Rahul Bandopant Dahiwadkar

@jaychemicals.co.in

Research and Development, Jay Chemicals
Jay Chemicals



                 

https://researchid.co/rahul29394

Rahul completed his Ph.D. from IIT Gandhinagar under supervision of Dr. Sriram Kanvah. His doctoral research includes synthesis of functional sensors of important analytes and imaging agents of cellular organelle. After completion of doctoral research, he joined Jay Chemicals as a research associate where his research focusses on development of methodology for synthesis of fine and speciality chemicals.

EDUCATION

Doctor of Philosophy in Chemistry (2018-2023)
Institute - Indian Institute of Technology Gandhinagar
Supervisor - Dr Sriram Kanvah
Thesis Title - "Functional Cyanostilbenes: Sensing to Imaging"

Master in Science (Organic Chemistry) (2015-2017)
Institute - Department of Chemistry, Savitribai Phule Pune University (Formerly University of Pune)
Thesis Supervisor - Prof. Dilip D Dhavale
Thesis Title - " Synthesis of Pancratistatin Analogues Intermediates"

Bachelor of Science
Institute - G.S. College, Khamgaon, Affiliated to Sant Gadge Baba Amravati University

RESEARCH, TEACHING, or OTHER INTERESTS

Organic Chemistry, Biochemistry, Chemistry

8

Scopus Publications

49

Scholar Citations

4

Scholar h-index

2

Scholar i10-index

Scopus Publications

  • Halogen-bonded co-crystals with AIE-active α-cyanostilbenes
    Rahul Dahiwadkar, Gurudutt Dubey, Althaf Shaik, Palash Jana, Vijay Thiruvenkatam, and Sriram Kanvah

    Royal Society of Chemistry (RSC)
    A cooperative co-crystal and co-gels were obtained from combining two different aggregation-induced emitting cyanostilbene units through halogen bonding interaction.

  • AIE active cyanostilbenes for live-cell imaging of lipid droplets
    Rahul Dahiwadkar, Deeksha Rajput, Deepmala Singh, Virupakshi Soppina, and Sriram Kanvah

    Royal Society of Chemistry (RSC)
    Trifluoromethyl-substituted fluorophores with naphthalene and julolidine groups were utilized imaging and quantifying lipid droplets in COS-7 cells.

  • Plasmon-Rich BCZT Nanoparticles in the Photonic Crystal-Coupled Emission Platform for Cavity Hotspot-Driven Attomolar Sensing
    Sudha Maria Lis S, Seemesh Bhaskar, Rahul Dahiwadkar, Sriram Kanvah, Sai Sathish Ramamurthy, and Shivakiran Bhaktha B. N

    American Chemical Society (ACS)

  • Functional α-Cyanostilbenes: Sensing to Imaging
    Sriram Kanvah, Rahul Dahiwadkar, and Masood A. Kaloo

    Georg Thieme Verlag KG
    AbstractIn recent years, there has been considerable interest in cyanostilbenes due to their unique photophysical properties. The compounds emit light when aggregating, commonly called aggregation-induced emission (AIE). This remarkable feature makes cyanostilbenes ideal for various sensing applications, especially in aqueous environments. The detection of various analytes, such as metal ions and nitroaromatic compounds, has been accomplished using these compounds through various sensing mechanisms from chelation-enhanced fluorescence to fluorescence quenching. Furthermore, cyanostilbenes have shown great promise in biological imaging applications and have been employed for intracellular imaging, tracking, and targeting of sub-cellular organelles. The development and utilization of cyanostilbenes can significantly impact advanced sensing and imaging technologies in both analytical and biological fields. This potential stems from the unique properties of cyanostilbenes, such as their AIE characteristics, which sets them apart from other compounds and makes them highly useful for various applications. Further exploration and development of cyanostilbenes could lead to the creation of novel sensing and imaging technologies with wide-ranging applications in both academic and industrial settings.

