotubes depending on their concentration and temperature was studied using the methods of molecular dynamics, semi‐empirical quantum‐chemical parameterized model number 3 and Monte‐Carlo. The molecules were found to form stable bonds with the carbon nanotubes walls, with a tendency between intercalate stability and the carbon nanotubes structure. A temperature increase (above ˜460 K) causes gradual bond ruining followed by extrusion of interwall intercalate. Further temperature increase up to 600–750 K is characterised with intercalate external surface desorption, stabilising the whole system and keeping the interwall intercalate only. Double‐walled carbon nanotubes UV‐spectra depending on the intercalate concentration and association constant of the “double‐walled carbon nanotubes‐intercalate” system were calculated. A combination of unique optical, electrical and magnetic behaviour of cyclopentadienyl complexes with their ability to form high‐stable intercalate with carbon nanotubes opens a prospect of their application in nanotechnology.
O. V. Mykhailenko, Yu. I. Prylutskyy, D. Matsui, Y. M. Strzhemechny, F. Le Normand, U. Ritter, and P. Scharff
American Scientific Publishers
L. L. Kondratenko, O. V. Mykhailenko, Yu. I. Prylutskyy, T. M. Radchenko, and V. A. Tatarenko
National Academy of Sciences of Ukraine (Co. LTD Ukrinformnauka)
Oleksiy Mykhailenko, Denis Matsui, Yuriy Prylutskyy, Francois Le Normand, Peter Eklund, and Peter Scharff
Springer Science and Business Media LLC
O. V. Mykhailenko, D. Hui, Y. M. Strzhemechny, D. Matsui, Yu. I. Prylutskyy, and P. Eklund
American Scientific Publishers
We performed Monte Carlo simulations for single- and double-walled carbon nanotubes intercalated with different atomic species (Fe, Ni, Co, and B). A relationship was established between the length of a carbon nanotube and the number as well as the type of the intercalating atoms. Carbon nanotube systems intercalated with Ni, Co, and B were shown to be more stable with temperature and retained a greater internal concentration of the intercalate atoms compared to the case of Fe intercalated systems where a substantial extrusion of atoms was observed as a result of thermal treatment.