Dr. Lakkanna S Chougala is currently working as Teaching Assistant in the Department of Physics, Karnatak University, India. Lakkanna S Chougala research interest includes Material science, Synthesis and characterization of Nanoparticles, Photovoltaics, Fluorescence Quenching and Spectroscopic Investigations of organic and inorganic Materials.
EDUCATION
M.Sc, Ph.D
RESEARCH INTERESTS
Material science, Synthesis and characterization of Nanoparticles, Photovoltaics, Fluorescence Quenching and Spectroscopic Investigations of organic and inorganic Materials.
Biogenic Synthesis and Characterization of ZnO Nanoparticles from Aloe barbadensis Miller Leaf Extract Vijayakumar D. Jangannanavar, Mallikarjun K. Patil, Lakkanna S. Chougala, Sanjeev R. Inamdar, Kotresh M. Goudar Macromolecular Symposia, 2021 Abstract This study is aimed to synthesize zinc oxide nanoparticles (ZnO NPs) from Aloe barbadensis Miller leaf extract using the green synthesis method at room temperature. The biosynthesized NPs are characterized by X‐ray diffraction (XRD), UV–vis spectroscopy (UV–vis), Fourier transform infrared (FTIR) spectroscopy, and scanning electron microscope (SEM). The XRD pattern has revealed the hexagonal wurtzite structure with a crystallite size of 16 nm for synthesized ZnO NPs. The FTIR results display the formation of ZnO NPs and the presence of other functional groups. The UV–vis absorption spectrum shows an absorption band at 347 nm and the value of the bandgap is found to be 3.75 eV. The surface morphology of synthesized NPs is visualized by SEM images, it is observed that most of the NPs are needle in shape. Further, these NPs will find applications in biosensing and photocatalytic activity.
Role of Substituent Position in Coumarin Derivatives during their Interaction with TiO2 Nano Particles Nirupama M. Jagadeeshwar, Netravati I. Khanapurmath, Lakkanna S. Chougala, Manohar V. Kulkarni, Jagadish S. Kadadevarmath Journal of Fluorescence, 2021 The effect of position of benzo group in coumarin derivatives, 5,6 benzo-4-azidomethyl coumarin (5BAMC) and 7,8 benzo-4-azidomethyl coumarin (7BAMC) during their interaction with TiO2 nanoparticles in ethyl acetate, tetrahydrofuran, butan-1-ol and acetonitrile solvents has been studied using different spectroscopic methods and electrochemical analysis. Benesi-Hildebrand plots indicate that nature of interaction between 7BAMC and TiO2 is 1:2 in solvent with low dielectric constant whereas for 5BAMC and TiO2, it is 1:1 in all the solvents. From the fluorescence quenching study and binding equilibria analysis, it is observed that interaction between 5BAMC and TiO2 depends on the dielectric constant of the solvent. Time resolved quenching study reveals that quenching is dynamic for 5BAMC in solvent with high dielectric constant. Whereas for 7BAMC, it is dynamic in solvent with low dielectric constant. Hence the nature of interaction of these two coumarin derivatives with TiO2 NPs is different. From electrochemical analysis, it is observed that, free energy change for electron transfer is more negative for 5BAMC-TiO2 compared to 7BAMC-TiO2 therefore quenching is more efficient for 5BAMC-TiO2 compared to 7BAMC-TiO2 system, which is also confirmed from fluorescence quenching studies. Non-radiative energy transfer rate is more than radiative energy transfer rate for both the systems according to FRET study.
Fluorescence Investigations on Interactions between 7,8-benzo-4-azidomethyl Coumarin and Ortho- and Para-phenylenediamines in Binary Solvent Mixtures of THF and Water Nirupama J.M., L. S. Chougala, N. I. Khanapurmath, A. Ashish, L. A. Shastri, M. V. Kulkarni, J. S. Kadadevarmath Journal of Fluorescence, 2018 Fluorescence investigations on interactions between 7,8-benzo-4-azidomethyl coumarin (7BAMC) and quenchers ortho-phenylenediamine (OPD) and para-phenylenediamines (PPD) in binary solvent mixtures (THF + water) have been reported. UV-absorption study indicated a weak hydrophobic interaction between 7BAMC and the para isomer. NMR spectral studies indicated the presence of an interaction between 7BAMC and PPD. Magnitudes of the parameters associated with FRET, showed the presence of interactions between 7BAMC and PPD quencher is more predominant than OPD. Fluorescence quenching studies reveal the role of static and dynamic quenching pathways, depending upon Stern–Volmer constant, dielectric constant and dominant non-radiative processes. Binding equilibria analysis indicates a strong interaction between 7BAMC and PPD than OPD and formation of H-bonding. Based on the magnitudes of free energy, enthalpy change and entropy, bimolecular interaction process may be considered as spontaneous and hydrophobic.