  • Functional organogel with α-cyanostilbene scaffold: Aggregation enhanced emission and picric acid sensing
    Rahul Dahiwadkar, Arumugavel Murugan, Delna Johnson, Rik Chakraborty, Vijay Thiruvenkatam, and Sriram Kanvah

    Elsevier BV

  • White light emission from AIE-active luminescent organic materials
    Beena Kumari, Rahul Dahiwadkar, and Sriram Kanvah

    Wiley
    AbstractFluorescent organic materials that exhibit unique aggregation‐induced emission have been utilized for various applications, including white light emission (WLE). The materials typically rely on composite designs involving a mixture of compounds emitting at different wavelengths of light. To overcome the limitations offered by the design of such composite mixtures, tremendous efforts were also emphasized in developing single‐molecule substrates that emit white light. The white light by either method is typically controlled by the solvent polarity, energy and charge transfer, host‐guest interactions, gelation, or embedding in the polymer or organic frameworks. This article briefly reviews various molecules exhibiting aggregation‐induced emission behavior and emitting white light.

  • Detection of illicit GHB using AIE active fluorene containing α-Cyanostilbenes
    Rahul Dahiwadkar, Harsh Kumar, and Sriram Kanvah

    Elsevier BV

  • One- and Two-Component Organogels Containing Cyanostilbene without any Auxiliary Substituents
    Jagadish Katla, Althaf Shaik, Rahul Dahiwadkar, Vijay Thiruvenkatam, and Sriram Kanvah

    Wiley
    AbstractPyridyl acrylonitrile without traditional auxiliary groups form stable organogels in ethanol. The addition of a second non‐gelating cyanostilbene component results in a more stable two‐component gel. Single crystal X‐ray data reveal the influence of C−H⋅ ⋅ ⋅N, C−H⋅ ⋅ ⋅π, and π–π interactions in the formation of organogels. The morphology of the xerogels was studied by using SEM, which showed the self‐assembly of molecules to fibers and sheet‐like structures, and phase differences upon the gel formation and the structural phase characterization was measured using powder XRD. Exposure of the organogels to acidic (TFA) vapors results in distinct color changes and loss of gelation properties, thus highlighting the potential of these gels in sensing. The results represent a rare example of two‐component organogels using two different cyanostilbene units and show that functional two‐component organogels can be formed by utilizing the synergistic effects of the individual components.

RECENT SCHOLAR PUBLICATIONS

  • Functional α-Cyanostilbenes: Sensing to Imaging
    R Dahiwadkar, MA Kaloo, S Kanvah
    Synlett 35 (01), 3-20 2024

  • Plasmon-Rich BCZT Nanoparticles in the Photonic Crystal-Coupled Emission Platform for Cavity Hotspot-Driven Attomolar Sensing
    SBBN Sudha Maria Lis S, Seemesh Bhaskar, Rahul Dahiwadkar, Sriram Kanvah ...
    ACS Appl. Nano Mater. 2023, 6, 20, 19312–19326 20 (6), 19312 2023

  • Functional organogel with α-cyanostilbene scaffold: aggregation enhanced emission and picric acid sensing
    R Dahiwadkar, A Murugan, D Johnson, R Chakraborty, V Thiruvenkatam, ...
    Journal of Photochemistry and Photobiology A: Chemistry 434, 114227 2023

  • Halogen-bonded co-crystals with AIE-active α-cyanostilbenes
    R Dahiwadkar, G Dubey, A Shaik, P Jana, V Thiruvenkatam, S Kanvah
    New Journal of Chemistry 47 (24), 11685-11696 2023

  • AIE active cyanostilbenes for live-cell imaging of lipid droplets
    R Dahiwadkar, D Rajput, D Singh, V Soppina, S Kanvah
    New Journal of Chemistry 47 (21), 10016-10024 2023

