@uvigo.gal
Chemical Engineering
Universidade de Vigo
Chemical Engineering, Catalysis, Environmental Chemistry, Waste Management and Disposal
Scopus Publications
A. Puga, J. Meijide, M. Pazos, M.A. Sanromán, and E. Rosales
Elsevier BV
A. Cruz del Álamo, A. Puga, M.I. Pariente, E. Rosales, R. Molina, M. Pazos, F. Martínez, and M.A. Sanromán
Elsevier BV
Antón Puga, Emilio Rosales, Marta Pazos, and María Angeles Sanromán
MDPI AG
The development of novel approaches to the remotion of pharmaceuticals in wastewater is a subject of concern due to their effect on living beings and the environment. Advanced oxidation processes and the use of relevant catalysts are feasible treatment alternatives that require further development. The development of suitable heterogeneous catalysts is a necessity. This work proposes the synthesis of an iron catalyst in a deep eutectic solvent (Fe-DES) composed of choline chloride and citric acid, which was physically and chemically characterized using SEM-EDS and TEM, FTIR, RAMAN, XRD and XPS. The characterisation confirmed the presence of iron in the form of hematite. Fe-DES was shown to be a multipurpose catalyst that can be applied in the removal of sulfamethoxazole as a reagent in the Fenton and electro-Fenton processes and as an activator of peroxymonosulfate (PMS) processes. After testing the catalyst with the aforementioned techniques, the best result was achieved by combining these processes in an electro-PMS, with great efficiency achieved by dual activation of the PMS with the catalyst and electric field, attaining total elimination at natural pH in 90 min. Furthermore, the degradation was confirmed by the detection of short-chain carboxylic acids (oxalic, succinic, and acetic) and reduction in toxicity values. These results confirm the suitability of Fe-DES to degrade high-priority pharmaceutical compounds.
A. Puga, J. Meijide, M. Pazos, E. Rosales, and M.A. Sanromán
Elsevier BV
Antón Puga, Manuela M. Moreira, Marta Pazos, Sónia A. Figueiredo, M. Ángeles Sanromán, Cristina Delerue-Matos, and Emilio Rosales
Elsevier BV
Antón Puga, Marta Pazos, Emilio Rosales, and M Angeles Sanromán
Elsevier BV
Antón Puga, Manuela M. Moreira, Sónia A. Figueiredo, Cristina Delerue-Matos, Marta Pazos, Emilio Rosales, and M. Ángeles Sanromán
Elsevier BV
A. Puga, E. Rosales, M. Pazos, and M.A. Sanromán
Elsevier BV
V. Acevedo-García, E. Rosales, A. Puga, M. Pazos, and M.A. Sanromán
Elsevier BV
Antón Puga, Emilio Rosales, Maria Angeles Sanromán, and Marta Pazos
Elsevier BV