Photophysical, Electrochemical Studies of Novel Pyrazol-4-yl-2,3-dihydroquinazolin-4(1H)-ones and Their Anticancer Activity Atulkumar A. Kamble, Ravindra R. Kamble, Lakkanna S. Chougala, Jagadish S. Kadadevarmath, Shivaraj R. Maidur, Parutagouda S. Patil, Mahadev N. Kumbar, Sheetal B. Marganakop Chemistryselect, 2017 A series of novel 2,3-dihydroquinazolin-4(1H)-ones 7 a-g were designed, synthesized and were characterized by IR, 1H & 13C NMR, MS, and elemental analysis. The optical and electrochemical properties have been studied using UV-Vis absorption, fluorescence spectroscopy, life time and cyclic voltammetry (CV) measurements. Quantum yield and effect of solvents for the compounds 7 a-g were investigated. Density Functional Theory (DFT) computations have been carried out for all the synthesized compounds and the computed values found to be approximately in close agreement with the experimental results. Further, the compounds 7 a, 7 d, 7 f and 7 g were evaluated for their anticancer activity at National Cancer Institute, NIH, Bethesda, USA and have shown moderate to good anticancer activities.
Fluorescence enhancement of chalcone derivatives, during their interaction with nanoparticles JM Nirupama, RG Kalkhambkar, SS Malunavar, LS Chougala Proceedings of the fifteenth national symposium on radiation and … , 2023 2023
Influence of substituent position in aromatic diamines on coumarin derivative JM Nirupama, R Melavanki, NI Khanapurmath, LS Chougala, MV Kulkarni, ... Journal of Photochemistry and Photobiology A: Chemistry 422, 113560 , 2022 2022 Citations: 5
Biogenic Synthesis and Characterization of ZnO Nanoparticles from Aloe barbadensis Miller Leaf Extract VD Jangannanavar, MK Patil, LS Chougala, SR Inamdar, KM Goudar Macromolecular symposia 400 (1), 2100177 , 2021 2021 Citations: 11
Role of Substituent Position in Coumarin Derivatives during their Interaction with TiO 2 Nano Particles NM Jagadeeshwar, NI Khanapurmath, LS Chougala, MV Kulkarni, ... Journal of Fluorescence 31 (3), 775-785 , 2021 2021 Citations: 2
Effect of stereo electronic factors of coumarin derivatives during their interaction with TiO2 nanoparticles NI Khanapurmath, LS Chougala, MV Kulkarni, JS Kadadevarmath Journal of Molecular Liquids 291, 111266 , 2019 2019 Citations: 3
Effect of amino anilines on the fluorescence of coumarin derivative JM Nirupama, NI Khanapurmath, LS Chougala, LA Shastri, RF Bhajantri, ... Journal of Luminescence 208, 164-173 , 2019 2019 Citations: 12
Synthesis and Characterization of ZnO Nanoparticles and Its Application to Dye Sensitized Solar Cell LS Chougala, MS Yatnatti, RK Linganagoudar, JS Kadadevarmath Advanced Science Letters 24 (8), 5618-5623 , 2018 2018
(E)-N′-(4-nitrobenzylidene)-2-(1-(4-methoxyphenyl)-5-oxo-1H-1, 2, 4-triazol-4 (5H)-yl) acetohydrazide: Synthesis, crystal structure, DFT and Hirshfeld surface analysis SM Somagond, RR Kamble, SKJ Shaikh, SM Kumar, JP Dasappa, ... Chemical Data Collections 13, 126-138 , 2018 2018 Citations: 4
Chemical Data Collections SM Somagond, RR Kamble, SKJ Shaikh, SM Kumar, JP Dasappa, ... 2018
Spectroscopic investigations of interaction between TiO2 and newly synthesized phenothiazine derivative-PTA dye and its role as photo-sensitizer LS Chougala, JS Kadadevarmath, AA Kamble, AI Torvi, MS Yatnatti, ... Journal of Luminescence , 2018 2018 Citations: 10
Fluorescence Investigations on Interactions between 7,8-benzo-4- azidomethyl Coumarin and Ortho- and Para-phenylenediamines in Binary Solvent Mixtures of THF and Water N J.M, LS Chougala, NI Khanapurmath, A Ashish, LA Shastri, MV Kulkarni, ... Journal of Fluorescence 27 (136) , 2017 2017 Citations: 6
Simple Approach on Synthesis of ТІО 2 Nanoparticles and its Application in dye Sensitized Solar Cells. LS Chougala, MS Yatnatti, RK Linganagoudar, RR Kamble, ... J. Nano- Electron. Phys 9, 04005-1-04005-6 , 2017 2017 Citations: 277
Effect of TiO 2 nanoparticles on newly synthesized phenothiazine derivative-CPTA dye and its applications as dye sensitized solar cell LS Chougala, JS Kadadevarmath, AA Kamble, PK Bayannavar, ... Journal of Molecular Liquids 244, 97–102 , 2017 2017 Citations: 27