  • White light emission from AIE‐active luminescent organic materials
    B Kumari, R Dahiwadkar, S Kanvah
    Aggregate 3 (5), e191 2022

  • Detection of illicit GHB using AIE active fluorene containing α-Cyanostilbenes
    R Dahiwadkar, H Kumar, S Kanvah
    Journal of Photochemistry and Photobiology A: Chemistry 427, 113844 2022

  • Detection of Illicit GHB using AIE active fluorene containing?-cyanostilbenes
    R Dahiwadkar, H Kumar, S Kanvah
    Elsevier 2022

  • Sensitive detection of sedatives using fluorescent probes
    R Dahiwadkar, S Kanvah
    Proceedings of the sixteenth DAE-BRNS biennial Trombay symposium on 2022

  • Styryl pyridinium fluorescence probes for staining nucleus
    R Dahiwadkar, A Rajwar, S Kharbanda, D Bhatia, S Kanvah
    2020

  • Cover Feature: One‐and Two‐Component Organogels Containing Cyanostilbene without any Auxiliary Substituents (ChemPlusChem 12/2019)
    J Katla, A Shaik, R Dahiwadkar, V Thiruvenkatam, S Kanvah
    ChemPlusChem 84 (12), 1776-1776 2019

  • One‐and Two‐Component Organogels Containing Cyanostilbene without any Auxiliary Substituents
    J Katla, A Shaik, R Dahiwadkar, V Thiruvenkatam, S Kanvah
    ChemPlusChem 84 (12), 1789-1795 2019

  • One and two? component organogels with cyanostilbene without any auxiliary substituents
    J Katla, A Shaik, R Dahiwadkar, V Thiruvenkatam, S Kanvah
    Wiley 2019

  • Self-assembling, red-emitting pyridinium based cationic probes targeting nucleus and plasma membrane in mammalian cells
    R Dahiwadkar, S Kanvah, S Kharbanda, A Rajwar, D Bhatia
    Proceedings of the fifteenth DAE-BRNS biennial Trombay symposium on 2019

  • Synthesis and evaluation of stilbene derivatives for protein binding
    R Dahiwadkar, S Kanvah


MOST CITED SCHOLAR PUBLICATIONS

  • White light emission from AIE‐active luminescent organic materials
    B Kumari, R Dahiwadkar, S Kanvah
    Aggregate 3 (5), e191 2022
    Citations: 17

  • One‐and Two‐Component Organogels Containing Cyanostilbene without any Auxiliary Substituents
    J Katla, A Shaik, R Dahiwadkar, V Thiruvenkatam, S Kanvah
    ChemPlusChem 84 (12), 1789-1795 2019
    Citations: 10

  • Detection of illicit GHB using AIE active fluorene containing α-Cyanostilbenes
    R Dahiwadkar, H Kumar, S Kanvah
    Journal of Photochemistry and Photobiology A: Chemistry 427, 113844 2022
    Citations: 9

  • Functional organogel with α-cyanostilbene scaffold: aggregation enhanced emission and picric acid sensing
    R Dahiwadkar, A Murugan, D Johnson, R Chakraborty, V Thiruvenkatam, ...
    Journal of Photochemistry and Photobiology A: Chemistry 434, 114227 2023
    Citations: 7

  • AIE active cyanostilbenes for live-cell imaging of lipid droplets
    R Dahiwadkar, D Rajput, D Singh, V Soppina, S Kanvah
    New Journal of Chemistry 47 (21), 10016-10024 2023
    Citations: 4

  • Plasmon-Rich BCZT Nanoparticles in the Photonic Crystal-Coupled Emission Platform for Cavity Hotspot-Driven Attomolar Sensing
    SBBN Sudha Maria Lis S, Seemesh Bhaskar, Rahul Dahiwadkar, Sriram Kanvah ...
    ACS Appl. Nano Mater. 2023, 6, 20, 19312–19326 20 (6), 19312 2023
    Citations: 2