Materials Science, Electronic, Optical and Magnetic Materials, Renewable Energy, Sustainability and the Environment, Soil Science
3
Scopus Publications
132
Scholar Citations
3
Scholar h-index
2
Scholar i10-index
Scopus Publications
Tunable Transparent Conductors Based on SnO2: Theoretical and Experimental Studies of Codoping Wenjing Qian, Xianghui Feng, Yanxue Wang, Ahmet Nazligul, Yiwen Lu, Mingqing Wang, Wei Wu, Kwang Leong Choy ACS Omega, 2024 High Resolution Image Download MS PowerPoint Slide Transparent conducting oxides (TCOs) are widely used in modern electronics because they have both high transmittance and good conductivity, which is beneficial for many applications such as light-emitting diodes. Tailoring electronic states and hence the conductive types by design is important for developing new materials with optimal properties for TCOs. SnO 2, with a wide band gap, low cost, no toxins, and high stability, is a promising host material for TCOs. Here, we performed a set of hybrid-exchange density functional theory calculations on the two-element and three-element codoped SnO 2 by using Sr, Ta, Al, Ga, V, and Nb, which were then validated by the relevant experimental works on SnO 2 . As predicted by the first-principles calculations, the controllability of the electronic states to be n- or p-type can be demonstrated experimentally by varying the relative doping concentration between donors (Ta/Nb) and acceptors (Al/Ga). One of the main advantages for these codoping methods is that the charge neutrality problem caused by the dopant can be circumvented. The thin films fabricated showed a low sheet resistance (down to ∼450 Ω /□ ) and a high optical transparency (above 80%). The combination of our calculations and experimental material fabrication and characterizations has shown a great potential for codoping SnO 2 for (i) the efficient processing of the integrated circuit composed of both p-type and n-type transistors (using the same target precursors during the deposition) and (ii) a good lattice matching for p–n junctions. Most importantly, our calculations, supported by the experimental works, point to a promising route to accelerate the discovery process for the alternative cost-effective and high-performance indium-free TCOs using computational material design.
Recent development in earth-abundant kesterite materials and their applications Ahmet Sencer Nazligul, Mingqing Wang, Kwang Leong Choy Sustainability Switzerland, 2020 Kesterite Cu2ZnSnS4 (CZTS) has attracted attention as an earth-abundant alternative to commercially successful CIGS solar cells. CZTS exhibits decent optoelectrical properties while having excellent stability on top of being an earth-abundant, low-cost and non-toxic material. Therefore, in recent years, there has been a significant research effort to develop CZTS-based devices. The efficiency of CZTS solar cells reached 12.6% in 2013, and this was a remarkable achievement at the time. However, the efficiency of these devices has been stagnant since then while emerging technologies, most notably perovskite solar cells, keep breaking record after record. Currently, CZTS research focuses on discovering the secrets of material properties that hinder the efficiency of CZTS solar cells while branching out to develop alternative applications for this material. In this review, we summarize the interesting properties of CZTS as well as its promising applications, which include thin-film solar cells, charge-transfer layers in perovskite solar cells, and photoelectrochemical water splitting while briefly commenting on its other possible applications.
RECENT SCHOLAR PUBLICATIONS
Tunable Transparent Conductors Based on SnO 2 : Theoretical and Experimental Studies of Codoping W Qian, X Feng, Y Wang, A Nazligul, Y Lu, M Wang, W Wu, KL Choy ACS omega 9 (50), 49674-49682 , 2024 2024 Citations: 4
Exploring alternative renewable energy applications for kesterite materials through doping and cation substitution AS Nazligul UCL (University College London) , 2023 2023
Carbon-black combined with TiO2 and KuQ as sustainable photosystem for a reliable self-powered photoelectrochemical biosensor V Mazzaracchio, R Marrone, M Forchetta, F Sabuzi, P Galloni, M Wang, ... Electrochimica Acta 426, 140766 , 2022 2022 Citations: 14
Recent development in earth-abundant kesterite materials and their applications AS Nazligul, M Wang, KL Choy Sustainability 12 (12), 5138 , 2020 2020 Citations: 114
MOST CITED SCHOLAR PUBLICATIONS
Recent development in earth-abundant kesterite materials and their applications AS Nazligul, M Wang, KL Choy Sustainability 12 (12), 5138 , 2020 2020 Citations: 114
Carbon-black combined with TiO2 and KuQ as sustainable photosystem for a reliable self-powered photoelectrochemical biosensor V Mazzaracchio, R Marrone, M Forchetta, F Sabuzi, P Galloni, M Wang, ... Electrochimica Acta 426, 140766 , 2022 2022 Citations: 14
Tunable Transparent Conductors Based on SnO 2 : Theoretical and Experimental Studies of Codoping W Qian, X Feng, Y Wang, A Nazligul, Y Lu, M Wang, W Wu, KL Choy ACS omega 9 (50), 49674-49682 , 2024 2024 Citations: 4
Exploring alternative renewable energy applications for kesterite materials through doping and cation substitution AS Nazligul UCL (University College London) , 2023 2023