Модифікований метод вимірювання величини спонтанної поляризації сегнетоелектричних рідких кристалів ОВ Ковальчук, ОФ Шевчук Сумський державний університет , 2017 2017 Citations: 2
Photophysical, Electrochemical Studies of Novel Pyrazol-4-yl-2,3-dihydroquinazolin-4(1H)-ones and Their Anticancer Activity AA Kamble, RR Kamble, LS Chougala, JS Kadadevarmath, SR Maidur, ... ChemistrySelect 2, 6882–6890 , 2017 2017 Citations: 13
MOST CITED SCHOLAR PUBLICATIONS
Simple Approach on Synthesis of ТІО 2 Nanoparticles and its Application in dye Sensitized Solar Cells. LS Chougala, MS Yatnatti, RK Linganagoudar, RR Kamble, ... J. Nano- Electron. Phys 9, 04005-1-04005-6 , 2017 2017 Citations: 277
Effect of TiO 2 nanoparticles on newly synthesized phenothiazine derivative-CPTA dye and its applications as dye sensitized solar cell LS Chougala, JS Kadadevarmath, AA Kamble, PK Bayannavar, ... Journal of Molecular Liquids 244, 97–102 , 2017 2017 Citations: 27
Photophysical, Electrochemical Studies of Novel Pyrazol-4-yl-2,3-dihydroquinazolin-4(1H)-ones and Their Anticancer Activity AA Kamble, RR Kamble, LS Chougala, JS Kadadevarmath, SR Maidur, ... ChemistrySelect 2, 6882–6890 , 2017 2017 Citations: 13
Effect of amino anilines on the fluorescence of coumarin derivative JM Nirupama, NI Khanapurmath, LS Chougala, LA Shastri, RF Bhajantri, ... Journal of Luminescence 208, 164-173 , 2019 2019 Citations: 12
Biogenic Synthesis and Characterization of ZnO Nanoparticles from Aloe barbadensis Miller Leaf Extract VD Jangannanavar, MK Patil, LS Chougala, SR Inamdar, KM Goudar Macromolecular symposia 400 (1), 2100177 , 2021 2021 Citations: 11
Spectroscopic investigations of interaction between TiO2 and newly synthesized phenothiazine derivative-PTA dye and its role as photo-sensitizer LS Chougala, JS Kadadevarmath, AA Kamble, AI Torvi, MS Yatnatti, ... Journal of Luminescence , 2018 2018 Citations: 10
Fluorescence Investigations on Interactions between 7,8-benzo-4- azidomethyl Coumarin and Ortho- and Para-phenylenediamines in Binary Solvent Mixtures of THF and Water N J.M, LS Chougala, NI Khanapurmath, A Ashish, LA Shastri, MV Kulkarni, ... Journal of Fluorescence 27 (136) , 2017 2017 Citations: 6
Influence of substituent position in aromatic diamines on coumarin derivative JM Nirupama, R Melavanki, NI Khanapurmath, LS Chougala, MV Kulkarni, ... Journal of Photochemistry and Photobiology A: Chemistry 422, 113560 , 2022 2022 Citations: 5
(E)-N′-(4-nitrobenzylidene)-2-(1-(4-methoxyphenyl)-5-oxo-1H-1, 2, 4-triazol-4 (5H)-yl) acetohydrazide: Synthesis, crystal structure, DFT and Hirshfeld surface analysis SM Somagond, RR Kamble, SKJ Shaikh, SM Kumar, JP Dasappa, ... Chemical Data Collections 13, 126-138 , 2018 2018 Citations: 4
Effect of stereo electronic factors of coumarin derivatives during their interaction with TiO2 nanoparticles NI Khanapurmath, LS Chougala, MV Kulkarni, JS Kadadevarmath Journal of Molecular Liquids 291, 111266 , 2019 2019 Citations: 3
Role of Substituent Position in Coumarin Derivatives during their Interaction with TiO 2 Nano Particles NM Jagadeeshwar, NI Khanapurmath, LS Chougala, MV Kulkarni, ... Journal of Fluorescence 31 (3), 775-785 , 2021 2021 Citations: 2
Модифікований метод вимірювання величини спонтанної поляризації сегнетоелектричних рідких кристалів ОВ Ковальчук, ОФ Шевчук Сумський державний університет , 2017 2017 Citations: 2
Fluorescence enhancement of chalcone derivatives, during their interaction with nanoparticles JM Nirupama, RG Kalkhambkar, SS Malunavar, LS Chougala Proceedings of the fifteenth national symposium on radiation and … , 2023 2023
Synthesis and Characterization of ZnO Nanoparticles and Its Application to Dye Sensitized Solar Cell LS Chougala, MS Yatnatti, RK Linganagoudar, JS Kadadevarmath Advanced Science Letters 24 (8), 5618-5623 , 2018 2018
Chemical Data Collections SM Somagond, RR Kamble, SKJ Shaikh, SM Kumar, JP Dasappa, ... 2018